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    Process for ethylbenzene production
    1.
    发明授权
    Process for ethylbenzene production 有权

    公开(公告)号：US08802911B2

    公开(公告)日：2014-08-12

    申请号：US13868505

    申请日：2013-04-23

    Applicant: James R. Butler

    Inventor： James R. Butler

    IPC: C07C2/66

    CPC classification number: C07C2/66 ,  C07C2529/70 ,  Y02P20/584 ,  C07C15/073

    Abstract: A method of producing an alkylaromatic by the alkylation of an aromatic with an alkylating agent, such as producing ethylbenzene by an alkylation reaction of benzene, is disclosed. The method includes using an H-beta catalyst to minimize process upsets due to alkylation catalyst deactivation and the resulting catalyst regeneration or replacement. The H-beta catalyst can be used in a preliminary alkylation reactor that is located upstream of the primary alkylation reactor. The H-beta catalyst used in a preliminary alkylation reactor can reduce the deactivation of the catalyst in the primary alkylation reactor.

    Dilute ethylene alkylation of benzene
    3.
    发明授权
    Dilute ethylene alkylation of benzene 有权
    苯稀释乙烯烷基化

    公开(公告)号：US08742190B2

    公开(公告)日：2014-06-03

    申请号：US13178091

    申请日：2011-07-07

    Applicant: James R. Butler

    Inventor： James R. Butler

    IPC: C07C2/66

    CPC classification number: C07C2/66 ,  C07C2523/10 ,  C07C2529/06 ,  C07C2529/08 ,  C07C2529/70 ,  C07C15/073

    Abstract: Methods of forming ethylbenzene are described herein. In one embodiment, the method includes contacting dilute ethylene with benzene in the presence of an alkylation catalyst to form ethylbenzene, wherein such contact occurs in a reaction zone containing a gaseous phase and recovering ethylbenzene from the reaction zone.

    Abstract translation: 本文描述了形成乙苯的方法。 在一个实施方案中，该方法包括在烷基化催化剂存在下使稀乙烯与苯接触以形成乙苯，其中这种接触在含有气相的反应区中发生并从反应区回收乙苯。

    Production of EB from toluene and methane
    4.
    发明授权
    Production of EB from toluene and methane 有权
    从甲苯和甲烷生产EB

    公开(公告)号：US08734737B2

    公开(公告)日：2014-05-27

    申请号：US13604760

    申请日：2012-09-06

    Applicant: James R. Butler ,  Joseph E. Pelati

    Inventor： James R. Butler ,  Joseph E. Pelati

    IPC: B01J8/04

    CPC classification number: C07C15/46 ,  C07C2/66 ,  C07C2/84 ,  C07C5/48 ,  Y10S585/921 ,  Y10S585/943 ,  C07C15/073

    Abstract: A process for making ethylbenzene and/or styrene by reacting toluene with methane is disclosed. In one embodiment the process can include reacting toluene with methane to form a product stream comprising ethylbenzene and further processing the ethylbenzene to form styrene in an existing styrene production facility.

    Abstract translation: 公开了通过使甲苯与甲烷反应制备乙苯和/或苯乙烯的方法。 在一个实施方案中，该方法可以包括使甲苯与甲烷反应以形成包含乙苯的产物流，并进一步处理乙苯以在现有的苯乙烯生产设备中形成苯乙烯。

    Oxidative coupling of hydrocarbons as heat source
    5.
    发明授权
    Oxidative coupling of hydrocarbons as heat source 有权
    碳氢化合物作为热源的氧化偶联

    公开(公告)号：US08710286B2

    公开(公告)日：2014-04-29

    申请号：US12416074

    申请日：2009-03-31

    Applicant: James R. Butler

    Inventor： James R. Butler

    IPC: C07C2/78

    CPC classification number: C07C4/025 ,  C07C2/82 ,  C07C5/327 ,  C07C11/04 ,  C07C15/46

    Abstract: A process for the coupling of hydrocarbons and utilizing the heat energy produced by the reaction is disclosed. In one embodiment the process can include reacting methane with oxygen to form a product stream containing ethane and further processing the ethane to ethylene in an existing ethylene production facility while using the heat energy produced by the reaction within the facility.

