Opacifying pigment particle
    8.
    发明授权
    Opacifying pigment particle 有权
    不透明颜料颗粒

    公开(公告)号:US08304485B2

    公开(公告)日:2012-11-06

    申请号:US12800592

    申请日:2010-05-18

    IPC分类号: C08K3/32 B01J13/14

    摘要: A process for forming an opacifying pigment encapsulated in polymer including (a) dispersing a pigment particle having an average particle diameter of from 150 to 500 nm and an index of refraction of at least 1.8 such as, for example, TiO2 in a medium with from 0.1% to 10% by weight, based on the weight of said pigment particle, sulfur acid-functional first polymer whereby the zeta potential of the dispersed pigment particle is less than −28 mV between pH 5 and pH 8; and (b) performing an emulsion polymerization in the presence of the dispersed pigment particle to provide from 10% to 200%, by weight, based on the weight of the pigment particle, second polymer that at least partially encapsulates the dispersed pigment particle. Also provided are the encapsulated pigment particle so formed and compositions including the encapsulated pigment particle.

    摘要翻译: 一种形成包封在聚合物中的不透明颜料的方法,包括(a)将平均粒径为150-500nm,折射率至少为1.8的颜料颗粒,例如TiO 2在介质中分散, 0.1重量%至10重量%,基于所述颜料颗粒的重量,硫酸官能的第一聚合物,由此分散的颜料颗粒的ζ电位在pH5和pH8之间小于-28mV; 和(b)在分散的颜料颗粒的存在下进行乳液聚合,以基于颜料颗粒的重量计提供至少部分包封分散的颜料颗粒的第二聚合物的10重量%至200重量%。 还提供如此形成的包封的颜料颗粒和包含胶囊状颜料颗粒的组合物。

    SULFUR RESITANT CLADDED TITANIA-ALUMINA SUPPORTS
    9.
    发明申请
    SULFUR RESITANT CLADDED TITANIA-ALUMINA SUPPORTS 有权
    SULFUR RESIDANT CLADDED TITANIA-ALUMINA SUPPORTS

    公开(公告)号:US20120190541A1

    公开(公告)日:2012-07-26

    申请号:US13498609

    申请日:2010-10-01

    IPC分类号: B01J21/06

    摘要: The present invention is directed to a method of forming titania clad high surface area alumina suitable as a support for forming noble metal catalysts. The resultant catalysts exhibit resistance to poisoning by sulfurous materials and, therefore, are useful in applications directed to internal combustion engine emission conversion and the like. The present invention provides a commercially feasible and cost effective method of forming a highly desired support for noble metal catalyst application. The process comprises forming a slurry of porous alumina particulate suitable as a catalyst support for the intended application, mixing said slurry with a solution of titanyl sulfate having a pH of about 1, increasing the pH of the mixed slurry/solution at a slow rate of from 0.05 to 0.5 pH unit per minute to a pH of ≦4 by the addition of a basic solution, allowing the resultant slurry to age for a period of from 10 to 120 minutes, separating the treated porous alumina particulates and washing same free of sulfate with a weak base, drying and calcining said particulates to produce titania clad alumina particulate product. The resultant material exhibits a normalized sulfur uptake of less than about 45 μg/m2-sample. Such material can subsequently be coated with a noble metal to form the catalyst material.

    摘要翻译: 本发明涉及一种形成适合作为形成贵金属催化剂的载体的二氧化钛包覆高表面积氧化铝的方法。 所得到的催化剂表现出耐硫化材料的中毒性,因此可用于内燃机排放转换等的应用。 本发明提供了形成贵金属催化剂应用的高度期望的载体的商业可行且成本有效的方法。 该方法包括形成适合作为预期应用的催化剂载体的多孔氧化铝颗粒的浆料,将所述浆料与pH为约1的硫酸氧钛溶液混合,以较慢的速率增加混合浆料/溶液的pH 通过加入碱性溶液将0.05至0.5 pH单位/分钟至pH为< 1N; 4,使所得浆料老化10至120分钟,分离经处理的多孔氧化铝颗粒,并将其洗涤, 具有弱碱的硫酸盐,干燥和煅烧所述颗粒以产生二氧化钛包覆氧化铝颗粒产物。 所得材料表现出小于约45μg/ m 2样品的归一化硫吸收。 这种材料随后可以用贵金属涂覆以形成催化剂材料。