Conversion of co-fed methane and low hydrogen content hydrocarbon feedstocks to acetylene
    91.
    发明授权
    Conversion of co-fed methane and low hydrogen content hydrocarbon feedstocks to acetylene 有权
    共同供应的甲烷和低含氢烃原料转化为乙炔

    公开(公告)号:US08748686B2

    公开(公告)日:2014-06-10

    申请号:US12323132

    申请日:2008-11-25

    IPC分类号: C07C2/78 C07C4/04 C07C11/24

    摘要: A process and apparatus are provided to produce acetylene from a feed stream of low hydrogen content hydrocarbons such as coal by: (a) blending the hydrocarbons with methane to provide a blended mixture containing at least about 12.5 wt % atomic hydrogen; (b) partially combusting the blended mixture in a reactor in the presence of a source of oxygen to provide a partially combusted mixture at or above a temperature sufficient to produce methyl radicals; (c) maintaining the partially combusted mixture at or above the temperature for a residence time sufficient to produce a product stream containing enhanced yields of acetylene without significant formation of coke or coke precursors; (d) cooling the product stream to reduce the temperature of the product stream within a time sufficiently brief to substantially arrest any cracking reactions and provide a cooled product stream; and (e) recovering acetylene from the cooled product stream. The acetylene can be converted to ethylene by a conventional hydrogenation process.

    摘要翻译: 提供了一种方法和装置,用于通过以下方式从低含氢烃类进料流中产生乙炔:(a)将烃与甲烷混合,得到含有至少约12.5wt%原子氢的共混混合物; (b)在氧气源存在的情况下在反应器中部分燃烧混合物,以在足以产生甲基自由基的温度或高于其温度下提供部分燃烧的混合物; (c)将部分燃烧的混合物保持在等于或高于该温度的停留时间足以产生含有较高产率的乙炔的产物流,而不显着形成焦炭或焦炭前体; (d)冷却产物流以在足够短的时间内降低产物流的温度,以基本上阻止任何裂解反应并提供冷却的产物流; 和(e)从冷却的产物流中回收乙炔。 乙炔可以通过常规的氢化方法转化为乙烯。

    Conversion of co-fed methane and hydrocarbon feedstocks into higher value hydrocarbons
    94.
    发明授权
    Conversion of co-fed methane and hydrocarbon feedstocks into higher value hydrocarbons 有权
    将共同供应的甲烷和烃原料转化为更高价值的烃

    公开(公告)号:US08106248B2

    公开(公告)日:2012-01-31

    申请号:US12121353

    申请日:2008-05-15

    IPC分类号: C07C15/02 C07C2/00 B01J19/00

    摘要: In one aspect, the inventive process comprises a process for pyrolyzing a hydrocarbon feedstock containing nonvolatiles in a regenerative pyrolysis reactor system. The process comprises: (a) heating the nonvolatile-containing hydrocarbon feedstock upstream of a regenerative pyrolysis reactor system to a temperature sufficient to form a vapor phase that is essentially free of nonvolatiles and a liquid phase containing the nonvolatiles; (b) separating said vapor phase from said liquid phase; (c) feeding the separated vapor phase and methane to the pyrolysis reactor system; and (d) converting the methane and separated vapor phase in said pyrolysis reactor system to form a pyrolysis product. In another aspect, the invention includes a separation process that feeds multiple pyrolysis reactors.

    摘要翻译: 一方面,本发明的方法包括在再生热解反应器系统中热解含有非挥发物的烃原料的方法。 该方法包括:(a)将再生热解反应器系统上游的含非挥发物烃原料加热至足以形成基本上不含非挥发物的气相和含有非挥发物的液相的温度; (b)从所述液相中分离出所述气相; (c)将分离的气相和甲烷进料到热解反应器系统; 和(d)在所述热解反应器系统中转化甲烷和分离的气相以形成热解产物。 另一方面,本发明包括进料多个热解反应器的分离方法。

    Integrated Process and System for Steam Cracking and Catalytic Hydrovisbreaking with Catalyst Recycle
    95.
    发明申请
    Integrated Process and System for Steam Cracking and Catalytic Hydrovisbreaking with Catalyst Recycle 审中-公开
    用催化剂回收利用蒸汽裂解和催化加氢脱硫的综合工艺和系统

