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    Treatment of high-polymer materials
    2.
    发明授权
    Treatment of high-polymer materials 失效
    高分子材料的处理

    公开(公告)号：US4138298A

    公开(公告)日：1979-02-06

    申请号：US473303

    申请日：1974-05-24

    申请人： Wolfgang Bobeth ,  Adolf Heger ,  Helmar Passler ,  Hermann Roloff ,  Ellen Patitz ,  Adolf-Ernst Schwind ,  Erwin Zilinski

    发明人： Wolfgang Bobeth ,  Adolf Heger ,  Helmar Passler ,  Hermann Roloff ,  Ellen Patitz ,  Adolf-Ernst Schwind ,  Erwin Zilinski

    IPC分类号： D06M14/26 ,  C08J7/18 ,  C08J7/10

    CPC分类号： D06M14/26 ,  Y10S8/12 ,  Y10S8/18

    摘要： Two basic methods for texturizing or structurizing high-polymer materials are disclosed. One method resides in selectively irradiating a high-polymer material so as to form chemically active species in the material. The material is contacted with a treating medium which reacts with the chemically active species in such a manner as to cause shrinkage of the material. The texturizing or structurizing effects are due to the fact that the irradiated areas of the material will shrink to a different extent in dependence upon the concentration of the chemically active species and/or that the irradiated areas of the material will shrink to a different extent than the non-irradiated areas of the material.

    摘要翻译： 公开了用于使高分子材料进行组织化或结构化的两种基本方法。 一种方法是选择性地照射高分子材料以便在材料中形成化学活性物质。 该材料与处理介质接触，处理介质与化学活性物质反应，导致材料收缩。 组织化或结构化效应是由于以下事实：材料的照射区域将根据化学活性物质的浓度而收缩到不同程度，和/或材料的照射区域将收缩到与 材料的未照射区域。

    Method of enhancing high polymers, particularly textiles
    3.
    发明授权
    Method of enhancing high polymers, particularly textiles 失效
    增强高聚物，特别是纺织品的方法

    公开(公告)号：US4041192A

    公开(公告)日：1977-08-09

    申请号：US568245

    申请日：1975-04-15

    申请人： Adolf Heger ,  Helmar Passler ,  Frank Bennemann

    发明人： Adolf Heger ,  Helmar Passler ,  Frank Bennemann

    IPC分类号： D06M14/18 ,  B05D3/06

    CPC分类号： D06M14/18

    摘要： A method of enhancing the properties and appearance of polymeric substances is disclosed. The method involves treating a polymer so as to effect graft polymerization over the entire surface thereof in such a manner that variations in graft density occur across the surface of the polymer. This may be accomplished by forming chemically active species, e.g., ions or free radicals, in the polymer which vary in concentration across the surface of the latter and at least once contacting the surface of the polymer with a substance, for instance, a monomer such as a vinyl compound, which undergoes a graft polymerization reaction with the chemically active species. The chemically active species may be formed by irradiating the surface of the polymer with high energy radiation, for example, a beam of electrons. Different possibilities exist for achieving a varying concentration of the chemically active species across the surface of the polymer. One possibility resides in subjecting the surface of the polymer to both a homogeneous and a non-homogeneous irradiation. Another possibility resides in subjecting the surface of the polymer to a homogeneous irradiation and then eliminating at least some of the chemically active species in selected regions of the surface of the polymer. Still another possibility resides in directing a radiation beam at the surface of the polymer and varying the direction and/or the intensity of the beam. Numerous permutations within this framework exist.

    摘要翻译： 公开了增强聚合物质性质和外观的方法。 该方法包括处理聚合物以便在整个表面上实现接枝聚合，使得在聚合物表面上发生接枝密度的变化。 这可以通过在聚合物中形成化学活性物质，例如离子或自由基，其在后者的表面上的浓度变化，并且至少一次接触聚合物的表面与物质，例如单体 作为与化学活性物质进行接枝聚合反应的乙烯基化合物。 化学活性物质可以通过用高能辐射（例如电子束）照射聚合物的表面来形成。 存在不同的可能性，以实现聚合物表面上化学活性物质的不同浓度。 一种可能性在于使聚合物的表面经受均匀和非均匀照射。 另一种可能性在于使聚合物的表面经受均匀辐射，然后在聚合物表面的选定区域中消除至少一些化学活性物质。 另一种可能性在于将辐射束引导到聚合物的表面并改变光束的方向和/或强度。 在此框架内存在许多排列。

    Radiation treatment of high-polymer textile materials
    5.
    发明授权
    Radiation treatment of high-polymer textile materials 失效
    高分子纺织材料的辐射处理

