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1.发明授权Process to make long chain branched (LCB), block, or interconnected copolymers of ethylene 有权制备乙烯的长链支化（LCB），嵌段或互连共聚物的方法公开(公告)号：US08722817B2
公开(公告)日：2014-05-13
申请号：US12959768
申请日：2010-12-03
申请人： Teresa P. Karjala , Sean W. Ewart , Christopher R. Eddy , Alfred E. Vigil, Jr. , Mehmet Demirors , Sarat Munjal , Wallace W. Yau
发明人： Teresa P. Karjala , Sean W. Ewart , Christopher R. Eddy , Alfred E. Vigil, Jr. , Mehmet Demirors , Sarat Munjal , Wallace W. Yau
CPC分类号： C08F110/02 , C08F10/02 , C08F210/16 , C08F2410/04 , C08F4/64193 , C08F2/001 , C08F4/32 , C08F2500/09 , C08F2500/01 , C08F2500/02 , C08F2500/20 , C08F2500/04
摘要： A process is taught, comprising polymerizing ethylene in the presence of a catalyst to form a crystalline ethylene-based polymer having a crystallinity of at least 50% as determined by DSC Crystallinity in a first reactor or a first part of a multi-part reactor and reacting the crystalline ethylene-based polymer with additional ethylene in the presence of a free-radical initiator to form an ethylenic polymer in at least one other reactor or a later part of a multi-part reactor.
摘要翻译： 教导了一种方法，其包括在催化剂存在下聚合乙烯以形成结晶度为至少50％的结晶乙烯基聚合物，如通过DSC结晶度在第一反应器或多部分反应器的第一部分中测定的， 在结晶乙烯基聚合物与另外的乙烯在自由基引发剂存在下反应，以在至少一个其它反应器或多部分反应器的后续部分中形成乙烯聚合物。
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2.发明申请PROCESS TO MAKE LONG CHAIN BRANCHED (LCB), BLOCK, OR INTERCONNECTED COPOLYMERS OF ETHYLENE 有权制备长链分支（LCB），嵌段或互连的乙烯共聚物的方法公开(公告)号：US20110130533A1
公开(公告)日：2011-06-02
申请号：US12959768
申请日：2010-12-03
申请人： Teresa P. Karjala , Sean W. Ewart , Christopher R. Eddy , Alfred E. Vigil, JR. , Mehmet Demirors , Sarat Munjal , Wallace W. Yau
发明人： Teresa P. Karjala , Sean W. Ewart , Christopher R. Eddy , Alfred E. Vigil, JR. , Mehmet Demirors , Sarat Munjal , Wallace W. Yau
IPC分类号： C08F4/76
CPC分类号： C08F110/02 , C08F10/02 , C08F210/16 , C08F2410/04 , C08F4/64193 , C08F2/001 , C08F4/32 , C08F2500/09 , C08F2500/01 , C08F2500/02 , C08F2500/20 , C08F2500/04
摘要： A process is taught, comprising polymerizing ethylene in the presence of a catalyst to form a crystalline ethylene-based polymer having a crystallinity of at least 50% as determined by DSC Crystallinity in a first reactor or a first part of a multi-part reactor and reacting the crystalline ethylene-based polymer with additional ethylene in the presence of a free-radical initiator to form an ethylenic polymer in at least one other reactor or a later part of a multi-part reactor.
