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1.发明申请公开(公告)号：US20160281002A1
公开(公告)日：2016-09-29
申请号：US15036051
申请日：2014-01-06
发明人： Pankaj Kumar KASLIWAL , Kuvettu Mohan PRABHU , Arumugam Velayutham KARTHIKEYANI , Bandaru Venkata HARIPRASADGUPTA , Balaiah SWAMY , Biswanath SARKAR , Brijesh KUMAR , Santanam RAJAGOPAL , Ravinder Kumar MALHOTRA
摘要： The present invention provides a process and a system for coking and simultaneous upgrading of a heavy hydrocarbon feedstock. More particularly the present invention relates to a process of cracking heavy hydrocarbon feedstock employing high heat carrier, incorporated with weak acid sites for improving the liquid yield and reducing coke yield. The feedstock is vaporized and brought in contact with a heat carrier material to produce a product stream and separating the product stream from the particulate heat carrier, regeneration of the particulate heat carrier to the extent of 10-30% and collecting a gaseous and liquid product from the product stream.
摘要翻译： 本发明提供了重质烃原料的焦化和同时升级的方法和系统。 更具体地说，本发明涉及使用高热载体裂解重质烃原料的方法，其中加入弱酸性位点以改善液体产率并降低焦炭产率。 原料蒸发并与热载体材料接触以产生产物流并将产物流与颗粒状热载体分离，将颗粒状热载体再生至10-30％的程度，并收集气态和液体产物 从产品流。
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公开(公告)号：US09447324B2
公开(公告)日：2016-09-20
申请号：US14878746
申请日：2015-10-08
发明人： Frank Hershkowitz , Paul F. Keusenkothen , Jeffrey W. Frederick , Richard J. Basile , John W. Fulton
IPC分类号： C07C5/35 , C10G9/16 , C10B23/00 , C10B47/02 , C10G9/18 , C07C5/333 , C10G9/26 , B01J19/24 , C07C5/327 , C10B27/06
CPC分类号： C10G9/16 , B01J19/2485 , B01J2219/00164 , B01J2219/2411 , B01J2219/2419 , B01J2219/2434 , C07C5/327 , C07C5/333 , C07C5/35 , C10B23/00 , C10B27/06 , C10B43/10 , C10B47/02 , C10G9/18 , C10G9/26 , C10G2400/20
摘要： The invention relates to a process for converting hydrocarbons into unsaturated products such as acetylene and/or ethylene. The invention also relates to converting acetylene to olefins such as ethylene and/or propylene, to polymerizing the olefins, and to equipment useful for these processes.
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公开(公告)号：US08524159B2
公开(公告)日：2013-09-03
申请号：US13102641
申请日：2011-05-06
申请人： Frank Hershkowitz , Richard John Basile , Jeffrey William Frederick , John William Fulton , Paul F. Keusenkothen , Bryan A. Patel , Andrew Richard Szafran
发明人： Frank Hershkowitz , Richard John Basile , Jeffrey William Frederick , John William Fulton , Paul F. Keusenkothen , Bryan A. Patel , Andrew Richard Szafran
CPC分类号： G06F19/709 , B01J8/0453 , B01J8/048 , B01J8/0484 , B01J8/0492 , C01B3/46 , C01B2203/0216 , C01B2203/0233 , C01B2203/0238 , C01B2203/0266 , C10G9/26
摘要： A reactor with minimal dead volume especially suited to reverse-flow applications comprises: a) a reactor body; b) a first head engaged with said reactor body; c) a first conduit extending from outside said head to at least partially through said head; and d) a first valve in flow communication with said first conduit controlling fluid flow along a flow path extending from the first valve and through the reactor body. The reactor is especially suited for use in a process for rapid stream-switching of at least two streams in a reverse-flow reactor.
