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    Process for ethylbenzene production
    91.
    发明授权
    Process for ethylbenzene production 有权
    乙苯生产工艺

    公开(公告)号：US08865958B2

    公开(公告)日：2014-10-21

    申请号：US12568007

    申请日：2009-09-28

    Applicant: James R. Butler

    Inventor： James R. Butler

    IPC: C07C2/66

    CPC classification number: C07C2/66 ,  C07C2529/70 ,  Y02P20/584 ,  C07C15/073

    Abstract: A method of producing an alkylaromatic by the alkylation of an aromatic with an alkylating agent, such as producing ethylbenzene by an alkylation reaction of benzene, is disclosed. The method includes using an H-beta catalyst to minimize process upsets due to alkylation catalyst deactivation and the resulting catalyst regeneration or replacement. The H-beta catalyst can be used in a preliminary alkylation reactor that is located upstream of the primary alkylation reactor. The H-beta catalyst used in a preliminary alkylation reactor can reduce the deactivation of the catalyst in the primary alkylation reactor.

    Abstract translation: 公开了通过用烷基化剂烷基化烷基化制备烷基芳族化合物的方法，例如通过苯的烷基化反应制备乙苯。 该方法包括使用H-β催化剂来最小化由于烷基化催化剂失活和所得到的催化剂再生或置换导致的过程紊乱。 H-β催化剂可用于位于初级烷基化反应器上游的初步烷基化反应器。 在初步烷基化反应器中使用的H-β催化剂可以减少初级烷基化反应器中催化剂的失活。

    Dilute Liquid Phase Alkylation
    92.
    发明申请
    Dilute Liquid Phase Alkylation 有权
    稀液相烷基化

    公开(公告)号：US20130184508A1

    公开(公告)日：2013-07-18

    申请号：US13785851

    申请日：2013-03-05

    Applicant: James R. Butler

    Inventor： James R. Butler

    IPC: C07C2/66

    CPC classification number: C07C2/66 ,  C07C2523/10 ,  C07C2529/08 ,  C07C2529/70 ,  C07C15/073

    Abstract: Methods of forming ethylbenzene are described herein. In one embodiment, the method includes contacting dilute ethylene with benzene in the presence of an alkylation catalyst to form ethylbenzene, wherein such contact occurs in a liquid phase reaction zone and recovering ethylbenzene from the reaction zone.

    Abstract translation: 本文描述了形成乙苯的方法。 在一个实施方案中，该方法包括在烷基化催化剂存在下使稀乙烯与苯接触以形成乙苯，其中这种接触发生在液相反应区中并从反应区回收乙苯。

    Process for catalyst regeneration and extended use
    93.
    发明授权
    Process for catalyst regeneration and extended use 有权
    催化剂再生和延长使用的方法

    公开(公告)号：US08455383B2

    公开(公告)日：2013-06-04

    申请号：US12765119

    申请日：2010-04-22

    Applicant: James R. Butler

    Inventor： James R. Butler

    IPC: B01J38/56

    CPC classification number: C07C2/66 ,  Y02P20/584 ,  C07C15/073

    Abstract: A method of producing an alkylaromatic by the alkylation of an aromatic with an alkylating agent, such as producing ethylbenzene by an alkylation reaction of benzene, is disclosed. The method includes using an H-beta catalyst to minimize process upsets due to alkylation catalyst deactivation and the resulting catalyst regeneration or replacement. The H-beta catalyst can be used in a preliminary alkylation reactor that is located upstream of the primary alkylation reactor. The H-beta catalyst used in a preliminary alkylation reactor can lead to the reactivation of the catalyst in the primary alkylation reactor.

    Abstract translation: 公开了通过用烷基化剂烷基化烷基化制备烷基芳族化合物的方法，例如通过苯的烷基化反应制备乙苯。 该方法包括使用H-β催化剂来最小化由于烷基化催化剂失活和所得到的催化剂再生或置换导致的过程紊乱。 H-β催化剂可用于位于初级烷基化反应器上游的初步烷基化反应器。 在初步烷基化反应器中使用的H-β催化剂可导致催化剂在一级烷基化反应器中的再活化。

    METHOD FOR ALKYLATION OF TOLUENE IN A PRE-EXISTING DEHYDROGENATION PLANT
    95.
    发明申请
    METHOD FOR ALKYLATION OF TOLUENE IN A PRE-EXISTING DEHYDROGENATION PLANT 审中-公开
    在先前脱氢植物中氧化钛的方法

    公开(公告)号：US20120296131A1

    公开(公告)日：2012-11-22

    申请号：US13457507

    申请日：2012-04-27

    Applicant: James R. Butler ,  Sivadinarayana Chinta ,  Joseph E. Pelati

    Inventor： James R. Butler ,  Sivadinarayana Chinta ,  Joseph E. Pelati

    IPC: C07C2/88

    CPC classification number: C07C5/333 ,  C07C2/862 ,  C07C15/46 ,  C07C15/073

    Abstract: A process for making styrene in a pre-existing facility including an infrastructure capable of producing styrene, wherein the infrastructure includes at least one dehydrogenation unit. The process includes coupling an alkylation unit including an alkylation reactor to the infrastructure and contacting toluene with a C1 source in the presence of a first catalyst and a co-feed in the alkylation reactor to form a first product stream comprising styrene and ethylbenzene. The styrene and ethylbenzene from the first product stream are routed for further processing to a portion of the pre-existing facility.

    Abstract translation: 一种在预先存在的设施中制备苯乙烯的方法，包括能够生产苯乙烯的基础设施，其中基础设施包括至少一个脱氢单元。 该方法包括将包括烷基化反应器的烷基化单元与基础设施偶联，并在烷基化反应器中在第一催化剂和共进料存在下将甲苯与C1源接触以形成包含苯乙烯和乙苯的第一产物流。 来自第一产物流的苯乙烯和乙苯被路由以进一步处理到一部分预先存在的设施。

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