摘要:
A semi-continuous process for combusting coke from catalyst particles in a fixed bed is improved by rejecting from the combustion process a high moisture content flue gas stream which is produced by the combustion of a relatively large proportion of the hydrogen in the coke that enters the combustion section during an early stage of combustion. By operating the early stage of combustion at conditions to increase the rate of combustion of the hydrogen in the coke relative to that of the carbon in the coke, the overall equilibrium level of water in a flue gas/recycle gas that circulates through the process is lowered. The high moisture content flue gas stream from the early stage of combustion is rejected separately from the process. Subdivision of the bed and separation of the flue gas streams can be easily accomplished in a vertically arranged catalyst particle bed by adding baffles to the recycle gas distribution space that subdivide the distribution space into separate chambers and by adding baffles to the flue gas collection space that subdivide the collection space into separate chambers. The amount of high moisture content flue gas withdrawn from the process can be equal to the amount of the make-up gas streams entering the flue gas/recycle gas loop.
摘要:
A controlled method of transporting catalyst between two zones while inhibiting communication between the atmospheres of the zones is disclosed. Communication between the zones is inhibited by controlling pressure differences. The two zones are separated by a means to lift catalyst, which results in a savings in construction costs. This invention is adaptable to a multitude of processes for the catalytic conversion of hydrocarbons in which deactivated catalyst particles are regenerated.
摘要:
A semi-continuous process for combusting coke from catalyst particles in a fixed bed is improved by segregating flue gas from the combustion process into a high moisture content flue gas stream which is withdrawn from the process and a relatively low moisture content flue gas stream which is combined with an oxygen-containing make-up gas and recycled to the process. When coke is combusted in a fixed bed to which catalyst is added at an inlet and withdrawn from an outlet on a semi-continuous basis, hydrogen from the coke is quickly combusted whereas less volatile coke components are more slowly combusted. As a result, flue gas passing through the catalyst that has just entered the bed will have the highest water concentration. By separately recovering the flue gas stream having this high moisture content, the overall equilibrium level of water in a flue gas/recycle gas that circulates through the process is lowered. Segregation of flue gas can be easily accomplished in a vertically arranged catalyst bed by adding a baffle to the flue gas collection space that subdivides the collection space into separate chambers. The amount of high moisture content withdrawn from the process can be equal to the amount of make-up gas entering the flue gas/recycle gas loop. A larger amount of high moisture content flue gas than that vented from the process can be collected with the non-vented gas passing through a drier and other treatment steps before re-entering the process as part of the make-up gas. Using the unvented portion of the high moisture content flue gas increases the efficiency of using driers since a relatively large amount of water can be removed from a small volume of flue gas.
摘要:
A method for continuously or semi-continuously regenerating reforming catalyst by the recirculation of a gas stream advantageously controls the water content by using an oxygen-deficient makeup gas stream to supply the oxygen for combustion of coke. The volume of makeup gas entering the process is increased by reducing its oxygen concentration so that additional waste gases from the combustion of coke on the catalyst can be vented. The venting of additional gas from the circulating gas stream lowers the overall water concentration during the combustion of coke. The oxygen-deficient makeup gas stream can be supplied by oxygen and nitrogen separation from air. Where the production of the oxygen-deficient makeup gas stream also produces an oxygen-enriched stream, the oxygen-enriched stream is advantageously added to a catalyst reconditioning step for an increased dispersion of metals in the catalyst.
摘要:
A method and apparatus are provided for controlling the transfer of particles between zones of different pressure using particle collection and particle transfer conduits. The solids are moved from a low pressure zone to a high pressure zone by means of a valveless lock hopper system that vents all of the gas from the collection zones through the particle collection conduits. Venting gas from the collection zones through the transfer conduits prevents erosion of control valves and eliminates the need for filters which are prone to clogging. The venting of gas is accomplished by varying the size of the transfer conduits between zones. The invention is particularly applicable in the regeneration of catalyst used in hydrocarbon conversion processes such as catalytic reforming.
摘要:
Char-handling processes for controlling overall heat balance, ash accumulation, and afterburn in a reheater are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium. The spent heat transfer medium is separated into segregated char and char-depleted spent heat transfer medium. The char-depleted spent heat transfer medium is introduced into a dense bed of heat transfer medium fluidized by a stream of oxygen-containing regeneration gas. All or a portion of the segregated char is combusted in the dense bed using the stream of oxygen-containing regeneration gas. A portion of the segregated char may be exported out of the pyrolysis system to control the overall heat balance and ash accumulation.
摘要:
Embodiments of processes for producing propylene from paraffins are provided. The process comprises the steps of combining an effluent that comprises propylene and propane from a paraffin dehydrogenation reactor with an offgas stream that comprises propane to form a combined effluent stream. The combined effluent stream is separated into a propylene product stream and a propane-rich recycle stream. The propane-rich recycle stream is introduced to the paraffin dehydrogenation reactor operating at dehydrogenation conditions to convert propane in the propane-rich recycle stream to propylene.
摘要:
One exemplary embodiment can include an apparatus for transferring catalyst from a regeneration zone to a reaction zone in a hydrocarbon conversion unit. The hydrocarbon conversion unit can include a transfer vessel, and first, second, and third lines. The transfer vessel can transfer regenerated catalyst from the regeneration zone at a first pressure to the reaction zone at a second pressure where the second pressure is greater than the first pressure. Generally, the first line communicates the catalyst to the transfer vessel and is coupled to a first valve to allow catalyst into the transfer vessel and the second line communicates the catalyst from the transfer vessel and is coupled to a second valve to allow catalyst out of the transfer vessel. The third line for allowing the passage of gas therethrough may be at a pressure higher than the first pressure having a first portion communicating with the transfer vessel and having a second portion coupled to third and fourth valves. Each of the third and fourth valves can have a first position that is open and a second position that is closed, which may correspond, respectively, to the opening and closing of the first and second valves to allow gas to pass therethrough.
摘要:
A liquid distribution device is presented for the collection and distribution of liquid between reactor or adsorbent beds. The device includes a liquid collection tray, a mixing chamber in fluid communication with the liquid collection tray, a liquid distribution tray in fluid communication with the mixing chamber, and a plurality of nozzles for delivering the liquid over the top of a reactor or adsorbent bed.
摘要:
A process for hydroprocessing a hydrocarbonaceous feedstock in a continuous liquid phase utilizes a hydroprocessing catalyst comprising pills that have a largest dimension that averages no more than 1.27 mm ( 1/20 inch) and more than 100 nm to produce a hydrocarbonaceous product stream.