公开(公告)号：US06559221B2

公开(公告)日：2003-05-06

申请号：US09927390

申请日：2001-08-13

申请人： Mario Sandor ,  Joachim Pakusch ,  Wolfgang Hümmer ,  Hans-Jürgen Denu ,  Rolf Gulden

发明人： Mario Sandor ,  Joachim Pakusch ,  Wolfgang Hümmer ,  Hans-Jürgen Denu ,  Rolf Gulden

IPC分类号： C08L4304

CPC分类号： C08F290/06 ,  C08F246/00 ,  C08F257/02 ,  C09D143/04 ,  C09D151/003 ,  C09J151/003

摘要： An aqueous polymer dispersion, wherein the dispersion contains from 0.0001 to 1 mol of a hydrolyzable silicon group and from 0.0001 to 1 mol of a urea or thiourea group, based, in each case, on 100 g of the polymer present in the dispersion.

公开(公告)号：US06743834B2

公开(公告)日：2004-06-01

申请号：US09974628

申请日：2001-10-10

申请人： Tetsuya Yokoyama ,  Kamikado Koji

发明人： Tetsuya Yokoyama ,  Kamikado Koji

IPC分类号： C08L4304

CPC分类号： C09D5/4407 ,  Y10S525/902 ,  Y10T428/31551 ,  Y10T428/31573 ,  Y10T428/31598

摘要： Anionic electrodeposition coating compositions for forming matte films containing acrylic resin; alkoxysilyl group containing emulsified polymer produced by a multiple stage emulsion polymerization of unsaturated monomer in the presence of water and a emulsifier, wherein the unsaturated monomer containing alkoxysilyl group-containing unsaturated monomer is present in an amount of 5 to 40% by weight based on a total amount of all the unsaturated monomers used in the multiple stage emulsion polymerization; and crosslinking agent.

摘要翻译： 用于形成含有丙烯酸树脂的无光泽膜的阴离子电沉积涂料组合物; 含有烷氧基甲硅烷基的乳化聚合物，其通过在水和乳化剂的存在下的不饱和单体的多阶段乳液聚合制备，其中所述含烷氧基甲硅烷基的不饱和单体的不饱和单体的存在量为5-40重量％，基于 在多阶段乳液聚合中使用的所有不饱和单体的总量; 和交联剂。

公开(公告)号：US06531540B1

公开(公告)日：2003-03-11

申请号：US09858424

申请日：2001-05-16

申请人： Michael J. O'Brien

发明人： Michael J. O'Brien

IPC分类号： C08L4304

CPC分类号： A61K8/894 ,  A61K8/895 ,  A61Q1/02 ,  A61Q1/06 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q15/00 ,  A61Q19/00 ,  A61Q19/001 ,  C08G77/14 ,  C08G77/38 ,  C08L83/06

摘要： A composition comprising the reaction products of MaMHbMEcDdDHeDEfTgTHhTEiQj where M=R1R2R3SiO1/2; MH=R4R5HSiO1/2; ME=R6R7RESiO1/2; D=R8R9SiO2/2; DH=R10HSiO2/2; DE=R11RESiO2/2; T=R12SiO3/2; TH=HSiO3/2; TE=RESiO3/2; and Q=SiO4/2; where R1, R2, R3, R8, R9 and R12 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms; R4, R5 and R10 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or hydrogen; R6, R7, R11 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or RE; each RE is independently a monovalent hydrocarbon radical containing one or more oxirane moieties having from one to sixty carbon atoms; the stoichiometric subscripts a, b, c, d, e, f, g, h, i, and j are either zero or positive subject to the following limitations: a+b+c>1; b+e+h>1; c+f+i>1; b+e+h>c+f+i; and when d+e+f+g+h+i+j=0, a+b+c=2. In a preferred embodiment the reaction product of the present invention is a polyether siloxane copolymer network. In another preferred embodiment embodiment the reaction product of the present invention is a polyether siloxane copolymer network swollen with a volatile low molecular weight silicon containing compound. These compositions are useful for a variety of personal care compositions.

