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公开(公告)号:US06420503B1
公开(公告)日:2002-07-16
申请号:US09497846
申请日:2000-02-03
申请人: Saikumar Jayaraman , Richard Vicari , Larry F. Rhodes , Pushkara Rao Varanasi , Thomas I. Wallow , Ratnam Sooriyakumaran , Robert D. Allen , Richard A. DiPietro , Hiroshi Ito , Juliann Opitz
发明人: Saikumar Jayaraman , Richard Vicari , Larry F. Rhodes , Pushkara Rao Varanasi , Thomas I. Wallow , Ratnam Sooriyakumaran , Robert D. Allen , Richard A. DiPietro , Hiroshi Ito , Juliann Opitz
IPC分类号: C08F2806
摘要: The invention is directed to polymers containing a repeating unit derived from a norbornene sulfonamide. These may be addition polymers which include copolymers with one or more comonomers such as norbornene, ethylene, an acrylate or sulfur dioxide or carbon monoxide. Said monomers may be polymerized using single or multicomponent Group VIII catalysts. The norbornene sulfonamides can also form ROMP polymers using known metathesis catalysts. Preferably the ROMP polymers may be hydrogenated to give more stable polymers.
摘要翻译: 本发明涉及含有衍生自降冰片烯磺酰胺的重复单元的聚合物。 这些可以是加成聚合物,其包括与一种或多种共聚单体如降冰片烯,乙烯,丙烯酸酯或二氧化硫或一氧化碳的共聚物。 所述单体可以使用单组分或多组分VIII族催化剂进行聚合。 降冰片烯磺酰胺也可以使用已知的复分解催化剂形成ROMP聚合物。 优选地,ROMP聚合物可以被氢化以得到更稳定的聚合物。
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公开(公告)号:US06235849B1
公开(公告)日:2001-05-22
申请号:US09497356
申请日:2000-02-03
IPC分类号: C08F804
摘要: The invention is directed to polymers containing a repeating unit derived from a norbornene sulfonamide. These may be addition polymers which include copolymers with one or more comonomers such as norbornene, ethylene, an acrylate or sulfur dioxide or carbon monoxide. Said monomers may be polymerized using single or multicomponent Group VIII catalysts. The norbornene sulfonamides can also form ROMP polymers using known metathesis catalysts. Preferably the ROMP polymers may be hydrogenated to give more stable polymers.
摘要翻译: 本发明涉及含有衍生自降冰片烯磺酰胺的重复单元的聚合物。 这些可以是加成聚合物,其包括与一种或多种共聚单体如降冰片烯,乙烯,丙烯酸酯或二氧化硫或一氧化碳的共聚物。 所述单体可以使用单组分或多组分VIII族催化剂进行聚合。 降冰片烯磺酰胺也可以使用已知的复分解催化剂形成ROMP聚合物。 优选地,ROMP聚合物可以被氢化以得到更稳定的聚合物。
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公开(公告)号:US07312292B2
公开(公告)日:2007-12-25
申请号:US10860876
申请日:2004-06-04
申请人: Ravi Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Saikumar Jayaraman , Robert John Duff , John-Henry Lipian
发明人: Ravi Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Saikumar Jayaraman , Robert John Duff , John-Henry Lipian
IPC分类号: C08F30/02
CPC分类号: C08J5/2256 , C08G61/06 , C08J2385/04 , H01B1/122 , H01M4/8605 , H01M8/1023 , H01M8/1025 , H01M8/1032 , H01M8/1039
摘要: A polymer comprising polycyclic repeating units having recurring ion conducting groups and optional crosslinkable groups is disclosed. The present invention provides the capability of tailoring polymers to impart unique properties to membranes fabricated from the polymers. Membranes comprising the polymers and methods for preparing the membranes and their use in ion conducting membranes, particularly in fuel cells, are also provided.
