Continuous preparation for polyester
    1.
    发明授权
    Continuous preparation for polyester 有权
    连续准备聚酯

    公开(公告)号:US09527953B2

    公开(公告)日:2016-12-27

    申请号:US14083936

    申请日:2013-11-19

    CPC classification number: C08G63/78 C08G63/6854 C08L67/02

    Abstract: A process of continuous production for polyester, comprising continuously supplying an esterification or transesterification product comprising ester oligomers with an acid value of less than 100 meq/kg to a liquid phase polymerization reactor, wherein the esterification or transesterification product is produced by esterification or transesterification of a polycarboxylic acid or an alkyl ester thereof and a polyhydric alcohol; and performing a liquid-phase polymerization at a temperature of 200 to 270° C. and at a pressure of 0 to 5 torr in a liquid-phase polymerization reactor to produce the polyester with an intrinsic viscosity of 0.4 dl/g or higher.

    Abstract translation: 一种连续生产聚酯的方法,包括将含有小于100meq / kg的酸值的酯低聚物的酯化或酯交换产物连续供给到液相聚合反应器中,其中酯化或酯交换反应产物通过酯化或酯交换反应 多元羧酸或其烷基酯和多元醇; 在液相聚合反应器中,在200〜270℃,0〜5托的压力下进行液相聚合,得到特性粘度为0.4dl / g以上的聚酯。

    METHOD FOR PREPARING UNSATURATED CARBOXYLIC ACID
    3.
    发明申请
    METHOD FOR PREPARING UNSATURATED CARBOXYLIC ACID 有权
    制备不饱和羧酸的方法

    公开(公告)号:US20140171681A1

    公开(公告)日:2014-06-19

    申请号:US14098154

    申请日:2013-12-05

    CPC classification number: C07C51/347 C07C51/377 C07C59/01 C07C57/04

    Abstract: A method for preparing an unsaturated carboxylic acid comprising (a) preparing an aqueous solution comprising an ammonium salt of hydroxycarboxylic acid and a salt of inorganic acid; (b) contacting the aqueous solution with a cation exchange resin to prepare a conversion aqueous solution comprising a hydroxycarboxylic acid and an inorganic acid; and (c) dehydrating the hydroxycarboxylic acid using the inorganic acid as a catalyst is provided.

    Abstract translation: 一种制备不饱和羧酸的方法,包括(a)制备包含羟基羧酸的铵盐和无机酸的盐的水溶液; (b)使所述水溶液与阳离子交换树脂接触以制备包含羟基羧酸和无机酸的转化水溶液; 和(c)使用无机酸作为催化剂使羟基羧酸脱水。

    Method for preparing unsaturated carboxylic acid
    5.
    发明授权
    Method for preparing unsaturated carboxylic acid 有权
    不饱和羧酸的制备方法

    公开(公告)号:US09181170B2

    公开(公告)日:2015-11-10

    申请号:US14098154

    申请日:2013-12-05

    CPC classification number: C07C51/347 C07C51/377 C07C59/01 C07C57/04

    Abstract: A method for preparing an unsaturated carboxylic acid comprising (a) preparing an aqueous solution comprising an ammonium salt of hydroxycarboxylic acid and a salt of inorganic acid; (b) contacting the aqueous solution with a cation exchange resin to prepare a conversion aqueous solution comprising a hydroxycarboxylic acid and an inorganic acid; and (c) dehydrating the hydroxycarboxylic acid using the inorganic acid as a catalyst is provided.

    Abstract translation: 一种制备不饱和羧酸的方法,包括(a)制备包含羟基羧酸的铵盐和无机酸的盐的水溶液; (b)使所述水溶液与阳离子交换树脂接触以制备包含羟基羧酸和无机酸的转化水溶液; 和(c)使用无机酸作为催化剂使羟基羧酸脱水。

    Method of preparing furfural compounds
    10.
    发明授权
    Method of preparing furfural compounds 有权
    糠醛化合物的制备方法

    公开(公告)号:US09469619B2

    公开(公告)日:2016-10-18

    申请号:US14066541

    申请日:2013-10-29

    CPC classification number: C07D307/46 C07D307/48 C07D307/50

    Abstract: Provided is a two-step method of producing a compound of chemical formula 1 in the presence of an alcohol solvent and a Group 3B metal catalyst or a salt thereof, comprising a first step comprising alkylation or isomerization of an aldohexose-containing substrate to obtain an intermediate, and a second step comprising dehydration of the intermediate to produce a compound of chemical formula 1. Preferably, additional solvent and/or catalyst are not added in the second step.

    Abstract translation: 本发明提供了在醇溶剂和3B族金属催化剂或其盐的存在下制备化学式1的化合物的两步法,该方法包括第一步骤,包括含醛糖基底物的烷基化或异构化以获得 中间体和第二步,包括中间体的脱水以产生化学式1的化合物。优选在第二步中不加入另外的溶剂和/或催化剂。

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