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公开(公告)号:US20210178382A1
公开(公告)日:2021-06-17
申请号:US16714383
申请日:2019-12-13
申请人: UOP LLC
发明人: John J. Senetar , Lev Davydov
摘要: Higher temperature regenerated dehydrogenation catalyst is mixed with the lower temperature spent dehydrogenation catalyst from a dehydrogenation reaction to heat the spent catalyst. Air or other oxygen containing gas may be introduced to facilitate mixing. The mixing of hot regenerated catalyst with cooler spent catalyst increases the temperature of the spent catalyst and makes the coke on catalyst and in the supplemental fuel gas instantly ready to combust without the delay necessary to heat up the spent catalyst to combustion temperature. The regenerated dehydrogenation catalyst may be mixed with the spent dehydrogenation catalyst before the mixture of catalyst is contacted with the supplemental fuel gas. Combustion with fuel gas should be conditioned to avoid generation of a flame.
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公开(公告)号:US10974238B2
公开(公告)日:2021-04-13
申请号:US16039091
申请日:2018-07-18
申请人: UOP LLC
发明人: Zhihao Fei , Lisa M. Wolschlag , Brian W. Hedrick
IPC分类号: B01J38/26 , B01J38/34 , B01J38/04 , B01J8/34 , B01J8/00 , B01J8/26 , B01J8/28 , B01J38/30 , C10G11/18 , B01J29/90
摘要: A counter-current catalyst regenerator with at least two stages of counter-current contact is proposed. Each stage may comprise a permeable barrier that allows upward passage of oxygen-containing gas and downward passage of coked catalyst into each stage, but inhibits upward movement of catalyst to mitigate back mixing and approximate true counter-current contact and efficient combustion of coke from catalyst.
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公开(公告)号:US20210023547A1
公开(公告)日:2021-01-28
申请号:US17066484
申请日:2020-10-08
摘要: A method for circulating a cooled regenerated catalyst comprises the following steps: a regenerated catalyst derived from a regenerator (5) is cooled to 200-720° C. by a catalyst cooler (8A), which either directly enters into a riser reactor (2) without mixing with hot regenerated catalyst, or enters the same after mixing with another portion of uncooled hot regenerated catalyst and thereby obtaining a hybrid regenerated catalyst with its temperature lower than that of the regenerator; a contact reaction between a hydrocarbon raw materials and the catalyst is performed in the riser reactor (2); the reaction product is introduced into a settling vessel (1) to separated the catalyst and oil gas; the separated catalyst ready for regeneration is stream-stripped in a stream stripping phase (1A) and enters the regenerator (5) for regeneration through charring; after cooling, the regenerated catalyst returns to the riser reactor (2) for recycling.
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4.
公开(公告)号:US10688477B2
公开(公告)日:2020-06-23
申请号:US16094582
申请日:2017-05-05
发明人: Matthew T. Pretz , Liwei Li
IPC分类号: B01J23/96 , C10G11/18 , B01J38/18 , B01J8/00 , B01J8/18 , B01J8/34 , B01J8/26 , B01J23/62 , B01J38/02 , B01J38/04 , B01J38/10 , C07C5/333 , B01J38/30
摘要: A process to react an oxygen containing regenerated catalyst stream prior to use in a fluidized bed reactor comprising providing a regenerated catalyst stream which comprises at least 0.001 wt % oxygen; reacting the regenerated catalyst stream with a fuel source thereby forming oxides and reducing the amount of oxygen in the regenerated catalyst stream to produce a usable regenerated catalyst stream; and injecting the usable regenerated catalyst stream into a hydrocarbon fluidized bed reactor is provided.
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公开(公告)号:US10654035B2
公开(公告)日:2020-05-19
申请号:US16079362
申请日:2017-02-22
发明人: Andrzej Malek , David Gordon Barton , Lin Luo
IPC分类号: B01J38/44 , B01J38/18 , B01J23/62 , B01J23/96 , B01J38/30 , B01J38/34 , B01J23/08 , B01J23/92 , C07C5/32 , B01J38/14 , B01J35/10 , B01J38/02 , B01J35/02 , B01J21/12
摘要: The present disclosure provides an air-soak containing regeneration process reducing its time. The process includes (i) removing surface carbon species from a gallium-based alkane dehydrogenation catalyst in a combustion process in the presence of a fuel gas; (ii) conditioning the gallium-based alkane dehydrogenation catalyst after (i) in air-soak treatment at a temperature of 660° C. to 850° C. with (iii) a flow of oxygen-containing gas having (iv) 0.1 to 100 parts per million by volume (ppmv) of a chlorine source selected from chlorine, a chlorine compound or a combination thereof; and achieving a predetermined alkane conversion percentage for the gallium-based alkane dehydrogenation catalyst undergoing the air-soak containing regeneration process using (i) through (iv) 10% to 50% sooner in air-soak treatment than that required to achieve the same predetermined alkane conversion percentage for the gallium-based alkane dehydrogenation catalyst undergoing the air-soak containing regeneration process using (i) through (iii), but without (iv).