摘要翻译： 教导了一种方法，其包括在催化剂存在下聚合乙烯以形成结晶度为至少50％的结晶乙烯基聚合物，如通过DSC结晶度在第一反应器或多部分反应器的第一部分中测定的， 在结晶乙烯基聚合物与另外的乙烯在自由基引发剂存在下反应，以在至少一个其它反应器或多部分反应器的后续部分中形成乙烯聚合物。
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3.发明申请PROCESS TO MAKE LONG CHAIN BRANCHED (LCB), BLOCK, OR INTERCONNECTED COPOLYMERS OF ETHYLENE 审中-公开制备长链分支（LCB），嵌段或互连的乙烯共聚物的方法公开(公告)号：US20100311927A1
公开(公告)日：2010-12-09
申请号：US12792054
申请日：2010-06-02
申请人： Teresa P. Karjala , Sean W. Ewart , Christopher R. Eddy , Alfred E. Vigil , Mehmet Demirors , Sarat Munjal , Wallace W. Yau
发明人： Teresa P. Karjala , Sean W. Ewart , Christopher R. Eddy , Alfred E. Vigil , Mehmet Demirors , Sarat Munjal , Wallace W. Yau
IPC分类号： C08F4/76
CPC分类号： C08F110/02 , C08F10/02 , C08F210/16 , C08F295/00 , C08F2410/04 , C08F4/64193 , C08F2/001 , C08F4/16 , C08F2500/09
摘要： A process is taught, comprising polymerizing ethylene in the presence of a catalyst to form a crystalline ethylene-based polymer having a crystallinity of at least 50% as determined by DSC Crystallinity in a first reactor or a first part of a multi-part reactor and reacting the crystalline ethylene-based polymer with additional ethylene in the presence of a free-radical initiator to form an ethylenic polymer in at least one other reactor or a later part of a multi-part reactor.
摘要翻译： 教导了一种方法，其包括在催化剂存在下聚合乙烯以形成结晶度为至少50％的结晶乙烯基聚合物，如通过DSC结晶度在第一反应器或多部分反应器的第一部分中测定的， 在结晶乙烯基聚合物与另外的乙烯在自由基引发剂存在下反应，以在至少一个其它反应器或多部分反应器的后续部分中形成乙烯聚合物。
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4.发明申请HIGH PRESSURE LOW DENSITY POLYETHYLENE RESINS WITH IMPROVED OPTICAL PROPERTIES PRODUCED THROUGH USE OF HIGHLY ACTIVE CHAIN TRANSFER AGENTS 有权具有通过使用高活性链转移剂生产的改进的光学性能的高压低密度聚乙烯树脂公开(公告)号：US20110178253A1
公开(公告)日：2011-07-21
申请号：US13063960
申请日：2009-10-01
申请人： Teresa P. Karjala , Christopher R. Eddy , Mehmet Demirors , Wallace W. Yau , Sarat Munjal , Stefan Hinrichs , Jian Wang , Otto J. Berbee , Werner Zschoch , Cornelis J. Hosman , Lonnie G. Hazlitt
发明人： Teresa P. Karjala , Christopher R. Eddy , Mehmet Demirors , Wallace W. Yau , Sarat Munjal , Stefan Hinrichs , Jian Wang , Otto J. Berbee , Werner Zschoch , Cornelis J. Hosman , Lonnie G. Hazlitt
IPC分类号： C08F110/02 , C08F2/01 , C08F2/38
CPC分类号： C08F10/02 , C08F110/02 , Y10S526/917 , C08F2/01 , C08F2/001 , C08F2/38 , C08F2/00 , C08F2500/08 , C08F2500/12 , C08F2500/20 , C08F2500/04
摘要： Disclosed is an ethylene-based polymer with a density from about 0.90 to about 0.94 in grams per cubic centimeter, with a molecular weight distribution (Mw/Mn) from about 2 to about 30, a melt index (I2) from about 0.1 to about 50 grams per 10 minutes, and further comprising sulfur from about 5 to about 4000 parts per million. The amount of sulfur is also determined based upon the total weight of the ethylene-based polymer. Also disclosed is process for making an ethylene-based polymer which includes the steps of splitting a process fluid for delivery into a tubular reactor; feeding an upstream process feed stream into a first reaction zone and at least one downstream process feed stream into at least one other reaction zone, where the process fluid has an average velocity of at least 10 meters per second; and initiating a free-radical polymerization reaction.