    Abstract translation: 公开了一种用于偶联烃并利用由反应产生的热能的方法。 在一个实施方案中，该方法可以包括使甲烷与氧反应形成含有乙烷的产物流，并且在现有乙烯生产设备中进一步处理乙烯至乙烯，同时使用由设备内的反应产生的热能。

    Process for the reduction of alkylation catalyst deactivation
    7.
    发明授权
    Process for the reduction of alkylation catalyst deactivation 有权
    降低烷基化催化剂失活的方法

    公开(公告)号：US08552238B2

    公开(公告)日：2013-10-08

    申请号：US13863722

    申请日：2013-04-16

    Applicant: James R. Butler ,  Xin Xiao ,  James T. Merrill

    Inventor： James R. Butler ,  Xin Xiao ,  James T. Merrill

    IPC: C07C2/66

    CPC classification number: C07C2/66 ,  B01J29/06 ,  B01J29/7057 ,  B01J2219/00006 ,  C07C6/126 ,  C07C7/12 ,  C07C15/073 ,  C07C2529/08 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P20/588 ,  C07C15/04

    Abstract: Alkylation systems and methods of minimizing alkylation catalyst regeneration are described herein. The alkylation systems generally include a preliminary alkylation system adapted to receive an input stream including an alkyl aromatic hydrocarbon and contact the input stream with a preliminary alkylation catalyst disposed therein to form a first output stream. The preliminary alkylation catalyst generally includes a zeolite catalyst having a SiO2/Al2O3 ratio of less than about 25. The alkylation systems further include a first alkylation system adapted to receive the first output stream and contact the first output stream with a first alkylation catalyst disposed therein and an alkylating agent to form a second output stream.

    Abstract translation: 本文描述了使烷基化催化剂再生最小化的烷基化系统和方法。 烷基化系统通常包括适于接收包含烷基芳族烃的输入流并将输入流与设置在其中的预置烷基化催化剂接触以形成第一输出流的初步烷基化系统。 初步烷基化催化剂通常包括SiO 2 / Al 2 O 3比小于约25的沸石催化剂。烷基化系统还包括适于接收第一输出流并将第一输出流与置于其中的第一烷基化催化剂接触的第一烷基化系统 和烷基化剂以形成第二输出流。

    Vaporization and Transportation of Alkali Metal Salts
    8.
    发明申请
    Vaporization and Transportation of Alkali Metal Salts 有权
    碱金属盐的汽化和运输

    公开(公告)号：US20130165722A9

    公开(公告)日：2013-06-27

    申请号：US12685892

    申请日：2010-01-12

    Applicant: Joseph E. Pelati ,  James R. Butler ,  Hollie Craig

    Inventor： Joseph E. Pelati ,  James R. Butler ,  Hollie Craig

    IPC: C07C5/367 ,  B01F3/02 ,  B01F5/00 ,  B01D1/14 ,  B01F3/04

    CPC classification number: B01F5/0403 ,  B01B1/005 ,  B01D7/00 ,  B01F5/045 ,  B01J4/001 ,  B01J8/02 ,  B01J38/06 ,  B01J38/64 ,  C07C5/32

    Abstract: An apparatus and method for vaporizing and transporting an alkali metal salt is shown. The apparatus has a first conduit capable of transporting an alkali metal salt solution and a second conduit in fluid communication with the first conduit, the second conduit capable of transporting steam so that the alkali metal salt is dissipated into the steam forming a solution that can be transported, such as to a remote reaction zone. The solution can be transported via a third conduit that is capable of being heated by a heat source. The method can be used to add a promoter to a dehydrogenation catalyst during a dehydrogenation reaction.

    Abstract translation: 示出了用于蒸发和运输碱金属盐的装置和方法。 该设备具有能够输送碱金属盐溶液的第一导管和与第一导管流体连通的第二导管，第二导管能够输送蒸汽，使得碱金属盐被散发到形成可以是 运送到远程反应区。 该溶液可以经由能够被热源加热的第三导管输送。 该方法可用于在脱氢反应期间向脱氢催化剂中加入助催化剂。

    Dilute liquid phase alkylation
    10.
    发明授权
    Dilute liquid phase alkylation 有权
    稀液相烷基化

    公开(公告)号：US08426661B2

    公开(公告)日：2013-04-23

    申请号：US13024602

    申请日：2011-02-10

    Applicant: James R. Butler

    Inventor： James R. Butler

    IPC: C07C2/66 ,  C07C6/12

    CPC classification number: C07C2/66 ,  C07C2523/10 ,  C07C2529/08 ,  C07C2529/70 ,  C07C15/073

    Abstract: Methods of forming ethylbenzene are described herein. In one embodiment, the method includes contacting dilute ethylene with benzene in the presence of an alkylation catalyst to form ethylbenzene, wherein such contact occurs in a liquid phase reaction zone and recovering ethylbenzene from the reaction zone.

    Abstract translation: 本文描述了形成乙苯的方法。 在一个实施方案中，该方法包括在烷基化催化剂存在下使稀乙烯与苯接触以形成乙苯，其中这种接触发生在液相反应区中并从反应区回收乙苯。

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