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公开(公告)号：US07851575B2
公开(公告)日：2010-12-14
申请号：US11983505
申请日：2007-11-09
申请人： Ramakrishna Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Robert John Duff , Saikumar Jayaraman , John-Henry Lipian
发明人： Ramakrishna Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Robert John Duff , Saikumar Jayaraman , John-Henry Lipian
IPC分类号： C08F30/02
CPC分类号： C08J5/2256 , C08G61/06 , C08J2385/04 , H01B1/122 , H01M4/8605 , H01M8/1023 , H01M8/1025 , H01M8/1032 , H01M8/1039
摘要： A polymer comprising polycyclic repeating units having recurring ion conducting groups and optional crosslinkable groups is disclosed. The present invention provides the capability of tailoring polymers to impart unique properties to membranes fabricated from the polymers. Membranes comprising the polymers and methods for preparing the membranes and their use in ion conducting membranes, particularly in fuel cells, are also provided.
摘要翻译： 公开了包含具有重复离子导电基团和任选的可交联基团的多环重复单元的聚合物。 本发明提供了定制聚合物以赋予由聚合物制造的膜独特的性能的能力。 还提供了包含聚合物的膜和用于制备膜的方法及其在离子传导膜中的用途，特别是在燃料电池中。
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公开(公告)号：US20080242750A1
公开(公告)日：2008-10-02
申请号：US11983505
申请日：2007-11-09
申请人： R. Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Robert John Duff , Saikumar Jayaraman , John-Henry Lipian
发明人： R. Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Robert John Duff , Saikumar Jayaraman , John-Henry Lipian
IPC分类号： B01J47/12
CPC分类号： C08J5/2256 , C08G61/06 , C08J2385/04 , H01B1/122 , H01M4/8605 , H01M8/1023 , H01M8/1025 , H01M8/1032 , H01M8/1039
摘要： A polymer comprising polycyclic repeating units having recurring ion conducting groups and optional crosslinkable groups is disclosed. The present invention provides the capability of tailoring polymers to impart unique properties to membranes fabricated from the polymers. Membranes comprising the polymers and methods for preparing the membranes and their use in ion conducting membranes, particularly in fuel cells, are also provided.
摘要翻译： 公开了包含具有重复离子导电基团和任选的可交联基团的多环重复单元的聚合物。 本发明提供了定制聚合物以赋予由聚合物制造的膜独特的性能的能力。 还提供了包含聚合物的膜和用于制备膜的方法及其在离子传导膜中的用途，特别是在燃料电池中。
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公开(公告)号：US07312292B2
公开(公告)日：2007-12-25
申请号：US10860876
申请日：2004-06-04
申请人： Ravi Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Saikumar Jayaraman , Robert John Duff , John-Henry Lipian
发明人： Ravi Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Saikumar Jayaraman , Robert John Duff , John-Henry Lipian
IPC分类号： C08F30/02
CPC分类号： C08J5/2256 , C08G61/06 , C08J2385/04 , H01B1/122 , H01M4/8605 , H01M8/1023 , H01M8/1025 , H01M8/1032 , H01M8/1039
摘要： A polymer comprising polycyclic repeating units having recurring ion conducting groups and optional crosslinkable groups is disclosed. The present invention provides the capability of tailoring polymers to impart unique properties to membranes fabricated from the polymers. Membranes comprising the polymers and methods for preparing the membranes and their use in ion conducting membranes, particularly in fuel cells, are also provided.
摘要翻译： 公开了包含具有重复离子导电基团和任选的可交联基团的多环重复单元的聚合物。 本发明提供了定制聚合物以赋予由聚合物制造的膜独特的性能的能力。 还提供了包含聚合物的膜和用于制备膜的方法及其在离子传导膜中的用途，特别是在燃料电池中。
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公开(公告)号：US20130012637A1
公开(公告)日：2013-01-10
申请号：US13636136
申请日：2011-03-21
申请人： Joachim C. Ritter , Joel M. Pollino , Michael T. Pottiger , Lakshmi Krishnamurthy , John C. Howe , Harry Vaughn Samuelson , Marios Avgousti , Zheng-Zheng Huang , Robert John Duff
发明人： Joachim C. Ritter , Joel M. Pollino , Michael T. Pottiger , Lakshmi Krishnamurthy , John C. Howe , Harry Vaughn Samuelson , Marios Avgousti , Zheng-Zheng Huang , Robert John Duff
摘要： An improved process for forming polyarylene sulfide fibers is provided. The process comprises forming at least one fiber from a polymer melt comprising a polyarylene sulfide and at least one tin additive comprising a branched tin(II) carboxylate. Using such a melt, the fiber forming continuity is improved compared to that of the native polyarylene sulfide melt processed under the same conditions.