摘要翻译： 公开了密度为约0.90至约0.94（克/立方厘米）的乙烯基聚合物，分子量分布（Mw / Mn）为约2至约30，熔体指数（I 2）为约0.1至约 50克/ 10分钟，还含有约5至约4000ppm的硫。 硫的量也基于乙烯类聚合物的总重量来确定。 还公开了制备基于乙烯的聚合物的方法，其包括将工艺流体分离成管式反应器的步骤; 将上游工艺进料流输送到第一反应区和至少一个下游工艺进料流进入至少一个其它反应区，其中所述工艺流体具有至少10米/秒的平均速度; 并引发自由基聚合反应。
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5.发明授权Long chain branched (LCB), block or interconnected copolymers of ethylene in combination with one other polymer 有权长链支化（LCB），乙烯与另一种聚合物组合的嵌段或互连共聚物公开(公告)号：US08202958B2
公开(公告)日：2012-06-19
申请号：US12402789
申请日：2009-03-12
申请人： Mehmet Demirors , Teresa P. Karjala , Christopher R. Eddy , Lonnie G. Hazlitt , Pak-Meng Cham , Sarat Munjal , Wallace W. Yau
发明人： Mehmet Demirors , Teresa P. Karjala , Christopher R. Eddy , Lonnie G. Hazlitt , Pak-Meng Cham , Sarat Munjal , Wallace W. Yau
CPC分类号： C08F255/02 , C08F110/02 , C08F255/00 , C08F297/08 , C08F297/083 , C08L23/0815 , C08L51/06 , C08L53/00 , C08L2666/02 , C08F2500/09 , C08F2500/12 , C08F2500/20 , C08F2500/17 , C08F2500/07 , C08F2500/19
摘要： An ethylenic polymer comprising amyl groups from about 0.1 to about 2.0 units per 1000 carbon atoms as determined by Nuclear Magnetic Resonance and both a peak melting temperature, Tm, in ° C., and a heat of fusion, Hf, in J/g, as determined by DSC Crystallinity, where the numerical values of Tm and Hf correspond to the relationship Tm≧(0.2143*Hf)+79.643. An ethylenic polymer comprising at least one preparative TREF fraction that elutes at 95° C. or greater using a Preparative Temperature Rising Elution Fractionation method, where at least one preparative TREF fraction that elutes at 95° C. or greater has a gpcBR value greater than 0.05 and less than 5 as determined by gpcBR Branching Index by 3D-GPC, and where at least 5% of the ethylenic polymer elutes at a temperature of 95° C. or greater based upon the total weight of the ethylenic polymer.
摘要翻译： 包含通过核磁共振测定的约0.1至约2.0单位/ 1000个碳原子的乙烯基聚合物，峰值熔融温度Tm，℃，熔融热，Hf / J， 通过DSC结晶度测定，其中Tm和Hf的数值对应于Tm≥（0.2143×Hf）+79.643的关系。 包含至少一种使用制备型升温洗脱分级方法在95℃或更高洗脱的制备性TREF级分的乙烯性聚合物，其中至少一种在95℃或更高洗脱的制备性TREF级分的gpcBR值大于 通过3D-GPC通过gpcBR分枝指数测定的0.05和小于5，并且其中至少5％的乙烯类聚合物在基于乙烯类聚合物的总重量的95℃或更高的温度下洗脱。
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6.发明申请LONG CHAIN BRANCHED (LCB), BLOCK OR INTERCONNECTED COPOLYMERS OF ETHYLENE IN COMBINATION WITH ONE OTHER POLYMER 审中-公开长链分支（LCB），乙烯与一种其他聚合物组合的嵌段或互连共聚物公开(公告)号：US20110021713A1
公开(公告)日：2011-01-27
申请号：US12918090
申请日：2009-03-12
申请人： Mehmet Demirors , Teresa P. Karjala , Christopher R. Eddy , Lonnie G. Hazlitt , Pak-Meng Cham , Sarat Munjal , Wallace W. Yau
发明人： Mehmet Demirors , Teresa P. Karjala , Christopher R. Eddy , Lonnie G. Hazlitt , Pak-Meng Cham , Sarat Munjal , Wallace W. Yau
IPC分类号： C08F255/02 , C08F110/14
CPC分类号： C08F255/02 , C08F110/02 , C08F255/00 , C08F297/08 , C08F297/083 , C08L23/0815 , C08L51/06 , C08L53/00 , C08L2666/02 , C08F2500/09 , C08F2500/12 , C08F2500/20 , C08F2500/17 , C08F2500/07 , C08F2500/19
摘要： An ethylenic polymer comprising amyl groups from about 0.1 to about 2.0 units per 1000 carbon atoms as determined by Nuclear Magnetic Resonance and both a peak melting temperature, Tm, in ° C., and a heat of fusion, Hf, in J/g, as determined by DSC Crystallinity, where the numerical values of Tm and Hf correspond to the relationship Tm>(0.2143*Hf)+79.643. An ethylenic polymer comprising at least one preparative TREF fraction that elutes at 95° C. or greater using a Preparative Temperature Rising Elution Fractionation method, where at least one preparative TREF fraction that elutes at 95° C. or greater has a gpcBR value greater than 0.05 and less than 5 as determined by gpcBR Branching Index by 3D-GPC, and where at least 5% of the ethylenic polymer elutes at a temperature of 95° C. or greater based upon the total weight of the ethylenic polymer.
