Separation of normally hydrophobic plastic materials by froth flotation
    93.
    发明授权
    Separation of normally hydrophobic plastic materials by froth flotation 失效
    通过泡沫浮选分离正常疏水性塑料

    公开(公告)号:US5377844A

    公开(公告)日:1995-01-03

    申请号:US60698

    申请日:1993-05-10

    Inventor: Jiann-Yang Hwang

    Abstract: A targeted particulate, synthetic organic plastic material having normally hydrophobic surface characteristics is separated from a mixture of two or more of such plastic materials by conditioning the mixture of plastic materials in a flotation cell with a heteropolar surfactant which has a hydrophile-lipophile balance (HLB) value greater than 5 and which selectively depresses the targeted plastic material by making the surfaces thereof more hydrophilic without substantially affecting the surfaces of the other plastic material(s) and introducing gas bubbles into the resulting conditioned pulp such that the gas bubbles selectively adhere to the surfaces of the other plastic materials(s) and cause them to float. The targeted plastic material is recovered in the cell product and the other plastic material(s) is recovered in the float concentrate.

    Abstract translation: 通过将浮选槽中的塑料材料的混合物与具有亲水 - 亲油平衡的异极性表面活性剂(HLB)进行调节,将具有通常疏水表面特性的目标颗粒状合成有机塑料材料与两种或更多种这种塑料材料的混合物分离 )值大于5,并且其通过使其表面更亲水而选择性地压下目标塑料材料,而基本上不影响其它塑料材料的表面并将气泡引入所得到的调节纸浆中,使得气泡选择性地粘附到 其他塑料材料的表面使其浮起。 将目标塑料材料回收到电池产品中,并将另一种塑料材料回收到浮选精矿中。

    Phosphate beneficiation process
    94.
    发明授权
    Phosphate beneficiation process 失效
    磷酸盐选矿过程

    公开(公告)号:US5147528A

    公开(公告)日:1992-09-15

    申请号:US681817

    申请日:1991-04-08

    Inventor: Srdjan Bulatovic

    Abstract: A process for the froth flotation separation of phosphate containing minerals by the use of a new collector agent is described. The new phosphate collector agent is prepared by mixing a fatty acid, tall oil pitch, an amine, and optionally sarcosine with fuel or furnace oil, and subsequently oxidizing the mixture by known methods. The new phosphate collector agent is added to the conditioned slurry of the ground and deslimed phosphate containing ore. The slurry is then subjected to froth flotastion in one or more stages to collect the phosphate concentrate in the froth. The phosphate collector agent is also effective in recovering phosphates from slime.

    Abstract translation: 描述了通过使用新的收集剂进行泡沫浮选分离含磷酸盐矿物的方法。 通过将脂肪酸,妥尔油沥青,胺和任选的肌氨酸与燃料或炉油混合,然后通过已知方法氧化该混合物来制备新的磷酸盐收集剂。 将新的磷酸盐收集剂加入到经研磨和脱磷酸盐的矿石的调理浆料中。 然后将浆料在一个或多个阶段进行泡沫吸收,以在泡沫中收集磷酸盐浓缩物。 磷酸盐收集剂对于从粘液中回收磷酸盐也是有效的。

    Process for the froth flotation of oxide and salt type minerals and
composition
    95.
    发明授权
    Process for the froth flotation of oxide and salt type minerals and composition 失效
    氧化物和盐类矿物的泡沫浮选方法及组成

    公开(公告)号:US5130037A

    公开(公告)日:1992-07-14

    申请号:US504782

    申请日:1990-04-04

    CPC classification number: B03D1/008 B03D2201/02 B03D2203/04

    Abstract: A process is provided for the froth flotation of oxide and salt type minerals utilizing as the collector a combination of a monoester of a dicarboxylic acid of the general formula ##STR1## in which R' is an aliphatic hydrocarbon group with 7-21 carbon atoms, R" is a hydrocarbon radical with 2-6 carbon atoms and A is an alkylene oxide group derived from an alkylene oxide with 2-4 carbon atoms; and a monocarboxylic acid having the general formulaR'"COOH IIwherein R'" is a hydrocarbon group with 5-23 carbon atoms, the acid as being in an amount to increase the yield and/or the selectivity of the monoester in the flotation of alkaline earth metal-containing oxide and salt type minerals, such as apatite, fluorspar, calcite, baryte, scheelite, dolomite, and magnesite.