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公开(公告)号：US08450552B2
公开(公告)日：2013-05-28
申请号：US12576002
申请日：2009-10-08
CPC分类号： C04B35/488 , B01J4/002 , B01J8/0438 , B01J8/0442 , B01J8/0492 , B01J19/02 , B01J19/2485 , B01J2208/00115 , B01J2208/00309 , B01J2208/00504 , B01J2208/0084 , B01J2208/00849 , B01J2219/00081 , B01J2219/00117 , B01J2219/00157 , B01J2219/00159 , B01J2219/0263 , C04B35/486 , C04B35/505 , C04B2235/3206 , C04B2235/3208 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3232 , C04B2235/3239 , C04B2235/3241 , C04B2235/3244 , C04B2235/3246 , C04B2235/3251 , C04B2235/3256 , C04B2235/3258 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3418 , C04B2235/528 , C04B2235/5296 , C04B2235/5436 , C04B2235/5445 , C04B2235/5472 , C04B2235/5481 , C04B2235/6021 , C04B2235/658 , C04B2235/6584 , C04B2235/72 , C04B2235/762 , C04B2235/77 , C04B2235/96 , C04B2235/9607 , C04B2235/9669 , C04B2235/9684 , C10G1/02 , C10G9/00 , C10G9/005 , C10G9/18 , C10G9/26 , C10G75/00 , Y02P20/582
摘要： In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, the apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C. and which remains in oxide form when exposed to a gas having carbon partial pressure of 10−22 bar, an oxygen partial pressure of 10−10 bar, at a temperature of 1200° C. In some embodiments, the reactor comprises a regenerative pyrolysis reactor apparatus and in other embodiments it includes a reverse flow regenerative reactor apparatus. In other aspects, this invention includes a method for pyrolyzing a hydrocarbon feedstock using a pyrolysis reactor system comprising the step of providing in a heated region of a pyrolysis reactor system for pyrolyzing a hydrocarbon feedstock, apparatus comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C. and that remains in oxide form when exposed to a gas having a carbon partial pressure of 10−22 bar, an oxygen partial pressure of 10−10 bar, at a temperature of 1200° C.
摘要翻译： 在一个方面，本发明包括用于热解烃原料的反应器装置，该装置包括：反应器组件，其包含氧化物形式的耐火材料，耐火材料的熔点至少为2060℃，并保留在氧化物 当暴露于碳分压为10-22巴，氧气分压为10-10巴的气体时，在1200℃的温度下形成。在一些实施方案中，反应器包括再生热解反应器装置，在其它实施方案中 它包括逆流再生反应器装置。 在其他方面，本发明包括使用热解反应器系统热解烃原料的方法，该方法包括在加热区域中提供用于热解烃原料的热解反应器系统，包括氧化物形式的耐火材料的装置，耐火材料 材料具有至少2060℃的熔点，并且当暴露于碳分压为10-22巴，氧分压为10-10巴的气体时，在1200℃的温度下保持为氧化物形式 C。
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公开(公告)号：US08278231B2
公开(公告)日：2012-10-02
申请号：US12277056
申请日：2008-11-24
申请人： Changmin Chun , Frank Hershkowitz
发明人： Changmin Chun , Frank Hershkowitz
IPC分类号： C04B35/482
CPC分类号： C10G9/00 , C04B35/482 , C04B35/486 , C04B38/0006 , C04B2111/00793 , C04B2111/0081 , C04B2235/3201 , C04B2235/3206 , C04B2235/3208 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3232 , C04B2235/3239 , C04B2235/3241 , C04B2235/3246 , C04B2235/3251 , C04B2235/3256 , C04B2235/3258 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3418 , C04B2235/5436 , C04B2235/5445 , C04B2235/5472 , C04B2235/6021 , C04B2235/72 , C04B2235/77 , C04B2235/783 , C04B2235/785 , C04B2235/786 , C04B2235/788 , C04B2235/95 , C04B2235/96 , C10G9/26 , C04B38/0074
摘要： In one aspect, the invention includes a heat stable, formed ceramic component that includes a multimodal grain distribution including (i) at least 50 wt % of coarse grains including stabilized zirconia, the coarse grains comprising a D50 grain size in the range of from 5 to 800 μm, based upon the total weight of the component; and (ii) at least 1 wt % of fine grains comprising a D50 average grain size not greater than one-fourth the D50 grain size of the coarse grain, dispersed within the coarse grains, based upon the total weight of the component; wherein after sintering, the component has porosity at ambient temperature in the range of from 5 to 45 vol. %, based on the formed volume of the component. In other embodiments, the invention includes a process for the manufacture of a hydrocarbon pyrolysis product from a hydrocarbon feed using a regenerative pyrolysis reactor system, comprising the steps of: (a) heating a pyrolysis reactor comprising a bi-modal stabilized zirconia ceramic component to a temperature of at least 1500° C. to create a heated reactive region, wherein after exposing the component to a temperature of at least 1500° C. for two hours the component has a bulk porosity measured at ambient temperature in the range of from 5 to 45 vol. %, based on the bulk volume of the component; (b) feeding a hydrocarbon feed to the heated pyrolysis reactor to pyrolyze the hydrocarbon feed and create a pyrolyzed hydrocarbon feed; and (c) quenching the pyrolyzed hydrocarbon feed to produce the hydrocarbon pyrolysis product.