    公开(公告)号:US20110180456A1

    公开(公告)日:2011-07-28

    申请号:US12692222

    申请日:2010-01-22

    IPC分类号: C10G65/10 B01J8/00

    摘要: This invention relates to a process for cracking hydrocarbon feedstock containing resid comprising: (a) heating a hydrocarbon feedstock containing resid; (b) adding molecular hydrogen to said heated feedstock to form a mixture stream; (c) adding a catalyst containing metal-sulfide particles to said heated feedstock and/or said mixture stream; (d) reacting said mixture in a catalytic hydrovisbreaking reactor under conditions of temperature, pressure and residence time sufficient to catalytically hydrovisbreak at least a portion of said resid into hydrovisbroken hydrocarbon components; (e) passing said reacted mixture stream into a high pressure separator and separating hydrogen from said reacted mixture; (f) passing said reacted mixture through a knockout drum to remove catalyst and unreacted or uncracked resid as a bottoms stream; and (g) passing said catalytically hydrovisbroken hydrocarbon components into a steam cracking furnace and thermally cracking said hydrocarbon components to form light olefins, alternately the knockout drum of step (f) is integrated into the steam cracking furnace of step (g).

    摘要翻译: 本发明涉及一种用于裂化含有残渣的烃原料的方法,包括:(a)加热含有渣油的烃原料; (b)向所述加热的原料中加入分子氢以形成混合物流; (c)向所述加热的原料和/或所述混合物流中加入含有金属硫化物颗粒的催化剂; (d)使所述混合物在催化加氢脱硫反应器中在温度,压力和停留时间的条件下反应,足以将至少一部分所述残余物催化裂解成含水分解烃组分; (e)使所述反应的混合物流进入高压分离器并从所述反应的混合物中分离氢; (f)使所述反应的混合物通过敲除鼓以除去作为塔底物流的催化剂和未反应或未裂化的残渣; 和(g)将所述催化氢裂解烃组分通入蒸汽裂解炉中并热裂化所述烃组分以形成轻质烯烃,或者将步骤(f)的脱模鼓整合到步骤(g)的蒸汽裂解炉中。

    Multi component catalyst and its use in catalytic cracking
    96.
    发明授权
    Multi component catalyst and its use in catalytic cracking 有权
    多组分催化剂及其在催化裂化中的应用

    公开(公告)号:US07326332B2

    公开(公告)日:2008-02-05

    申请号:US10671080

    申请日:2003-09-25

    IPC分类号: C10G11/00 C10G11/05

    摘要: A multi component catalyst and catalytic cracking process for selectively producing C3 olefins. The catalyst comprises a first molecular sieve having an intermediate pore size, a second molecular sieve and, optionally a third molecular sieve having a large pore size. At least one of the channels of the second molecular sieve has a pore size index that is less than the pore size index of at least one channel of the first molecular sieve. The process is carried out by contacting a feedstock containing hydrocarbons having at least 5 carbon atoms is contacted, under catalytic cracking conditions, with the multi component catalyst. The catalyst finds application in the cracking of naphtha and heavy hydrocarbon feedstocks.

    摘要翻译: 用于选择性制备C 3 O 3烯烃的多组分催化剂和催化裂解方法。 催化剂包括具有中等孔径的第一分子筛,第二分子筛和任选的具有大孔径的第三分子筛。 第二分子筛的至少一个通道的孔径指数小于第一分子筛的至少一个通道的孔径指数。 该方法通过使含有至少5个碳原子的烃的原料在催化裂化条件下与多组分催化剂接触来进行。 该催化剂可用于石脑油和重质烃原料的裂解。

    Reduction of total sulfur in crude and condensate cracking
    97.
    发明授权
    Reduction of total sulfur in crude and condensate cracking 失效
    减少粗硫和冷凝水裂解总硫

    公开(公告)号:US07285697B2

    公开(公告)日:2007-10-23

    申请号:US10893716

    申请日:2004-07-16

    IPC分类号: C10G9/36

    摘要: A process for cracking hydrocarbon feedstock comprising at least one sulfur-containing compound comprising: heating the feedstock and a peroxide-containing compound, mixing the heated feedstock and peroxide-containing compound with a fluid and/or a primary dilution steam stream to form a mixture, flashing the mixture to form a vapor phase and a liquid phase which collect as bottoms and removing the liquid phase, separating and cracking the vapor phase, and cooling the product effluent, wherein the oxidized sulfur-containing species are removed as bottoms

    摘要翻译: 一种用于裂化烃原料的方法,包括至少一种含硫化合物,包括:加热原料和含过氧化物的化合物,将加热的原料和含过氧化物的化合物与流体和/或初级稀释蒸汽流混合以形成混合物 将混合物闪烁以形成气相和液相,其以塔底收集并除去液相,分离和裂化气相,并冷却产物流出物,其中氧化的含硫物质作为底部物质被除去