    Abstract translation: 提供了一种用于泡沫浮选氧化物和盐型矿物的方法,其利用作为收集器的通式为其中R'为具有7-21个碳原子的脂族烃基的二羧酸的单酯的组合 R“是具有2-6个碳原子的烃基,A是衍生自2-4个碳原子的烯化氧的烯化氧基团; 和具有通式R“COOH II的一元羧酸,其中R”是具有5-23个碳原子的烃基,该酸的量可以提高单酯的产率和/或选择性 浮选含碱土金属的氧化物和盐类矿物,如磷灰石,萤石,方解石,重晶石,白钨矿,白云石和菱镁矿。

    Use of derivatives of tricyclo-(5.2.1.02,6)-dec-3-ene as frothers in the
flotation of coal and ores
    97.
    发明授权
    Use of derivatives of tricyclo-(5.2.1.02,6)-dec-3-ene as frothers in the flotation of coal and ores 失效
    在矿石和矿石浮选中使用三环(5.2.1.02,6) - 癸-3-烯的衍生物作为起泡剂

    公开(公告)号:US4925559A

    公开(公告)日:1990-05-15

    申请号:US164166

    申请日:1988-03-04

    CPC classification number: B03D1/008 B03D2201/04 B03D2203/08

    Abstract: Derivatives of tricyclo-[5.2.1.0.sup.2,6 ]-dec-3-ene corresponding to the following general formula ##STR1## in which R.sup.1 is hydrogen; a linear or branched C.sub.1 -C.sub.8 alkyl radical; an acyl radical R.sup.2 -CO, where R.sup.2 is hydrogen or a linear or branched C.sub.1 -C.sub.18 alkyl or alkenyl radical; or a hydroxyalkyl radical ##STR2## in which R.sup.3 and R.sup.4 independently of one another may be hydrogen or a hydroxy group and m and n are integers of 0 to 5 and the sum (m+n) is an integer of 1 to 5, with the proviso that at least one of the radicals R.sup.3 and R.sup.4 is a hydroxy group; are used as frothers in the flotation of coal and ores.

    Abstract translation: 对应于下列通式(Ⅰ)的三环[5.2.1.02,6]癸烯-3-酮的衍生物,其中R1是氢; 直链或支链C 1 -C 8烷基; 酰基R2-CO,其中R2是氢或直链或支链C1-C18烷基或烯基; 或其中R 3和R 4彼此独立地为羟基或羟基的羟基烷基基团,其中m和n为0〜5的整数,且和(m + n)为1〜5的整数,与 条件是基团R 3和R 4中的至少一个是羟基; 用作浮选煤和矿石中的起泡剂。

    Beryllium flotation process
    100.
    发明授权
    Beryllium flotation process 失效
    铍浮选工艺

    公开(公告)号:US4735710A

    公开(公告)日:1988-04-05

    申请号:US933844

    申请日:1986-11-24

    Inventor: Srdjan Bulatovic

    Abstract: A process and reagents are described for separating beryllium silicate concentrates by flotation from oxidic minerals. The process is especially suitable for the separation of phenacite and bertrandite present in ores with complex gangue compositions. The ore is ground and subjected to acid pretreatment, then conditioned by the addition of pH modifier, alkali fluoride activator and a depressant containing sodium hexametaphosphate and carboxymethyl cellulose, or hexametaphosphate and quebracho. The conditioned ore is thereafter treated with a tall oil fatty acid-based collector mixture, of general formula C.sub.17 H.sub.31-35 COOH; which also contains cresylic acid, kerosene and a branched short-chained aliphatic alcohol, such as methyl-iso-butyl carbinol. Mercapto acetic acid and alkali metal hydrogen sulphide may also be added in the second and third stages of conditioning, respectively, for increasing selectivity. The mineral concentration process includes conventional rougher and cleaner flotation steps. Yttrium and rare earth oxides, if present will be retained in the tailings.

    Abstract translation: 描述了通过浮选从氧化矿物中分离硅酸镧精矿的方法和试剂。 该方法特别适用于矿物中存在的复合脉石组合物中的矿物和矿物的分离。 将矿石研磨并进行酸预处理,然后通过加入pH调节剂,碱金属氟化物活化剂和含有六偏磷酸钠和羧甲基纤维素或六偏磷酸盐和quebracho的抑制剂进行调理。 然后将经调节的矿石用通式C 17 H 31 1- 35 COOH的妥尔油脂肪酸基收集​​混合物处理; 其还含有甲酚,煤油和支链短链脂族醇,例如甲基 - 异丁基甲醇。 也可以在调理的第二和第三阶段分别加入巯基乙酸和碱金属硫化氢以提高选择性。 矿物浓缩过程包括常规的粗糙和更清洁的浮选步骤。 钇和稀土氧化物(如果存在)将保留在尾矿中。

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