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公开(公告)号：US06833959B2
公开(公告)日：2004-12-21
申请号：US10781402
申请日：2004-02-18
申请人： Roger W. Phillips
发明人： Roger W. Phillips
IPC分类号： G02B110
CPC分类号： G02B5/287 , C01P2004/88 , C09C1/0015 , C09C1/0021 , C09C2200/1004 , C09C2200/1037 , C09C2200/1087 , C09C2200/301 , C09C2200/303 , C09C2200/304 , C09C2200/306 , C09C2220/20 , C09D5/36 , C23C14/0005 , C23C14/0015 , C23C16/006 , C23C16/01 , G02B5/285 , G02B5/286
摘要： A color shifting multilayer interference film is provided which may be used to produce foils or flakes for use in pigment compositions and colorants having color shifting properties. The flakes can be interspersed into a pigment medium to form paints, inks, or cosmetic preparations which can subsequently be applied to objects, papers, or people. Three and five layer designs of the interference film include alternating layers of a dielectric material and carbon in various configurations. The dielectric layers are formed to have an optical thickness at a design wavelength that provides a color shift as the angle of incident light or viewing angle changes.
摘要翻译： 提供了一种颜色偏移多层干涉膜，其可用于生产用于颜料组合物和具有色移特性的着色剂的箔或薄片。 片状物可以散布在颜料介质中，形成可随后应用于物体，纸张或人物的油漆，油墨或化妆品制剂。 干涉膜的三层和五层设计包括各种构造的介电材料和碳的交替层。 电介质层形成为具有在入射光的角度或视角变化时提供色移的设计波长的光学厚度。
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公开(公告)号：US06751022B2
公开(公告)日：2004-06-15
申请号：US10355545
申请日：2003-01-31
申请人： Roger W. Phillips
发明人： Roger W. Phillips
IPC分类号： G02B2700
CPC分类号： G02B5/287 , C01P2004/88 , C09C1/0015 , C09C1/0021 , C09C2200/1004 , C09C2200/1037 , C09C2200/1087 , C09C2200/301 , C09C2200/303 , C09C2200/304 , C09C2200/306 , C09C2220/20 , C09D5/36 , C23C14/0005 , C23C14/0015 , C23C16/006 , C23C16/01 , G02B5/285 , G02B5/286
摘要： A color shifting multilayer interference film is provided which may be used to produce foils or flakes for use in pigment compositions and colorants having color shifting properties. The flakes can be interspersed into a pigment medium to form paints, inks, or cosmetic preparations which can subsequently be applied to objects, papers, or people. Three and five layer designs of the interference film include alternating layers of a dielectric material and carbon in various configurations. The dielectric layers are formed to have an optical thickness at a design wavelength that provides a color shift as the angle of incident light or viewing angle changes.
摘要翻译： 提供了一种颜色偏移多层干涉膜，其可用于生产用于颜料组合物和具有色移特性的着色剂的箔或薄片。 片状物可以散布在颜料介质中，形成可随后应用于物体，纸张或人物的油漆，油墨或化妆品制剂。 干涉膜的三层和五层设计包括各种构造的介电材料和碳的交替层。 电介质层形成为具有在入射光的角度或视角变化时提供色移的设计波长的光学厚度。
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公开(公告)号：US06545809B1
公开(公告)日：2003-04-08
申请号：US09420717
申请日：1999-10-20
申请人： Roger W. Phillips
发明人： Roger W. Phillips
IPC分类号： G02B2700
CPC分类号： G02B5/287 , C01P2004/88 , C09C1/0015 , C09C1/0021 , C09C2200/1004 , C09C2200/1037 , C09C2200/1087 , C09C2200/301 , C09C2200/303 , C09C2200/304 , C09C2200/306 , C09C2220/20 , C09D5/36 , C23C14/0005 , C23C14/0015 , C23C16/006 , C23C16/01 , G02B5/285 , G02B5/286
摘要： A color shifting multilayer interference film is provided which may be used to produce foils or flakes for use in pigment compositions and colorants having color shifting properties. The flakes can be interspersed into a pigment medium to form paints, inks, or cosmetic preparations which can subsequently be applied to objects, papers, or people. Three and five layer designs of the interference film include alternating layers of a dielectric material and carbon in various configurations. The dielectric layers are formed to have an optical thickness at a design wavelength that provides a color shift as the angle of incident light or viewing angle changes.
