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    Optically variable flakes paint and article
    3.
    发明授权
    Optically variable flakes paint and article 失效
    光学可变薄片油漆和制品

    公开(公告)号：US5653792A

    公开(公告)日：1997-08-05

    申请号：US348562

    申请日：1994-12-02

    申请人： Roger W. Phillips ,  Thomas Mayer ,  Gary S. Ash

    发明人： Roger W. Phillips ,  Thomas Mayer ,  Gary S. Ash

    IPC分类号： B05D1/28 ,  B05D5/06 ,  B41M3/00 ,  B41M3/14 ,  C03C17/00 ,  C09C1/00 ,  C09D11/00 ,  F24J2/48 ,  C04B14/00

    CPC分类号： C09C1/0051 ,  B05D1/286 ,  B05D5/06 ,  B41M3/00 ,  B41M3/14 ,  C03C17/00 ,  C09C1/0015 ,  C09C1/0078 ,  C09D11/50 ,  F24J2/485 ,  C01P2004/54 ,  C09C2200/24 ,  C09C2210/10 ,  C09C2220/10 ,  C09C2220/20 ,  Y02E10/40

    摘要： An article with a surface with a paint film adherent thereto having a liquid medium hardened into a solid to form said paint film and having first and second parallel surfaces with the first parallel surface being adhered to the surface of the article and the second surface exposed to be viewed by the human eye. A plurality of flakes are provided having first and second planar parallel surfaces lying in said paint film with the first and second planar parallel surfaces being parallel to the first and second parallel surfaces of the paint film. The flakes are characterized in that they have physical dimensions such that when the dimensions of the flakes are measured parallel to and perpendicular to the respective first and second planar parallel surfaces, an aspect ratio of at least two-to-one is provided. Each of the flakes has a symmetrical optically variable multilayer thin film interference structure including at least one thick substantially opaque metal reflecting layer having first and second surfaces and a multilayer thin film including at least one thin semi-transparent metal layer and at least one dielectric layer formed of an inorganic material with an index of refraction of 1.65 or less and disposed on each side of the substantially opaque metal reflecting layer. The multilayer thin film structure produces a shift in color between two distinct colors when the angle of incident light on the paint film is shifted between two different angles.

    摘要翻译： 具有附着有涂膜的表面的物品具有硬化成固体的液体介质以形成所述漆膜并且具有第一和第二平行表面，其中第一平行表面粘附到物品的表面，而第二表面暴露于 被人眼看。 提供多个薄片，其具有位于所述漆膜中的第一和第二平面平行表面，其中第一和第二平面平行表面平行于漆膜的第一和第二平行表面。 薄片的特征在于它们具有物理尺寸，使得当薄片的尺寸平行于并垂直于相应的第一和第二平面平行表面测量时，提供至少两对一的纵横比。 每个薄片具有对称的可变多层薄膜干涉结构，其包括至少一个具有第一表面和第二表面的基本上不透明的厚度的金属反射层，以及包括至少一个薄的半透明金属层和至少一个介电层 由折射率为1.65以下的无机材料形成，并设置在基本上不透明的金属反射层的每一侧。 当涂膜上的入射光的角度在两个不同的角度之间移动时，多层薄膜结构产生两种不同颜色之间的颜色偏移。

    Ink incorporating optically variable thin film flakes
    8.
    发明授权
    Ink incorporating optically variable thin film flakes 失效
    包含光学可变薄膜片的墨水

    公开(公告)号：US5059245A

    公开(公告)日：1991-10-22

    申请号：US251034

    申请日：1988-09-26

    申请人： Roger W. Phillips ,  Thomas Mayer ,  Gary S. Ash

    发明人： Roger W. Phillips ,  Thomas Mayer ,  Gary S. Ash

    IPC分类号： B05D1/28 ,  B05D5/06 ,  B41M3/00 ,  B41M3/14 ,  B44F1/12 ,  C03C17/00 ,  C09C1/00 ,  C09D11/00 ,  F24J2/48

    CPC分类号： C09C1/0051 ,  B05D1/286 ,  B05D5/06 ,  B41M3/00 ,  B41M3/14 ,  C03C17/00 ,  C09C1/0015 ,  C09C1/0078 ,  C09D11/50 ,  F24J2/485 ,  C01P2004/51 ,  C01P2004/54 ,  C09C2200/1054 ,  C09C2200/24 ,  C09C2220/20 ,  Y02E10/40