摘要翻译： 包含其中M = R1R2R3SiO1 / 2; MH = R4R5HSiO1 / 2; ME = R6R7RESiO1 / 2; D = R8R9SiO2 / 2; DH = R10HSiO2 / 2; DE = R11RESiO2 / 2; T = R12SiO3 / 2; TH = HSiO3 / 2; TE = RESiO3 / 2; 和Q = SiO 4/2;其中R 1，R 2，R 3，R 8，R 9和R 12独立地为具有1至60个碳原子的一价烃基; R4，R5和R10独立地为具有1-6个碳原子的一价烃基或氢; R6，R7，R11独立为具有1-6个碳原子的一价烃基或RE; 每个RE独立地是含有一个或多个具有一个至六十个碳原子的环氧乙烷部分的单价烃基; 化学计量下标a，b，c，d，e，f，g，h，i和j分别为零或正数，但有以下限制：a + b + c> 1; b + e + h> 1; c + f + i> 1; b + e + h> c + f + i; 并且当d + e + f + g + h + i + j = 0时，a + b + c = 2。 在优选的实施方案中，本发明的反应产物是聚醚硅氧烷共聚物网络。 在另一个优选的实施方案中，本发明的反应产物是用挥发性低分子量含硅化合物溶胀的聚醚硅氧烷共聚物网络。 这些组合物可用于各种个人护理组合物。

公开(公告)号：US06538061B2

公开(公告)日：2003-03-25

申请号：US09858795

申请日：2001-05-16

申请人： Atchara Chaiyawat ,  Michael J. O'Brien

发明人： Atchara Chaiyawat ,  Michael J. O'Brien

IPC分类号： C08L4304

CPC分类号： A61K8/891 ,  A61K8/02 ,  A61K8/042 ,  A61K8/894 ,  A61K2800/54 ,  A61K2800/56 ,  A61Q1/02 ,  A61Q1/04 ,  A61Q1/06 ,  A61Q5/12 ,  A61Q15/00 ,  A61Q19/00

摘要： A composition comprising the reaction products of MaMHbMEcDdDHeDEfTgTHhTEiQj where M=R1R2R3SiO1/2; MH=R4R5HSiO1/2; ME=R6R7RESiO1/2; D=R8R9SiO2/2; DH=R10HSiO2/2; DE=R11RESiO2/2; T=R12SiO3/2; TH=HSiO3/2; TE=RESiO3/2; and Q=SiO4/2; where R1, R2, R3, R8, R9 and R12 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms; R4, R5 and R10 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or hydrogen; R6, R7, R11 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or RE; each RE is independently a monovalent hydrocarbon radical containing one or more oxirane moieties having from one to sixty carbon atoms; the stoichiometric subscripts a, b, c, d, e, f, g, h, i, and j are either zero or positive subject to the following limitations: a+b+c>1; b+e+h>1; c+f+i>1; b+e+h>c+f+i; and when d+e+f+g+h+i+j=0, a+b+c=2. In a preferred embodiment the reaction product of the present invention is a polyether siloxane copolymer network. In another preferred embodiment embodiment the reaction product of the present invention is a polyether siloxane copolymer network swollen with a volatile low molecular weight silicon containing compound. These compositions are useful for a variety of personal care compositions.