摘要翻译： 在一个方面，本发明包括一种热稳定的成形陶瓷组分，其包括多峰晶粒分布，其包括（i）至少50重量％的包含稳定的氧化锆的粗晶粒，所述粗晶粒包含D50晶粒尺寸在5 至800μm，基于组分的总重量; 和（ii）基于组分的总重量，至少1重量％的包含分散在粗晶粒内的D50平均粒径不大于粗晶粒的D50晶粒尺寸的四分之一的细晶粒; 其中烧结后，该组分在环境温度下具有5至45体积％的孔隙率。 ％，基于组成的体积。 在其它实施方案中，本发明包括使用再生热解反应器系统从烃进料制造烃热解产物的方法，包括以下步骤：（a）将包含双稳态氧化锆陶瓷组分的热解反应器加热至 至少1500℃的温度以产生加热的反应性区域，其中在将组分暴露于至少1500℃的温度两小时之后，该组分具有在环境温度下测量的体积孔隙，范围为5 至45体积 ％，基于组件的批量; （b）将烃进料加入到加热的热解反应器中以使烃进料热解并产生热解的烃进料; 和（c）淬灭热解的烃进料以产生烃热解产物。
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6.发明授权
公开(公告)号：US4008147A
公开(公告)日：1977-02-15
申请号：US456145
申请日：1974-03-29
申请人： Masaki Kondo
发明人： Masaki Kondo
CPC分类号： C10G9/26
摘要： A method for treatment of the heavy hydrocarbonaceous fraction resulting from thermal cracking of high molecular-weight hydrocarbonaceous materials, which method comprises removing light hydrocarbons contained in said fraction by bringing it into contact with a bed packed with refractory inorganic particles at an elevated temperature so as to evaporate said light hydrocarbons and regenerating said refractory inorganic particles-packed bed by incinerating heavy hydrocarbonaceous materials remaining on and/or among said particles in the bed by supplying oxygen to the bed.
摘要翻译： 一种处理由高分子量含烃材料的热裂解产生的重质烃馏分的方法，该方法包括通过在高温下使其与填充有耐火无机颗粒的床接触来除去所述馏分中所含的轻质烃，以便 蒸发所述轻质烃并再生所述耐火无机颗粒填充床，通过向所述床中供应氧来焚烧残留在床中和/或所述颗粒之间的重质烃类材料。
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公开(公告)号：US3649212A
公开(公告)日：1972-03-14
申请号：US3649212D
申请日：1969-12-29
申请人： MARATHON OIL CO
发明人： OLESZKO THADDEUS J , WALKER LYNN P
CPC分类号： C10G9/00 , C10G9/26 , Y10S585/924
摘要： A pyrolysis furnace such as a Wulff furnace having an octagonal baffle in each of the combustion chambers, located so that the longitudinal axis of the baffle is between the fuel inlets of the combustion chamber and the center refractory mass which separates two combustion chambers.
摘要翻译： 一种热解炉，例如在每个燃烧室中具有八角形挡板的瓦尔夫炉，其位于使得挡板的纵向轴线位于燃烧室的燃料入口和分离两个燃烧室的中心耐火材料块之间。
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公开(公告)号：US3629353A
公开(公告)日：1971-12-21
申请号：US3629353D
申请日：1969-10-08
申请人： ROBERT H REITSEMA , LYNN P WALKER
发明人： REITSEMA ROBERT H , WALKER LYNN P
CPC分类号： C10G9/26 , C10G2400/20
摘要： THE PRESENT INVENTION COMPRISES, IN A PROCESS FOR THE PYROLYSIS OF NAPHTHA, THE IMPROVEMENT CONSISTING ESSENTIALLY OF FEEDING FROM ABOUT 1.5 TO ABOUT 2.2 POUNDS OF STEAM PER POUND OF NAPHTHA FED TO THE PYROLYSIS FURNACE WHILE FEEDING ABOUT 4.0 TO ABOUT 6.5 POUNDS PER MINUTE OF HYDROCARBONS PER SQUARE FOOT OF CROSS SECTIONAL AREA OF SAID FURNACE.
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公开(公告)号：US3607154A
公开(公告)日：1971-09-21
申请号：US3607154D
申请日：1969-11-06
CPC分类号： C10G9/26 , C10G2400/26
摘要： An apparatus and process for producing a combustible oil gas as a supplement to heating gas from a gas generator comprising a bed of curved elongated refractory bodies composed of silicon carbide material having a high thermal conductivity superimposed upon a layer of refractory grid tile capable of withstanding over 3,000* F., the bed being of a thickness of 0.05-0.5 times the diameter of the shell of the gas generator containing the refractory bed, each body having a curved surface with a diameter between 0.5 to 0.08 times the bed thickness and a length approximately 0.2 to 1.0 times the bed thickness, the bed being directly exposed to form the bottom of a combustion chamber within the gas machine so as to absorb thermal shock and to preserve the conventional refractory brick tile from fusing and spalling and restricting the flow of gas through the refractory bed as well as to maintain a rapid heating oil ignition to avoid explosions within the refractory bed.
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公开(公告)号：US3539162A
公开(公告)日：1970-11-10
申请号：US3539162D
申请日：1968-11-13
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