摘要翻译： 提供了一种颜色偏移多层干涉膜，其可用于生产用于颜料组合物和具有色移特性的着色剂的箔或薄片。 片状物可以散布在颜料介质中，形成可随后应用于物体，纸张或人物的油漆，油墨或化妆品制剂。 干涉膜的三层和五层设计包括各种构造的介电材料和碳的交替层。 电介质层形成为具有在入射光的角度或视角变化时提供色移的设计波长的光学厚度。
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公开(公告)号：US6150022A
公开(公告)日：2000-11-21
申请号：US207121
申请日：1998-12-07
CPC分类号： C09C1/0021 , C09C1/0015 , C09C1/0024 , C09C1/003 , C09C1/0051 , C09C1/0057 , C01P2004/20 , C01P2004/84 , C09C2200/1004 , C09C2200/1054 , C09C2200/1058 , C09C2200/1087 , C09C2200/24 , C09C2200/301 , C09C2200/302 , C09C2200/303 , C09C2200/304 , C09C2200/306 , C09C2210/10 , C09C2220/20 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.
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公开(公告)号：US5383995A
公开(公告)日：1995-01-24
申请号：US146834
申请日：1993-10-29
申请人： Roger W. Phillips , Thomas Mayer , Gary S. Ash
发明人： Roger W. Phillips , Thomas Mayer , Gary S. Ash
IPC分类号： B05D1/28 , B05D5/06 , B41M3/00 , B41M3/14 , C03C17/00 , C09C1/00 , C09D11/00 , F24J2/48 , B44C1/165
CPC分类号： C09C1/0051 , B05D1/286 , B05D5/06 , B41M3/00 , B41M3/14 , C03C17/00 , C09C1/0015 , C09C1/0078 , C09D11/50 , F24J2/485 , C01P2004/54 , C09C2200/24 , C09C2210/10 , C09C2220/10 , C09C2220/20 , Y02E10/40
摘要： Articles and methods for forming optically variable thin film flakes and replicated coatings having preselected optical properties. The articles generally comprise a flexible web of material and an optically variable thin film coating formed on one surface of the web. The optically variable coating is separated from the web to form optically variable thin film flakes. The flakes are disposed in ink and paint vehicles to provide optically variable inks, paints and the like.
摘要翻译： 用于形成具有预选光学性质的光学可变薄膜薄片和复制涂层的制品和方法。 制品通常包括形成在幅材的一个表面上的柔性材料幅材和可变光薄膜涂层。 将光学可变涂层与纤维网分离以形成光学可变的薄膜薄片。 将薄片放置在油墨和油漆车辆中以提供光学可变的油墨，油漆等。
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公开(公告)号：US5059245A
公开(公告)日：1991-10-22
申请号：US251034
申请日：1988-09-26
申请人： Roger W. Phillips , Thomas Mayer , Gary S. Ash
发明人： Roger W. Phillips , Thomas Mayer , Gary S. Ash
IPC分类号： B05D1/28 , B05D5/06 , B41M3/00 , B41M3/14 , B44F1/12 , C03C17/00 , C09C1/00 , C09D11/00 , F24J2/48
CPC分类号： C09C1/0051 , B05D1/286 , B05D5/06 , B41M3/00 , B41M3/14 , C03C17/00 , C09C1/0015 , C09C1/0078 , C09D11/50 , F24J2/485 , C01P2004/51 , C01P2004/54 , C09C2200/1054 , C09C2200/24 , C09C2220/20 , Y02E10/40
摘要： Optically variable ink for obtaining a color shaft between two distinct two colors at first and second angles of incident light comprised of an ink vehicle and optically variable flakes disposed in the ink vehicle. The optically variable flakes are comprised of a multilayer thin film interference structure having first and second parallel planar surfaces. The optically variable flakes have physical dimensions such that when the flakes are measured in directions parallel and perpendicular respectively to the planar surfaces an aspect ratio of at least 2 to 1 is provided. The multilayer thin film structure is of symmetrical design and includes a metal reflector having first and second surfaces parallel to the first and second parallel planar surfaces and at least one period disposed on each of said first and second surfaces of the metal reflector. Each period is comprised of a dielectric layer with an index of refraction of 1.65 or less and a semi-opaque layer.
摘要翻译： 光学可变墨水，用于在由油墨载体和设置在墨水载体中的光学可变薄片构成的入射光的第一和第二角度处获得两种不同的两种颜色之间的颜色轴。 光学可变薄片包括具有第一和第二平行平面的多层薄膜干涉结构。 光学可变薄片具有物理尺寸，使得当薄片分别在平面和垂直平面上垂直的方向测量时，提供至少2比1的纵横比。 所述多层薄膜结构是对称设计的，并且包括具有平行于所述第一和第二平行平面的第一和第二表面的金属反射器以及设置在所述金属反射器的所述第一和第二表面的每一个上的至少一个周期。 每个周期由折射率为1.65或更小的介电层和半不透明层组成。
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97.发明授权Thin film optical variable article having substantial color shift with angle and method 失效薄膜光学可变制品具有显着的颜色偏移角度和方法
公开(公告)号：US4705356A
公开(公告)日：1987-11-10
申请号：US630414
申请日：1984-07-13
CPC分类号： G02B5/288 , G02B5/223 , G06K19/06046 , Y10S283/902
摘要： Thin film optically variable article having substantial color shift with varying angle of light incidence and viewing and including an optically thick, substantially transparent element carrying a colorant and having first and second surfaces. A multilayer interference coating is carried on one of said first and second surfaces. The colorant serves to modify in essentially a subtractive mode the color at normal incidence and the color shift with angle of the multilayer interference coating as seen by reflection or transmission.