    摘要： Optically variable ink for obtaining a color shaft between two distinct two colors at first and second angles of incident light comprised of an ink vehicle and optically variable flakes disposed in the ink vehicle. The optically variable flakes are comprised of a multilayer thin film interference structure having first and second parallel planar surfaces. The optically variable flakes have physical dimensions such that when the flakes are measured in directions parallel and perpendicular respectively to the planar surfaces an aspect ratio of at least 2 to 1 is provided. The multilayer thin film structure is of symmetrical design and includes a metal reflector having first and second surfaces parallel to the first and second parallel planar surfaces and at least one period disposed on each of said first and second surfaces of the metal reflector. Each period is comprised of a dielectric layer with an index of refraction of 1.65 or less and a semi-opaque layer.

    摘要翻译： 光学可变墨水，用于在由油墨载体和设置在墨水载体中的光学可变薄片构成的入射光的第一和第二角度处获得两种不同的两种颜色之间的颜色轴。 光学可变薄片包括具有第一和第二平行平面的多层薄膜干涉结构。 光学可变薄片具有物理尺寸，使得当薄片分别在平面和垂直平面上垂直的方向测量时，提供至少2比1的纵横比。 所述多层薄膜结构是对称设计的，并且包括具有平行于所述第一和第二平行平面的第一和第二表面的金属反射器以及设置在所述金属反射器的所述第一和第二表面的每一个上的至少一个周期。 每个周期由折射率为1.65或更小的介电层和半不透明层组成。

    Luminescent pigments and foils with color-shifting properties
    10.
    发明授权
    Luminescent pigments and foils with color-shifting properties 有权
    具有色偏性的发光颜料和箔

    公开(公告)号：US06572784B1

    公开(公告)日：2003-06-03

    申请号：US09715937

    申请日：2000-11-17

    申请人： Paul G. Coombs ,  Jaroslaw Zieba ,  Richard A. Bradley, Jr. ,  Christopher W. Lantman ,  Thomas Mayer ,  Roger W. Phillips ,  Stacey A. Yamanaka

    发明人： Paul G. Coombs ,  Jaroslaw Zieba ,  Richard A. Bradley, Jr. ,  Christopher W. Lantman ,  Thomas Mayer ,  Roger W. Phillips ,  Stacey A. Yamanaka

    IPC分类号： C09K1100

    CPC分类号： C09C1/0081 ,  B82Y10/00 ,  B82Y30/00 ,  C01P2004/20 ,  C01P2004/84 ,  C09C1/0015 ,  C09C2200/1054 ,  C09C2210/50 ,  C09C2220/10 ,  C09C2220/20 ,  Y10T428/2991 ,  Y10T428/2998

    摘要： Interference pigment flakes and foils are provided which have luminescent and color-shifting properties. The pigment flakes can have a symmetrical coating structure on opposing sides of a core layer, can have an asymmetrical coating structure with all of the layers on one side of the core layer, or can be formed with encapsulating coatings around the core layer. The coating structure of the flakes and foils includes a core layer, a dielectric layer overlying the core layer, and an absorber layer overlying the dielectric layer. A luminescent material is incorporated into the flakes or foils as a separate layer or as at least part of one or more of the other layers. The pigment flakes and foils exhibit a discrete color shift so as to have a first color at a first angle of incident light or viewing and a second color different from the first color at a second angle of incident light or viewing. The pigment flakes can be interspersed into liquid media such as paints or inks to produce colorant materials for subsequent application to objects or papers. The foils can be laminated to various objects or can be formed on a carrier substrate.

    摘要翻译： 提供了具有发光和色移特性的干涉颜料薄片和薄片。 颜料薄片可以在芯层的相对侧上具有对称的涂层结构，可以具有不对称的涂层结构，其具有在芯层的一侧上的所有层，或者可以在芯层周围形成包封涂层。 薄片和箔片的涂层结构包括芯层，覆盖芯层的电介质层和覆盖在介电层上的吸收层。 发光材料作为单独的层或作为一个或多个其它层的至少一部分结合到片状物或箔中。 颜料薄片和薄片呈现离散的颜色偏移，以便在入射光或观察的第一角度具有第一颜色，并且在入射光或观看的第二角度具有不同于第一颜色的第二颜色。 颜料薄片可以散布到液体介质如油漆或油墨中，以产生用于随后应用于物体或纸张的着色剂材料。 箔可以层压到各种物体上，或者可以在载体基底上形成。