PROCESS FOR THE PREPARATION OF (METH)ACRYLIC ESTERS AND DERIVATIVES
    4.
    发明申请
    PROCESS FOR THE PREPARATION OF (METH)ACRYLIC ESTERS AND DERIVATIVES 有权
    (甲基)丙烯酸酯和衍生物的制备方法

    公开(公告)号:US20140364619A1

    公开(公告)日:2014-12-11

    申请号:US14301576

    申请日:2014-06-11

    CPC classification number: C07D233/32

    Abstract: Transesterification processes for producing a compound of formula (I) wherein R1 is H or a methyl group, A and B are each, independently, a linear or branched C2-C5 alkylene group, comprising reacting: an acrylate or methacrylate of formula (II) wherein R1 is H or a methyl group and R2 is a C1-C4 alkyl group, with a compound of formula (III) wherein the reaction is performed: (i) in the presence of calcium oxide and calcium hydroxide, and (ii) wherein the molar ratio of the compounds of formula (II) to formula (III) is less than 4:1 or 3:1 respectively.

    Abstract translation: 制备其中R 1为H或甲基的式(I)化合物的酯交换方法,A和B各自独立地为直链或支链C 2 -C 5亚烷基,包括使式(II)的丙烯酸酯或甲基丙烯酸酯反应: 其中R1是H或甲基,R2是C1-C4烷基,其中进行反应的式(III)化合物:(i)在氧化钙和氢氧化钙的存在下,和(ii)其中 式(II)化合物与式(III)的摩尔比分别小于4:1或3:1。

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