公开(公告)号：US20160319099A1

公开(公告)日：2016-11-03

申请号：US15107655

申请日：2014-12-19

Applicant: TORAY INDUSTRIES, INC.

Inventor： Keiko ICHINOSE ,  Hidenobu TAKAO ,  Daisuke YAMAMOTO ,  Koji YAMAUCHI

IPC: C08K5/098 ,  C08J5/18

CPC classification number: C08K5/098 ,  C08J5/18 ,  C08J2381/04 ,  C08L81/02

Abstract: A polyarylene sulfide resin composition including a polyarylene sulfide (A) and an alkaline earth metal organic carboxylate (B) in an amount of 0.001 to 10 mol % based on the formula —(Ar—S)—, a repeating unit of polyarylene sulfide, wherein the polyarylene sulfide (A) has a weight average molecular weight of 10,000 or more and a weight reduction during heating that satisfies the equation ΔWr=(W1-W2)/W1×100≦0.18 (%), wherein ΔWr is a weight reduction ratio (%) determined by a thermogravimetric analysis performed in a non-oxidizing atmosphere under normal pressure at a temperature rise rate of 20° C./min from 50° C. to any temperature equal to or higher than 330° C., wherein W1 is a sample weight at 100° C., and W2 is a sample weight at 330° C.

Abstract translation: 包含聚芳硫醚（A）和碱土金属有机羧酸酯（B）的聚芳硫醚树脂组合物的量为0.001〜10摩尔％，基于式 - （Ar-S） - ，聚芳硫醚的重复单元， 其中所述聚芳硫醚（A）的重均分子量为10,000以上，加热时的重量减少满足式ΔWr=（W1-W2）/ W1×100≤0.18（％），其中ΔWr为重量减少 通过在非氧化性气氛中在常压下以20℃/分钟的升温速率从50℃至任何等于或高于330℃的温度进行的热重分析测定的比率（％），其中 W1是100℃的样品重量，W2是330℃下的样品重量。

公开(公告)号：US20160009868A1

公开(公告)日：2016-01-14

申请号：US14770382

申请日：2014-03-05

Applicant: TORAY INDUSTRIES, INC.

Inventor： Keiko ICHINOSE ,  Makito YOKOE ,  Daisuke YAMAMOTO ,  Koji YAMAUCHI ,  Kohei YAMASHITA

IPC: C08G81/00 ,  C08G69/14 ,  C08G75/14

CPC classification number: C08G81/00 ,  C08G69/14 ,  C08G69/42 ,  C08G69/48 ,  C08G75/14 ,  C08G2261/126 ,  C08G2650/40 ,  C08L71/00 ,  C08L81/02

Abstract: A block comprised of a copolymer is obtained by ring-opening polymerization of a cyclic polyarylene sulfide, so that a block copolymer is produced to have a maximum peak molecular weight measured by size exclusion chromatography (SEC) in a range of not less than 2,000 and less than 2,000,000 and have a unimodal molecular weight distribution in this range.

Abstract translation: 通过环状聚芳硫醚的开环聚合得到共聚物的嵌段，制造嵌段共聚物，使其具有通过尺寸排阻色谱法（SEC）测定的最大峰分子量为2000以上的范围， 小于200万，在此范围内具有单峰分子量分布。

公开(公告)号：US20250092208A1

公开(公告)日：2025-03-20

申请号：US18729319

申请日：2023-02-08

Applicant: Toray Industries, Inc.

Inventor： Taisuke HIRANO ,  Masato AKAHIRA ,  Koji YAMAUCHI

IPC: C08J5/18 ,  C08G65/40

Abstract: The purpose of the present invention is to provide a polyether nitrile film which has excellent processability and high heat resistance, and which exhibits excellent stretchability before being stretched, while having high crystallinity after being stretched. In order to achieve the above-described purpose, a polyether nitrile film according to the present invention has the following configuration. The present invention provides a polyether nitrile film which is a molded film formed from a polyether nitrile that contains N repeating units represented by formula (I) and M repeating units represented by formula (II), with N and M being integers that satisfy the relational expression 0.80≤(N/(N+M))

公开(公告)号：US20200062704A1

公开(公告)日：2020-02-27

申请号：US16466230

申请日：2017-12-05

Applicant: TORAY INDUSTRIES, INC.

Inventor： Daijiro TSUKAMOTO ,  Masateru ITO ,  Katsushige YAMADA ,  Masato AKAHIRA ,  Daisuke YAMAMOTO ,  Koji YAMAUCHI

IPC: C07D201/08

Abstract: The present invention is a method of producing ε-caprolactam through adipamide as an intermediate, and characteristically includes a lactamization step of reacting adipamide, formed from a material compound, with hydrogen and ammonia in the presence of a catalyst containing: a metal oxide mainly containing an oxide(s) of one or more metallic elements selected from the group consisting of metallic elements of group 5 and groups 7 to 14 in the 4th to 6th periods of the periodic table; and a metal and/or a metal compound having a hydrogenation ability. The method can increase the selectivity of ε-caprolactam.

公开(公告)号：US20170320819A1

公开(公告)日：2017-11-09

申请号：US15523120

申请日：2015-10-27

Applicant: TORAY INDUSTRIES, INC.

Inventor： Masateru ITO ,  Daijiro TSUKAMOTO ,  Kenji KAWAMURA ,  Kohei YAMASHITA ,  Masato AKAHIRA ,  Katsushige YAMADA ,  Koji YAMAUCHI

IPC: C07D201/08 ,  C08G69/14 ,  B01J23/44

CPC classification number: C07D201/08 ,  B01J23/44 ,  C07B61/00 ,  C07D223/10 ,  C08G69/14 ,  Y02P20/52

Abstract: A method for selective production of ε-caprolactam, wherein a substance inducible from a biomass resource is used as a material; the reaction process is short; ammonium sulfate is not produced as a by-product; and production of by-products is suppressed; is disclosed. The method for producing ε-caprolactam comprises the step of reacting a particular compound inducible from a biomass resource, such as α-hydromuconic acid, 3-hydroxyadipic acid, or 3-hydroxyadipic acid-3,6-lactone, or a salt thereof with hydrogen or ammonia.