摘要翻译: 公开了包含具有重复离子导电基团和任选的可交联基团的多环重复单元的聚合物。 本发明提供了定制聚合物以赋予由聚合物制造的膜独特的性能的能力。 还提供了包含聚合物的膜和用于制备膜的方法及其在离子传导膜中的用途,特别是在燃料电池中。
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公开(公告)号:US20080242750A1
公开(公告)日:2008-10-02
申请号:US11983505
申请日:2007-11-09
申请人: R. Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Robert John Duff , Saikumar Jayaraman , John-Henry Lipian
发明人: R. Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Robert John Duff , Saikumar Jayaraman , John-Henry Lipian
IPC分类号: B01J47/12
CPC分类号: C08J5/2256 , C08G61/06 , C08J2385/04 , H01B1/122 , H01M4/8605 , H01M8/1023 , H01M8/1025 , H01M8/1032 , H01M8/1039
摘要: A polymer comprising polycyclic repeating units having recurring ion conducting groups and optional crosslinkable groups is disclosed. The present invention provides the capability of tailoring polymers to impart unique properties to membranes fabricated from the polymers. Membranes comprising the polymers and methods for preparing the membranes and their use in ion conducting membranes, particularly in fuel cells, are also provided.
摘要翻译: 公开了包含具有重复离子导电基团和任选的可交联基团的多环重复单元的聚合物。 本发明提供了定制聚合物以赋予由聚合物制造的膜独特的性能的能力。 还提供了包含聚合物的膜和用于制备膜的方法及其在离子传导膜中的用途,特别是在燃料电池中。
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公开(公告)号:US06455650B1
公开(公告)日:2002-09-24
申请号:US09412935
申请日:1999-10-05
申请人: John-Henry Lipian , Larry F. Rhodes , Brian L. Goodall , Andrew Bell , Richard A. Mimna , John C. Fondran , Saikumar Jayaraman , April D. Hennis , Christine N. Elia , Jennifer D. Polley , Ayusman Sen
发明人: John-Henry Lipian , Larry F. Rhodes , Brian L. Goodall , Andrew Bell , Richard A. Mimna , John C. Fondran , Saikumar Jayaraman , April D. Hennis , Christine N. Elia , Jennifer D. Polley , Ayusman Sen
IPC分类号: C08F480
CPC分类号: C08F32/08 , C08F32/00 , Y02P20/582
摘要: Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R′)zM(L′)x(L″)y]b[WCA]d wherein [(R′)zM(L′)x(L″)y] is a cation complex where M represents a Group 10 transition metal; R′ represents an anionic hydrocarbyl containing ligand; L′ represents a Group 15 neutral electron donor ligand; L″ represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.
摘要翻译: 使用阳离子10族金属络合物和下式的弱配位阴离子进行环烯加成聚合的方法:其中[(R')z M(L')x(L“)y]是阳离子络合物,其中M表示 第10组过渡金属; R'表示含阴离子烃基的配体; L'表示15族中性电子给体配体; L“表示不稳定的中性电子给体配体; x为1或2; y为0,1,2或3; 且z为0或1,其中x,y和z之和为4; 和[WCA]代表弱协调的对抗综合体; b和d是表示阳离子络合物和弱配位抗衡阴离子络合物在总体催化剂络合物上平衡电荷的次数的数字。
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公开(公告)号:US20080194740A1
公开(公告)日:2008-08-14
申请号:US11949328
申请日:2007-12-03
申请人: Edmund Elce , Andrew Bell , Brian Knapp , Hendra Ng , Larry F. Rhodes , Robert Shick , Wei Zhang , William DiMenna , Saikumar Jayaraman , Jianyong Jin , Rajesh Raja Puthenkovilakom , Ramakrishna Ravikiran , Xiaoming Wu , Etsu Takeuchi
发明人: Edmund Elce , Andrew Bell , Brian Knapp , Hendra Ng , Larry F. Rhodes , Robert Shick , Wei Zhang , William DiMenna , Saikumar Jayaraman , Jianyong Jin , Rajesh Raja Puthenkovilakom , Ramakrishna Ravikiran , Xiaoming Wu , Etsu Takeuchi
IPC分类号: C08K5/45 , C08G73/00 , C08K5/1545
CPC分类号: C08G61/04 , C08F232/08 , G03F7/0388
摘要: A polymer includes a first type of repeat unit represented by Formula I: where X is selected from —CH2—, —CH2—CH2—, or —O—; m is an integer from 0 to about 5; and where for the first type of repeat unit one of R1, R2, R3, and R4 is one of a maleimide containing group and for the second type of repeat unit one of R1, R2, R3, and R4 is a hindered aromatic group, a C8 or greater alkyl group, a C4 or greater halohydrocarbyl or perhalocarbyl group, a C7 or greater aralkyl group, or a heteroatom hydrocarbyl or halohydrocarbyl group.
