摘要:
High purity benzene and high octane alkylaromatic gasoline can be obtained via a dual stage reforming process utilizing a non-acidic Group VIII metal containing microporous crystalline silicate catalyst in the first stage followed by first stage effluent treatment over acidic zeolite catalyst operating under conditions in the second stage to upgrade the first stage effluent in RON, in aromatic content or both.
摘要:
A process for producing monosubstituted monoalkylaromatics from C.sub.8 +n-paraffins-containing feeds, by contacting the feeds with a non-acid catalyst comprising a microporous crystalline material containing tin, indium, thallium or lead, is disclosed.
摘要:
A low acidity Group VIII metal-containing zeolite MCM-22 catalyst, said zeolite exhibiting an Alpha value of not greater than about 150, is provided for conversion of aliphatic C.sub.2 to C.sub.12 hydrocarbon(s) to olefin(s) and/or aromatic(s).
摘要:
Aliphatic C.sub.2 to C.sub.12 hydrocarbon(s) are converted to olefin(s) and/or aromatic(s) in the presence of an essentially non-acidic Group VIII metal species-containing zeolite MCM-22 catalyst.
摘要:
An improved, low-pressure dehydrocyclization and/or reforming process based on a non-acidic metal containing crystalline microporous tin catalyst, in which the feed is rich in low octane hydrocarbons, such as paraffins, and in which the product has increased aromatic content and increased octane value over that of the feed.
摘要:
Aliphatic C.sub.2 to C.sub.12 hydrocarbon(s) are converted to olefin(s) and/or aromatic(s) in the presence of a low acidity Group VIII metal-containing zeolite MCM-22 catalyst, said zeolite exhibiting an Alpha value of not greater than about 150.
摘要:
A catalytic dehydrogenation to produce the unsaturated analogs of aliphatic compounds with high process selectivity for the unsaturated analog production. The catalytic dehydrogenation comprises contacting the aliphatic compound, under dehydrogenation conditions, with a catalyst composition comprising a dehydrogenation metal and indium containing non-acidic crystalline microporous material.
摘要:
A catalytic dehydrogenation to produce the unsaturated analogs of aliphatic compounds with high process selectivity for the unsaturated analog production. The catalytic dehydrogenation comprises contacting the aliphatic compound, under dehydrogenation conditions, with a catalyst composition comprising a dehydrogenation metal and indium containing non-acidic crystalline microporous material.
摘要:
An integrated refining scheme for hydroprocessing high boiling fractions such as gas oil and catalytically cracked cycle oils to produce premium quality distillates, especially jet fuels and naphthas suitable for reforming into high octane gasoline. In addition, unconverted, high boiling fractions suitable for processing by conventional refining techniques into high quality, low pour point lube base stocks are obtained. The integrated hydroprocessing comprises a first stage hydrocracking step employing an aromatic selective hydrocracking catalyst based on a large pore size acidic component such as amorphous alumina or silica alumina or a large pore size zeolite such as zeolite X or zeolite Y. The hydrocracking may be operated either in a naphtha directing mode under conditions of moderate to high severity or under conditions of low to moderate severity to produce a relatively higher proportion of product boiling in the middle distillate range. The unconverted fraction from the hydrocracking step is passed to a second step in which it is hydroprocessed over a zeolite beta catalyst with additional hydrogenation-dehydrogenation functionality. In this stage, the paraffins remaining in the feed are attacked by the zeolite beta to form isoparaffins and conditions may be controlled to favor hydroisomerization over hydrocracking so as to increase the yield of middle distillate product, especially of high isoparaffinic jet fuels and diesel fuel.
摘要:
A process for dewaxing a hydrocarbon feedstock with a relatively high pour point and containing paraffins selected from the group of normal paraffins and slightly branched paraffins and sulfur and nitrogen compounds which comprises subjecting said oil to hydrotreating in a hydrotreating zone operated at hydrotreating conditions sufficient to remove at least a portion of said sulfur and nitrogen compounds and subjecting said hydrotreated oil to catalytic dewaxing by contacting said oil with a catalyst comprising zeolite beta having a silica/alumina ratio of at least 30:1 and a hydrogenation/dehydrogenation component under isomerization conditions.