摘要翻译： 包含通过核磁共振测定的约0.1至约2.0单位/ 1000个碳原子的乙烯基聚合物，峰值熔融温度Tm，℃，熔融热，Hf / J， 通过DSC结晶度测定，其中Tm和Hf的数值对应于Tm>（0.2143×Hf）+79.643的关系。 包含至少一种使用制备型升温洗脱分级方法在95℃或更高洗脱的制备性TREF级分的乙烯性聚合物，其中至少一种在95℃或更高洗脱的制备性TREF级分的gpcBR值大于 通过3D-GPC通过gpcBR分枝指数测定的0.05和小于5，并且其中至少5％的乙烯类聚合物在基于乙烯类聚合物的总重量的95℃或更高的温度下洗脱。
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7.发明授权High pressure low density polyethylene resins with improved optical properties produced through use of highly active chain transfer agents 有权通过使用高活性链转移剂生产出具有改善的光学性能的高压低密度聚乙烯树脂公开(公告)号：US08415442B2
公开(公告)日：2013-04-09
申请号：US13063960
申请日：2009-10-01
申请人： Teresa P. Karjala , Christopher R. Eddy , Mehmet Demirors , Wallace W. Yau , Sarat Munjal , Stefan Hinrichs , Jian Wang , Otto J. Berbee , Werner Zschoch , Cornelis J. Hosman , Lonnie G. Hazlitt
发明人： Teresa P. Karjala , Christopher R. Eddy , Mehmet Demirors , Wallace W. Yau , Sarat Munjal , Stefan Hinrichs , Jian Wang , Otto J. Berbee , Werner Zschoch , Cornelis J. Hosman , Lonnie G. Hazlitt
CPC分类号： C08F10/02 , C08F110/02 , Y10S526/917 , C08F2/01 , C08F2/001 , C08F2/38 , C08F2/00 , C08F2500/08 , C08F2500/12 , C08F2500/20 , C08F2500/04
摘要： Disclosed is an ethylene-based polymer with a density from about 0.90 to about 0.94 in grams per cubic centimeter, with a molecular weight distribution (Mw/Mn) from about 2 to about 30, a melt index (I2) from about 0.1 to about 50 grams per 10 minutes, and further comprising sulfur from about 5 to about 4000 parts per million. The amount of sulfur is also determined based upon the total weight of the ethylene-based polymer. Also disclosed is process for making an ethylene-based polymer which includes the steps of splitting a process fluid for delivery into a tubular reactor; feeding an upstream process feed stream into a first reaction zone and at least one downstream process feed stream into at least one other reaction zone, where the process fluid has an average velocity of at least 10 meters per second; and initiating a free-radical polymerization reaction.