摘要翻译: 聚合物包括由式I表示的第一类型的重复单元:其中X选自-CH 2 - , - CH 2 -CH 2 > - 或-O-; m是0至约5的整数; 并且对于第一类型的重复单元,R 1,R 2,R 3和R 4中的一个,R 4, >是含有马来酰亚胺的基团之一,对于第二类型的重复单元,R 1,R 2,R 3和R 3中的一个,R 3,R 3, 受阻芳族基团,C 8或更高级烷基,C 4或更大的卤代烃基或全卤代羰基,C 7个或更大的芳烷基,或杂原子烃基或卤代烃基。
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公开(公告)号:US07378456B2
公开(公告)日:2008-05-27
申请号:US11044484
申请日:2005-01-27
IPC分类号: C08J3/28 , G03C1/73 , C08F236/20
CPC分类号: G03F7/0388 , C08F220/40 , C08F230/08 , C08F232/08 , G03F7/0758
摘要: The present invention relates to a directly photoimageable polymer composition (DPPC) and methods for its use in forming microelectronic and optoelectronic devices. Such DPPC encompasses a polymer having at least one norbornene-type repeat unit having a pendant silyl containing radical and at least one norbornene-type repeat unit having an acrylate containing radical.
摘要翻译: 本发明涉及直接可光成像的聚合物组合物(DPPC)及其用于形成微电子和光电器件的方法。 这样的DPPC包括具有至少一个降冰片烯型重复单元的聚合物,该单体具有含甲酰基侧基和至少一个具有含丙烯酸酯基团的降冰片烯型重复单元。
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公开(公告)号:US08053515B2
公开(公告)日:2011-11-08
申请号:US11949328
申请日:2007-12-03
申请人: Edmund Elce , Andrew Bell , Brian Knapp , Hendra Ng , Larry F. Rhodes , Robert Shick , Wei Zhang , William DiMenna , Saikumar Jayaraman , Jianyong Jin , Rajesh Raja Puthenkovilakom , Ramakrishna Ravikiran , Xiaoming Wu , Etsu Takeuchi
发明人: Edmund Elce , Andrew Bell , Brian Knapp , Hendra Ng , Larry F. Rhodes , Robert Shick , Wei Zhang , William DiMenna , Saikumar Jayaraman , Jianyong Jin , Rajesh Raja Puthenkovilakom , Ramakrishna Ravikiran , Xiaoming Wu , Etsu Takeuchi
IPC分类号: C08G63/60
CPC分类号: C08G61/04 , C08F232/08 , G03F7/0388
摘要: A polymer includes a first type of repeat unit represented by Formula I: where X is selected from —CH2—, —CH2—CH2—, or —O—; m is an integer from 0 to about 5; and where for the first type of repeat unit one of R1, R2, R3, and R4 is one of a maleimide containing group and for the second type of repeat unit one of R1, R2, R3, and R4 is a hindered aromatic group, a C8 or greater alkyl group, a C4 or greater halohydrocarbyl or perhalocarbyl group, a C7 or greater aralkyl group, or a heteroatom hydrocarbyl or halohydrocarbyl group.