摘要翻译： 提供了一种改进的形成聚芳硫醚纤维的方法。 该方法包括由包含聚芳硫醚的聚合物熔体和至少一种包含支化的（II）羧酸锡的锡添加剂形成至少一种纤维。 使用这样的熔体，与在相同条件下处理的天然聚芳硫醚熔体相比，纤维形成连续性得到改善。
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公开(公告)号：US20130011544A1
公开(公告)日：2013-01-10
申请号：US13636380
申请日：2011-03-16
申请人： Joel M. Pollino , Lakshmi Krishnamurthy , Joachim C. Ritter , Robert John Duff , Yefim Brun , Zheng-Zheng Zhuang , Zuohong Yin
发明人： Joel M. Pollino , Lakshmi Krishnamurthy , Joachim C. Ritter , Robert John Duff , Yefim Brun , Zheng-Zheng Zhuang , Zuohong Yin
摘要： A method for stabilizing a polymeric structure against thermo-oxidative degradation is described. A polymeric core structure is provided with a skin layer that contains a skin resin in which the skin resin at least partially envelops a portion of the core structure. The skin structure then provides a barrier that thereby stabilizes the portion of the structure that is enveloped. The skin resin is made from a treated polyarylene sulfide.
摘要翻译： 描述了一种稳定聚合物结构免受热氧化降解的方法。 聚合物芯结构设置有包含表皮树脂的表皮层，其中表皮树脂至少部分地包封芯结构的一部分。 皮肤结构然后提供了一个屏障，从而使被包封的结构的部分稳定。 皮肤树脂由经处理的聚芳硫醚制成。
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公开(公告)号：US20130009333A1
公开(公告)日：2013-01-10
申请号：US13635144
申请日：2011-03-17
申请人： Lakshmi Krishnamurthy , Zuohong Yin , Joachim C Ritter , Joel M Pollino , Michael T Pottiger , John C Howe , David Matthews Laura, JR. , Harry Vaughn Samuelson , Robert John Duff , Zheng-Zheng Huang
发明人： Lakshmi Krishnamurthy , Zuohong Yin , Joachim C Ritter , Joel M Pollino , Michael T Pottiger , John C Howe , David Matthews Laura, JR. , Harry Vaughn Samuelson , Robert John Duff , Zheng-Zheng Huang
IPC分类号： D04H3/16
摘要： A nonwoven web comprising bicomponent fibers. The fibers have continuous phases each of a first polyarylene sulfide (PAS) component and a polymer component. The polymer component may also be a second polyarylene sulfide. The first polyarylene sulfide component contains a tin or a zinc additive or both, and the first polyarylene sulfide component of any given fiber is at least partially exposed to the external surface of that fiber.
摘要翻译： 包含双组分纤维的非织造纤维网。 纤维具有各自具有第一聚芳硫醚（PAS）组分和聚合物组分的连续相。 聚合物组分也可以是第二聚芳硫醚。 第一聚芳硫醚组分含有锡或锌添加剂或两者，并且任何给定纤维的第一聚芳硫醚组分至少部分地暴露于该纤维的外表面。
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公开(公告)号：US20130012671A1
公开(公告)日：2013-01-10
申请号：US13634697
申请日：2011-03-22
IPC分类号： C08G75/16
摘要： A method for accelerating the curing of a polyarylene sulfide. The polyarylene sulfide is blended with a cure accelerator to form a mixture where the weight percentage of accelerator is between 0.2% and 15.0% of the total weight of the blend. The mixture is cured at 320° C. or above for at least 20 minutes. The cure accelerator is a compound selected from the group consisting of ionomers, hindered phenols, polyhydric alcohols, polycarboxylates, and mixtures of the foregoing.
摘要翻译： 一种加速聚芳硫醚固化的方法。 将聚芳硫醚与固化促进剂混合以形成混合物，其中促进剂的重量百分数在共混物的总重量的0.2％至15.0％之间。 混合物在320℃以上固化至少20分钟。 固化促进剂是选自离聚物，受阻酚，多元醇，多羧酸盐以及前述物质的混合物的化合物。
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公开(公告)号：US20130012092A1
公开(公告)日：2013-01-10
申请号：US13636351
申请日：2011-03-22
申请人： Joel M. Pollino , Lakshmi Krishnamurthy , Joachim C. Ritter , Robert John Duff , Yefim Brun , Zheng-Zheng Huang , Zuohong Yin
发明人： Joel M. Pollino , Lakshmi Krishnamurthy , Joachim C. Ritter , Robert John Duff , Yefim Brun , Zheng-Zheng Huang , Zuohong Yin
IPC分类号： D04H13/00
CPC分类号： D01F8/16 , D01F1/10 , D04H1/541 , Y10T442/637
摘要： A nonwoven web comprising bicomponent fibers. The fibers have continuous phases each of a first polyarylene sulfide (PAS) component and a polymer component. The polymer component may also be a second polyarylene sulfide. The first polyarylene sulfide component contains a tin or a zinc additive or both, and the first polyarylene sulfide component of any given fiber is at least partially exposed to the external surface of that fiber.
摘要翻译： 包含双组分纤维的非织造纤维网。 纤维具有各自具有第一聚芳硫醚（PAS）组分和聚合物组分的连续相。 聚合物组分也可以是第二聚芳硫醚。 第一聚芳硫醚组分含有锡或锌添加剂或两者，并且任何给定纤维的第一聚芳硫醚组分至少部分地暴露于该纤维的外表面。
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