摘要翻译： 公开了密度为约0.90至约0.94（克/立方厘米）的乙烯基聚合物，分子量分布（Mw / Mn）为约2至约30，熔体指数（I 2）为约0.1至约 50克/ 10分钟，还含有约5至约4000ppm的硫。 硫的量也基于乙烯类聚合物的总重量来确定。 还公开了制备基于乙烯的聚合物的方法，其包括将工艺流体分离成管式反应器的步骤; 将上游工艺进料流输送到第一反应区和至少一个下游工艺进料流进入至少一个其它反应区，其中所述工艺流体具有至少10米/秒的平均速度; 并引发自由基聚合反应。
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8.发明申请LONG CHAIN BRANCHED (LCB), BLOCK, OR INTERCONNECTED COPOLYMERS OF ETHYLENE IN COMBINATION WITH ONE OTHER POLYMER 有权长链分支（LCB），乙烯与一种其他聚合物组合的嵌段或互连共聚物公开(公告)号：US20120245287A1
公开(公告)日：2012-09-27
申请号：US13472619
申请日：2012-05-16
申请人： Mehmet Demirors , Teresa P. Karjala , Christopher R. Eddy , Lonnie G. Hazlitt , Pak-Meng Cham , Sarat Munjal , Wallace W. Yau
发明人： Mehmet Demirors , Teresa P. Karjala , Christopher R. Eddy , Lonnie G. Hazlitt , Pak-Meng Cham , Sarat Munjal , Wallace W. Yau
IPC分类号： C08F110/02 , C08F2/01
CPC分类号： C08F255/02 , C08F110/02 , C08F255/00 , C08F297/08 , C08F297/083 , C08L23/0815 , C08L51/06 , C08L53/00 , C08L2666/02 , C08F2500/09 , C08F2500/12 , C08F2500/20 , C08F2500/17 , C08F2500/07 , C08F2500/19
摘要： An ethylenic polymer comprising amyl groups from about 0.1 to about 2.0 units per 1000 carbon atoms as determined by Nuclear Magnetic Resonance and both a peak melting temperature, Tm, in ° C., and a heat of fusion, Hf, in J/g, as determined by DSC Crystallinity, where the numerical values of Tm and Hf correspond to the relationship Tm≧(0.2143*Hf)+79.643. An ethylenic polymer comprising at least one preparative TREF fraction that elutes at 95° C. or greater using a Preparative Temperature Rising Elution Fractionation method, where at least one preparative TREF fraction that elutes at 95° C. or greater has a gpcBR value greater than 0.05 and less than 5 as determined by gpcBR Branching Index by 3D-GPC, and where at least 5% of the ethylenic polymer elutes at a temperature of 95° C. or greater based upon the total weight of the ethylenic polymer.
摘要翻译： 包含通过核磁共振测定的约0.1至约2.0单位/ 1000个碳原子的乙烯基聚合物，峰值熔融温度Tm，℃，熔融热，Hf / J， 通过DSC结晶度测定，其中Tm和Hf的数值对应于Tm≥（0.2143×Hf）+79.643的关系。 包含至少一种使用制备型升温洗脱分级方法在95℃或更高洗脱的制备性TREF级分的乙烯性聚合物，其中至少一种在95℃或更高洗脱的制备性TREF级分的gpcBR值大于 通过3D-GPC通过gpcBR分枝指数测定的0.05和小于5，并且其中至少5％的乙烯类聚合物在基于乙烯类聚合物的总重量的95℃或更高的温度下洗脱。
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9.发明授权Long chain branched (LCB), block, or interconnected copolymers of ethylene in combination with one other polymer 有权乙烯与一种其它聚合物组合的长链支化（LCB），嵌段或互连共聚物公开(公告)号：US08541519B2
公开(公告)日：2013-09-24
申请号：US13472619
申请日：2012-05-16
申请人： Mehmet Demirors , Teresa P. Karjala , Christopher R. Eddy , Lonnie G. Hazlitt , Pak-Meng Cham , Sarat Munjal , Wallace W. Yau
发明人： Mehmet Demirors , Teresa P. Karjala , Christopher R. Eddy , Lonnie G. Hazlitt , Pak-Meng Cham , Sarat Munjal , Wallace W. Yau
CPC分类号： C08F255/02 , C08F110/02 , C08F255/00 , C08F297/08 , C08F297/083 , C08L23/0815 , C08L51/06 , C08L53/00 , C08L2666/02 , C08F2500/09 , C08F2500/12 , C08F2500/20 , C08F2500/17 , C08F2500/07 , C08F2500/19
摘要： An ethylenic polymer comprising amyl groups from about 0.1 to about 2.0 units per 1000 carbon atoms as determined by Nuclear Magnetic Resonance and both a peak melting temperature, Tm, in ° C., and a heat of fusion, Hf, in J/g, as determined by DSC Crystallinity, where the numerical values of Tm and Hf correspond to the relationship Tm≧(0.2143*Hf)+79.643. An ethylenic polymer comprising at least one preparative TREF fraction that elutes at 95° C. or greater using a Preparative Temperature Rising Elution Fractionation method, where at least one preparative TREF fraction that elutes at 95° C. or greater has a gpcBR value greater than 0.05 and less than 5 as determined by gpcBR Branching Index by 3D-GPC, and where at least 5% of the ethylenic polymer elutes at a temperature of 95° C. or greater based upon the total weight of the ethylenic polymer.