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6.
公开(公告)号:US10577541B2
公开(公告)日:2020-03-03
申请号:US14129786
申请日:2012-06-29
申请人: Marc Bories , Patrick Leroy , Eusebius Gbordzoe
发明人: Marc Bories , Patrick Leroy , Eusebius Gbordzoe
摘要: The present invention discloses a process for the catalytic cracking of a weakly coking feedstock having a Conradson carbon residue of 0.1% by weight and a hydrogen content of greater than 12.7% by weight, comprising at least a feedstock cracking zone, a zone for separating/stripping the effluents from the coked catalyst particles and a zone for regenerating said particles, characterized in that at least a solid carbon material in the fluidized state, having a carbon content equal to or greater than 80% by weight, is injected upstream of and/or during the catalyst regeneration step into a dense bed of coked catalyst.
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公开(公告)号:US10576443B1
公开(公告)日:2020-03-03
申请号:US16277103
申请日:2019-02-15
申请人: UOP LLC
发明人: Joseph Colmone , Michael S. Sandacz , Michael A. Stine , Richard A. Johnson, II , Nicholas Madonia , Minwoo Kim
摘要: A regenerator for an FCC apparatus. The regenerator includes an internal riser inside of a outer shell. The internal riser includes a cone and a cone skirt. An annulus is formed between the internal riser and the outer shell. A sealing apparatus for keeping catalyst out of a portion of the annulus comprises a first sealing element and a second sealing element disposed above the first sealing element. An annular trough in the annulus below the primary seal is filled with material that has a heat transfer coefficient at least as high as air to allow heat to get to the inner surface of the outer shell.
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公开(公告)号:US20190330125A1
公开(公告)日:2019-10-31
申请号:US16471383
申请日:2018-05-01
发明人: Deuk Soo PARK , Ung Gi HONG , Hyeongchan AHN , Won Choon CHOI , Yong Ki PARK
摘要: Disclosed is an olefin production method which includes: (a) providing the regenerated catalyst and the hydrocarbon including not less than 90 wt % of LPG into Riser of Fast Fluidization Regime, and dehydrogenating in the presence of an alumina type catalyst; (b) separating an effluent from the dehydrogenation reaction into the catalyst and propylene mixture; (c) stripping to remove the hydrocarbon compound included in the catalyst separated at stage (b); (d) mixing the catalyst stripped at stage (c) with the gas including oxygen, and continuously regenerating it; (e) recycling the catalyst regenerated at stage (d) to stage (a), and providing it again into Riser; and (f) producing propylene product by cooling, compressing and separating propylene mixture of the reaction product separated at stage (b).
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公开(公告)号:US10399075B2
公开(公告)日:2019-09-03
申请号:US15997188
申请日:2018-06-04
申请人: UOP LLC
发明人: Paolo Palmas
IPC分类号: B01J38/30 , B01J8/28 , B01J38/04 , B01J8/18 , B01J8/26 , C10G11/18 , C10G11/22 , F23C10/01 , F23C10/18
摘要: A process for combusting coke from catalyst in partial burn mode is disclosed. The partial burn regenerator runs deprived of oxygen such that the flue gas will contain a fair amount of carbon monoxide. The oxygen present in the flue gas can burn in the bed before reaching the dilute phase. The catalyst distributor is positioned in the upper chamber of the regeneration vessel for discharging the catalyst.
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公开(公告)号:US20180280964A1
公开(公告)日:2018-10-04
申请号:US15997188
申请日:2018-06-04
申请人: UOP LLC
发明人: Paolo Palmas
CPC分类号: B01J38/30 , B01J8/1818 , B01J8/1827 , B01J8/26 , B01J8/28 , B01J38/04 , B01J38/34 , B01J38/36 , B01J2208/00902 , B01J2208/00911 , C10G11/182 , C10G11/22 , F23C10/01 , F23C10/18
摘要: A process for combusting coke from catalyst in partial burn mode is disclosed. The partial burn regenerator runs deprived of oxygen such that the flue gas will contain a fair amount of carbon monoxide. The oxygen present in the flue gas can burn in the bed before reaching the dilute phase. The catalyst distributor is positioned in the upper chamber of the regeneration vessel for discharging the catalyst.
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