摘要翻译： 包含其中M = R1R2R3SiO1 / 2; MH = R4R5HSiO1 / 2; ME = R6R7RESiO1 / 2; D = R8R9SiO2 / 2; DH = R10HSiO2 / 2; DE = R11RESiO2 / 2; T = R12SiO3 / 2; TH = HSiO3 / 2; TE = RESiO3 / 2; 和Q = SiO 4/2;其中R 1，R 2，R 3，R 8，R 9和R 12独立地为具有1至60个碳原子的一价烃基; R4，R5和R10独立地为具有1-6个碳原子的一价烃基或氢; R6，R7，R11独立为具有1-6个碳原子的一价烃基或RE; 每个RE独立地是含有一个或多个具有一个至六十个碳原子的环氧乙烷部分的单价烃基; 化学计量下标a，b，c，d，e，f，g，h，i和j分别为零或正数，但有以下限制：a + b + c> 1; b + e + h> 1; c + f + i> 1; b + e + h> c + f + i; 并且当d + e + f + g + h + i + j = 0时，a + b + c = 2。 在优选的实施方案中，本发明的反应产物是聚醚硅氧烷共聚物网络。 在另一个优选的实施方案中，本发明的反应产物是用挥发性低分子量含硅化合物溶胀的聚醚硅氧烷共聚物网络。 这些组合物可用于各种个人护理组合物。

公开(公告)号：US06420480B1

公开(公告)日：2002-07-16

申请号：US09567540

申请日：2000-05-05

申请人： Eser Ozdeger

发明人： Eser Ozdeger

IPC分类号： C08L4304

CPC分类号： C09J151/003 ,  C08F265/04 ,  C08F290/068 ,  C08F290/148 ,  C08L2666/02 ,  C09D151/003 ,  C09D151/085 ,  C09J7/401 ,  C09J151/085 ,  C09J2433/005 ,  C09J2483/005 ,  Y10T428/31663

摘要： Polymer latices are provided that are useful as release coatings for pressure-sensitive adhesive (PSA) coated paper and tapes. With the ever-present environmental concern to eliminate organic solvents, the use of 100% solids and water-based release coatings is becoming more desirable. The latices of the present invention are waterborne, which is an advantage over the more conventional release coating compositions that are usually comprised of solvent-based polymers, and possess good and stable release characteristics.

摘要翻译： 提供聚合物胶乳，其可用作压敏粘合剂（PSA）涂布纸和胶带的剥离涂层。 随着环境问题的消除，消除有机溶剂，使用100％固体和水基防粘涂层变得越来越受欢迎。 本发明的胶乳是水性的，这是比通常由溶剂基聚合物组成的更常规的脱模涂料组合物的优点，并且具有良好和稳定的脱模特性。

公开(公告)号：US06831128B2

公开(公告)日：2004-12-14

申请号：US10189998

申请日：2002-07-02

申请人： Michael Gene Altes ,  Lee Bowen Jensen ,  Shaow Burn Lin ,  Anil Kumar Saxena ,  Anne Katja Shim ,  Todd Matthew Starke ,  Toshio Suzuki

发明人： Michael Gene Altes ,  Lee Bowen Jensen ,  Shaow Burn Lin ,  Anil Kumar Saxena ,  Anne Katja Shim ,  Todd Matthew Starke ,  Toshio Suzuki

IPC分类号： C08L4304

CPC分类号： C08J3/03 ,  C08J2300/108 ,  C08J2321/00

摘要： Water-continuous emulsion of silylated elastomeric polymers are disclosed having a solids content of greater than 75%, an average particle size less than 5 &mgr;m, and having sufficient stability to produce a stable lower solids emulsion upon dilution with water comprising; a silylated elastomeric polymer, surfactant, water, optional plasticizer, and optional low molecular weight acid. The water-continuous emulsions of silylated elastomeric polymers can be prepared by; (I) forming a premix comprising an elastomeric polymer and surfactant, and optionally a plasticizer and low molecular weight acid, and (II) adding water to the premix with mixing to form a water continuous emulsion of the silylated elastomeric polymer having a solids content of greater than 75%, an average particle size less than 5 &mgr;m, and having sufficient stability to produce a stable lower solids emulsion upon dilution with water.