摘要翻译： 包含通过核磁共振测定的约0.1至约2.0单位/ 1000个碳原子的乙烯基聚合物，峰值熔融温度Tm，℃，熔化热，Hf / J， 通过DSC结晶度测定，其中Tm和Hf的数值对应于Tm> =（0.2143×Hf）+79.643的关系。 包含至少一种使用制备型升温洗脱分级方法在95℃或更高洗脱的制备性TREF级分的乙烯性聚合物，其中至少一种在95℃或更高洗脱的制备性TREF级分的gpcBR值大于 通过3D-GPC通过gpcBR分枝指数测定的0.05和小于5，并且其中至少5％的乙烯类聚合物在基于乙烯类聚合物的总重量的95℃或更高的温度下洗脱。
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10.发明申请HIGH PRESSURE LOW DENSITY POLYETHYLENE RESINS WITH IMPROVED OPTICAL PROPERTIES PRODUCED THROUGH USE OF HIGHLY ACTIVE CHAIN TRANSFER AGENTS 审中-公开具有通过使用高活性链转移剂生产的改进的光学性能的高压低密度聚乙烯树脂公开(公告)号：US20100087606A1
公开(公告)日：2010-04-08
申请号：US12572314
申请日：2009-10-02
申请人： Teresa P. Karjala , Christopher R. Eddy , Mehmet Demirors , Wallace W. Yau , Sarat Munjal , Stefan Hinrichs , Jian Wang , Otto J. Berbee , Werner Zschoch , Cornelis J. Hosman , Lonnie G. Hazlitt , John O. Osby
发明人： Teresa P. Karjala , Christopher R. Eddy , Mehmet Demirors , Wallace W. Yau , Sarat Munjal , Stefan Hinrichs , Jian Wang , Otto J. Berbee , Werner Zschoch , Cornelis J. Hosman , Lonnie G. Hazlitt , John O. Osby
IPC分类号： C08F110/02 , C08F2/01
CPC分类号： C08F10/02 , C08F110/02 , Y10S526/917 , C08F2/01 , C08F2/001 , C08F2/38 , C08F2/00 , C08F2500/08 , C08F2500/12 , C08F2500/20 , C08F2500/04
摘要： Disclosed is an ethylene-based polymer with a density from about 0.90 to about 0.94 in grams per cubic centimeter, with a molecular weight distribution (Mw/Mn) from about 2 to about 30, a melt index (I2) from about 0.1 to about 50 grams per 10 minutes, and further comprising sulfur from about 5 to about 4000 parts per million. The amount of sulfur is also determined based upon the total weight of the ethylene-based polymer. Also disclosed is process for making an ethylene-based polymer which includes the steps of splitting a process fluid for delivery into a tubular reactor; feeding an upstream process feed stream into a first reaction zone and at least one downstream process feed stream into at least one other reaction zone, where the process fluid has an average velocity of at least 10 meters per second; and initiating a free-radical polymerization reaction.
摘要翻译： 公开了密度为约0.90至约0.94（克/立方厘米）的乙烯基聚合物，分子量分布（Mw / Mn）为约2至约30，熔体指数（I 2）为约0.1至约 50克/ 10分钟，还含有约5至约4000ppm的硫。 硫的量也基于乙烯类聚合物的总重量来确定。 还公开了制备基于乙烯的聚合物的方法，其包括将工艺流体分离成管式反应器的步骤; 将上游工艺进料流输送到第一反应区和至少一个下游工艺进料流进入至少一个其它反应区，其中所述工艺流体具有至少10米/秒的平均速度; 并引发自由基聚合反应。
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