摘要翻译: 聚合物包括由式I表示的第一类型的重复单元:其中X选自-CH 2 - , - CH 2 -CH 2 - 或-O-; m是0至约5的整数; 并且对于第一类型的重复单元,R 1,R 2,R 3和R 4中的一个是含马来酰亚胺基团之一,并且对于第二类型的重复单元,R 1,R 2,R 3和R 4中的一个是受阻芳族基团, C8或更大的烷基,C4或更大的卤代烃基或全卤代羰基,C7或更高的芳烷基或杂原子烃基或卤代烃基。
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公开(公告)号:US07851575B2
公开(公告)日:2010-12-14
申请号:US11983505
申请日:2007-11-09
申请人: Ramakrishna Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Robert John Duff , Saikumar Jayaraman , John-Henry Lipian
发明人: Ramakrishna Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Robert John Duff , Saikumar Jayaraman , John-Henry Lipian
IPC分类号: C08F30/02
CPC分类号: C08J5/2256 , C08G61/06 , C08J2385/04 , H01B1/122 , H01M4/8605 , H01M8/1023 , H01M8/1025 , H01M8/1032 , H01M8/1039
摘要: A polymer comprising polycyclic repeating units having recurring ion conducting groups and optional crosslinkable groups is disclosed. The present invention provides the capability of tailoring polymers to impart unique properties to membranes fabricated from the polymers. Membranes comprising the polymers and methods for preparing the membranes and their use in ion conducting membranes, particularly in fuel cells, are also provided.
摘要翻译: 公开了包含具有重复离子导电基团和任选的可交联基团的多环重复单元的聚合物。 本发明提供了定制聚合物以赋予由聚合物制造的膜独特的性能的能力。 还提供了包含聚合物的膜和用于制备膜的方法及其在离子传导膜中的用途,特别是在燃料电池中。
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公开(公告)号:US07022790B2
公开(公告)日:2006-04-04
申请号:US10465511
申请日:2003-06-19
申请人: Edmund Elce , Takashi Hirano , Jeffrey C. Krotine, Jr. , Larry F. Rhodes , Brian L. Goodall , SaiKumar Jayaraman , W. Chris McDougall , Shenliang Sun
发明人: Edmund Elce , Takashi Hirano , Jeffrey C. Krotine, Jr. , Larry F. Rhodes , Brian L. Goodall , SaiKumar Jayaraman , W. Chris McDougall , Shenliang Sun
IPC分类号: C08F10/00
CPC分类号: G03F7/0382 , C08G59/3218 , C08G61/02 , C08G61/06
摘要: A copolymer composition including a copolymer having repeat units of structural formula I: where X is selected from —CH2—, —CH2—CH2— and O; m is an integer from 0 to 5; and each occurrence of R1–R4 are independently selected from H; C1 to C25 linear, branched, and cyclic alkyl, aryl, aralkyl, alkaryl, alkenyl and alkynyl that can include one or more hetero atoms selected from O, N, and Si; a group that contains an epoxy functionality; —(CH2)nC(O)OR5; —(CH2)nC(O)OR6; —(CH2)nOR6; —(CH2)nOC(O)R6; —(CH2)nC(O)R6; —(CH2)nOC(O)OR6; and any combination of two of R1, R2, R3, and R4 linked together by a linking group. A portion of the repeat units having structural formula I contain at least one epoxy functional pendant group. The copolymer composition can be included with a material that photonically forms a catalyst in a photodefinable dielectric composition, which can be used to form a photodefinable layer on a substrate.
摘要翻译: 一种共聚物组合物,其包含具有结构式I的重复单元的共聚物:其中X选自-CH 2 - , - CH 2 -CH 2 > - 和O; m是0至5的整数; 并且每次出现的R 1 -R 4独立地选自H; C 1至C 25直链,支链和环状的烷基,芳基,芳烷基,烷芳基,烯基和炔基,其可以包括一个或多个选自O,N, 和Si; 含有环氧官能团的基团; - (CH 2)2 C(O)OR 5; - (CH 2)2 C(O)OR 6; - (CH 2 2)n - 或 - 6 - - (CH 2)n OC(O)R 6; - (CH 2 CH 2)n C(O)R 6; - (CH 2)n OC(O)OR 6; 并且R 1,R 2,R 3,R 4和R 4中的两个的任何组合通过 连接组。 具有结构式I的重复单元的一部分含有至少一个环氧官能侧基。 该共聚物组合物可以包含在可光致定影的电介质组合物中光子形成催化剂的材料,该组合物可用于在基底上形成光可定义层。
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