ORTHO-NITROSOPHENOLS AS POLYMERIZATION INHIBITORS
    1.
    发明申请
    ORTHO-NITROSOPHENOLS AS POLYMERIZATION INHIBITORS 审中-公开
    作为聚合抑制剂的OROO-NITROSOPHENOL

    公开(公告)号:US20090240092A1

    公开(公告)日:2009-09-24

    申请号:US12479115

    申请日:2009-06-05

    IPC分类号: C07C7/20

    摘要: Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of at least one nitroso inhibitor of the structure: wherein R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, nitro, nitroso, halogen, COOR wherein R is hydrogen or alkyl, alkyl, and heteroatom-substituted alkyl; or adjacent groups R1, R2, R3, and R4 can be taken together to form a substituted or unsubstituted fused six-membered ring.Also disclosed is a composition of matter comprising: A) an ethylenically unsaturated monomer and B) at least one nitroso compound of the above-described structure.

    摘要翻译: 本文公开了一种抑制烯键式不饱和单体过早聚合的方法,包括向所述单体中加入有效量的至少一种以下结构的亚硝基抑制剂:其中R 1,R 2,R 3和R 4独立地选自氢 硝基,亚硝基,卤素,COOR,其中R是氢或烷基,烷基和杂原子取代的烷基; 或相邻基团R 1,R 2,R 3和R 4可以一起形成取代或未取代的稠合六元环。 还公开了一种物质组合物,其包含:A)烯属不饱和单体和B)至少一种上述结构的亚硝基化合物。

    Ortho-nitrosophenols as polymerization inhibitors
    2.
    发明授权
    Ortho-nitrosophenols as polymerization inhibitors 失效
    邻硝基苯酚作为聚合抑制剂

    公开(公告)号:US07553896B2

    公开(公告)日:2009-06-30

    申请号:US11156214

    申请日:2005-06-17

    IPC分类号: C08K5/16

    摘要: Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of at least one nitroso inhibitor of the structure: wherein R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, nitro, nitroso, halogen, COOR wherein R is hydrogen or alkyl, alkyl, and heteroatom-substituted alkyl; or adjacent groups R1, R2, R3, and R4 can be taken together to form a substituted or unsubstituted fused six-membered ring. Also disclosed is a composition of matter comprising: A) an ethylenically unsaturated monomer and B) at least one nitroso compound of the above-described structure.

    摘要翻译: 本文公开了一种抑制烯键式不饱和单体过早聚合的方法,包括向所述单体中加入有效量的至少一种以下结构的亚硝基抑制剂:其中R 1,R 2,R 3和R 4独立地选自氢 硝基,亚硝基,卤素,COOR,其中R是氢或烷基,烷基和杂原子取代的烷基; 或相邻基团R 1,R 2,R 3和R 4可以一起形成取代或未取代的稠合六元环。 还公开了一种物质组合物,其包含:A)烯属不饱和单体和B)至少一种上述结构的亚硝基化合物。

    Polymerization inhibitor composition for vinyl aromatic compounds
    9.
    发明授权
    Polymerization inhibitor composition for vinyl aromatic compounds 失效
    乙烯基芳族化合物的聚合抑制剂组合物

    公开(公告)号:US4915873A

    公开(公告)日:1990-04-10

    申请号:US172048

    申请日:1988-03-22

    CPC分类号: C07C7/20 C09K15/30

    摘要: Vinyl aromatic compounds are stabilized against polymerization by the addition of an effective amount of a polymerization inhibition composition comprising (a) a phenothiazine compound; and (b) an aryl-substituted phenylenediamine compound. In other aspects, this invention is directed to a vinyl aromatic composition stabilized against polymerization by such polymerization inhibitor composition, as well as to a method of stabilizing a vinyl aromatic composition against polymerization which method comprises adding an effective amount of such polymerization inhibitor composition.

    摘要翻译: 乙烯基芳族化合物通过加入有效量的聚合抑制组合物而稳定,防止聚合,所述聚合抑制组合物包含(a)吩噻嗪化合物; 和(b)芳基取代的苯二胺化合物。 在其它方面,本发明涉及一种通过这种阻聚剂组合物稳定防止聚合的乙烯基芳族组合物,以及一种使乙烯基芳族组合物与聚合反应稳定的方法,该方法包括加入有效量的这种聚合抑制剂组合物。