    公开(公告)号：US4190623A

    公开(公告)日：1980-02-26

    申请号：US566334

    申请日：1975-04-09

    申请人： Wolfgang Bobeth ,  Adolf Heger ,  Helmar Passler ,  Hermann Roloff ,  Ellen Patitz ,  Adolf-Ernst Schwind ,  Erwin Zilinski

    发明人： Wolfgang Bobeth ,  Adolf Heger ,  Helmar Passler ,  Hermann Roloff ,  Ellen Patitz ,  Adolf-Ernst Schwind ,  Erwin Zilinski

    IPC分类号： D06M14/26 ,  B01D47/00 ,  B01F3/04

    CPC分类号： D06M14/26 ,  Y10S8/12 ,  Y10S8/18

    摘要： Two basic methods for texturizing or structurizing high-polymer materials are disclosed. One method resides in selectively irradiating a high-polymer material so as to form chemically active species in the material. The material is contacted with a treating medium which reacts with the chemically active species in such a manner as to cause shrinkage of the material. The texturizing or structurizing effects are due to the fact that the irradiated areas of the material will shrink to a different extent in dependence upon the concentration of the chemically active species and/or that the irradiated areas of the material will shrink to a different extent than the nonirradiated areas of the material. The other method resides in homogeneously irradiating a high-polymer material so as to form chemically active species in the material. The chemically active species in certain areas of the material are at least partially destroyed by contacting selected areas of the material with a suitable medium. The material is again contacted with a treating medium which reacts with the chemically active species in such a manner as to cause shrinkage of the material. The texturizing or structurizing effects are due to the fact that those areas of the material where chemically active species are present will shrink to a different extent in dependence upon the concentration of the chemically active species and/or that those areas of the material where chemically active species are present will shrink to a different extent than the areas where no chemically active species are present.

    摘要翻译： 公开了用于使高分子材料进行组织化或结构化的两种基本方法。 一种方法是选择性地照射高分子材料以便在材料中形成化学活性物质。 该材料与处理介质接触，处理介质与化学活性物质反应，导致材料收缩。 组织化或结构化效应是由于以下事实：材料的照射区域将根据化学活性物质的浓度而收缩到不同程度，和/或材料的照射区域将收缩到与 材料的非照射区域。 另一种方法是均匀地照射高分子材料以便在材料中形成化学活性物质。 材料的某些区域中的化学活性物质通过使材料的选定区域与合适的介质接触至少部分地被破坏。 该材料再次与以化学活性物质反应的处理介质接触，以使材料收缩。 纹理化或结构化效应是由于存在化学活性物质的材料的那些区域将根据化学活性物质的浓度和/或化学活性物质的那些区域而收缩到不同程度 存在的物种将会收缩到与没有化学活性物质存在的区域不同的程度。

    Method of making a pattern-dyed, pattern-textures, or lace like textile or foil
    6.
    发明授权
    Method of making a pattern-dyed, pattern-textures, or lace like textile or foil 失效
    制作图案染色，图案纹理或蕾丝如纺织品或箔片的方法

    公开(公告)号：US4112136A

    公开(公告)日：1978-09-05

    申请号：US539185

    申请日：1975-12-23

    申请人： Adolf Heger ,  Gerrit Mockel ,  Helmar Passler ,  Jochen Pohlink ,  Werner Wunsch

    发明人： Adolf Heger ,  Gerrit Mockel ,  Helmar Passler ,  Jochen Pohlink ,  Werner Wunsch

    IPC分类号： D06C7/02 ,  C08F2/46 ,  D06C29/00 ,  D06M14/18 ,  B05D3/06

    CPC分类号： D06M14/18

    摘要： A synthetic-resin textile or foil web is printed according to a predetermined pattern with a paste comprising a monomer, prepolymer or polymer. The web is irradiated over its entire surface before printing and only those areas where there is printing paste form high-molecular associations (cross-links, polymerizations, coagulations) so as to pattern the surface of the workpiece. According to the type of associatively-reactable compound used in the printing paste the workpiece will be textured so as to appear sculptured or will be locally colored and textured.

    摘要翻译： 根据预定图案，用包含单体，预聚物或聚合物的糊料印刷合成树脂织物或箔网。 在印刷之前纤维网在其整个表面上被照射，并且只有印刷浆料的那些区域形成高分子缔合（交联，聚合，凝结），以便对工件的表面进行图案化。 根据在印刷浆料中使用的可联合反应的化合物的类型，工件将被纹理化，以便显现出雕刻或将被局部着色和纹理化。