公开(公告)号：US06713558B2

公开(公告)日：2004-03-30

申请号：US09905659

申请日：2001-07-13

申请人： Michael Gene Altes ,  Lee Bowen Jensen ,  Shaow Burn Lin ,  Anil Kumar Saxena ,  Todd Matthew Starke ,  Toshio Suzuki

发明人： Michael Gene Altes ,  Lee Bowen Jensen ,  Shaow Burn Lin ,  Anil Kumar Saxena ,  Todd Matthew Starke ,  Toshio Suzuki

IPC分类号： C08L4304

CPC分类号： C08J3/03 ,  C08J2300/108 ,  C08J2321/00

摘要： Water-continuous emulsion of silylated elastomeric polymers are disclosed having a solids content of greater than 75%, an average particle size less than 5 &mgr;m, and having sufficient stability to produce a stable lower solids emulsion upon dilution with water comprising; a silylated elastomeric polymer, surfactant, water, optional plasticizer, and optional low molecular weight acid. The water-continuous emulsions of silylated elastomeric polymers can be prepared by; (I) forming a premix comprising an elastomeric polymer and surfactant, and optionally a plasticizer and low molecular weight acid, and (II) adding water to the premix with mixing to form a water continuous emulsion of the silylated elastomeric polymer having a solids content of greater than 75%, an average particle size less than 5 &mgr;m, and having sufficient stability to produce a stable lower solids emulsion upon dilution with water.

摘要翻译： 公开了具有大于75％的固体含量，平均粒度小于5um的甲硅烷基化弹性体聚合物的水连续乳液，并且在用水稀释时具有足够的稳定性以产生稳定的低固体乳剂; 甲硅烷基化弹性体聚合物，表面活性剂，水，任选的增塑剂和任选的低分子量酸。 甲硅烷基化弹性体聚合物的水连续乳液可以通过以下步骤制备： （I）形成包含弹性体聚合物和表面活性剂以及任选的增塑剂和低分子量酸的预混物，和（II）将混合物中的水加入到预混合物中以形成具有固体含量的甲硅烷基化弹性体聚合物的水连续乳液 大于75％，平均粒径小于5μm，并且在用水稀释时具有足够的稳定性以产生稳定的低固体乳剂。

公开(公告)号：US06420479B1

公开(公告)日：2002-07-16

申请号：US09752897

申请日：2000-12-29

申请人： Lein Phan ,  Rajeev Farwaha ,  Apala Mukherjee ,  John S. Thomaides

发明人： Lein Phan ,  Rajeev Farwaha ,  Apala Mukherjee ,  John S. Thomaides

IPC分类号： C08L4304

CPC分类号： C09J153/00 ,  C08F2/24 ,  C08F293/005 ,  C08F297/026 ,  C08L53/00 ,  C09D153/00

摘要： A colloid composition is presented which contains an amphiphilic star polymer having potentially crosslinkable sites on the polymer backbone. The potentially crosslinkable site is either a sterically hindered silane monomer or an acetoacetoxy-containing monomer. When the crosslinkable site is a sterically hindered silane monomer the star polymer also contains an internal catalyst, and when the crosslinkable site is an acetoacetoxy group the colliod composition also contains a non-polymeric polyfunctional amine. The star polymer can be either a random or heteroarm star polymer. The colloid composition is useful in the formation and stabilization of emulsion polymers, as a replacement for surfactants currently used for this purpose. Emulsion polymers formulated with the colloid composition are especially useful for one-part coatings such as paints and adhesives.

摘要翻译： 提出了一种胶体组合物，其包含在聚合物主链上具有潜在可交联位点的两亲性星形聚合物。 潜在可交联的位点是空间位阻硅烷单体或含乙酰乙酰氧基的单体。 当可交联位置是空间位阻硅烷单体时，星形聚合物还含有内部催化剂，并且当可交联位点是乙酰乙酰氧基时，该絮状组合物还含有非聚合多官能胺。 星形聚合物可以是无规或星形聚合物。 胶体组合物可用于形成和稳定乳液聚合物，作为目前用于此目的的表面活性剂的替代物。 用胶体组合物配制的乳液聚合物特别适用于一部分涂料如油漆和粘合剂。