摘要翻译： 薄膜光学可变制品具有具有变化的光入射角和观察角度的显着色移，并且包括带有着色剂并具有第一和第二表面的光学厚的基本上透明的元件。 所述第一表面和第二表面中的一个上承载多层干涉涂层。 着色剂用于在基本上减法模式下修改在反射或透射下观察到的多层干涉涂层在正常入射时的颜色和颜色偏移。
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98.发明授权
公开(公告)号：US4705300A
公开(公告)日：1987-11-10
申请号：US935065
申请日：1986-11-21
IPC分类号： B42D15/00
CPC分类号： B42D25/29
摘要： Thin film optical variable article to be used in a reflection mode having a gold to green color shift with angle for currency authentication and adapted to be carried by a substantially opaque currency sheet which serves as a substrate. The article includes a substantially transparent, optically thick element carrying a subtractive colorant and having first and second surfaces and a multilayer interference coating carried on one of said first and second surfaces. The article is adapted to be carried by the currency sheet so that the coating faces the currency sheet and the colorant carrying element serves as a superstrate facing the incident light. The multilayer interference coating is comprised of a substantially opaque layer of aluminum nearest the substrate, followed by a layer of magnesium fluoride, and then by a layer of chromium having substantial transmission. The colorant has a yellow hue. At normal incidence of light the article has a coppery-gold color shifting towards a vivid green at non-normal incidence of light. The colorant operates in an essentially subtractive mode in combination with the multilayer interference coating to provide the color shift from gold to green at two different angles of incidence and substantially no color at higher angles of incidence to cause a modification of the normal incidence gold color and the color shift with angle properties as seen by reflection.
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99.发明授权
公开(公告)号：US4565719A
公开(公告)日：1986-01-21
申请号：US433511
申请日：1982-10-08
CPC分类号： C03C17/3605 , C03C17/36 , C03C17/3613 , C03C17/3618 , C03C17/3644 , C03C17/366 , C03C17/3681 , C03C2217/78 , Y10T428/24975 , Y10T428/31678 , Y10T428/31681
摘要： An energy control sheet, including a highly transparent substructure having first and second surfaces, a substantially transparent, thin film metal layer formed on one surface of the substructure, and a highly transparent thin film dielectric layer formed over said metal layer. The dielectric layer comprises a mixed metal oxide layer having metal constituents of at least one lanthanide series metal (e.g. cerium oxide) and at least one transition or semiconductor metal (e.g. tin oxide). The dielectric layer is characterized by substantial water vapor impermeability so that the weatherability of the energy control sheet is substantially improved. The metal layer is either a silver layer or a silver-palladium alloy.
摘要翻译： 一种能量控制片，包括具有第一和第二表面的高度透明的子结构，形成在所述子结构的一个表面上的基本上透明的薄膜金属层，以及形成在所述金属层上的高透明薄膜电介质层。 电介质层包括具有至少一种镧系金属（例如氧化铈）和至少一种过渡金属或半导体金属（例如氧化锡）的金属成分的混合金属氧化物层。 电介质层的特征在于显着的水蒸气不渗透性，使得能量控制片的耐候性显着提高。 金属层是银层或银 - 钯合金。
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公开(公告)号：US4524953A
公开(公告)日：1985-06-25
申请号：US370874
申请日：1982-04-22
申请人： Roger W. Phillips , Ann L. Phillips
发明人： Roger W. Phillips , Ann L. Phillips
CPC分类号： E01F13/028 , E04H6/42
摘要： A protective crowd control barrier for maintaining observers in spaced relationship to an article being displayed such as an automobile or the like in which the barrier includes a plurality of adjustable uprights which receive a flexible barrier member in a manner such that the flexible member is spaced from and extends entirely around the article. The uprights are selectively adjustable to alter the elevation as well as the spacing of the barrier member from the article being displayed.
摘要翻译： 一种保护性人群控制屏障，用于将观察者维持在与正在显示的物品间隔开的关系中，例如汽车等，其中障碍物包括多个可调节的立柱，其以使得柔性构件与柔性构件间隔开的方式容纳柔性屏障构件 并完全围绕物品延伸。 立柱可选择性地调节，以改变屏障构件的高度以及所显示物品的间隔。
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