公开(公告)号：US07220709B1

公开(公告)日：2007-05-22

申请号：US10100778

申请日：2002-03-19

申请人： Qi Qu ,  Scott McCarthy ,  Daniel Patrick Vollmer

发明人： Qi Qu ,  Scott McCarthy ,  Daniel Patrick Vollmer

IPC分类号： C09K8/58

CPC分类号： C09K8/72 ,  C09K8/74 ,  C09K2208/30

摘要： A process for stimulating a formation is disclosed wherein a diverting fluid is used to divert an acid treatment package from a high permeability or damaged portion of a formation to a low permeability or undamaged portion of a formation. The fluid preferably forms vesicles.

摘要翻译： 公开了一种用于刺激地层的方法，其中使用转向流体将酸处理包从地层的高渗透性或损坏部分转移到地层的低渗透性或未损伤部分。 流体优选形成囊泡。

公开(公告)号：US20070087940A1

公开(公告)日：2007-04-19

申请号：US11581539

申请日：2006-10-16

申请人： Qi Qu ,  David Alleman

发明人： Qi Qu ,  David Alleman

IPC分类号： C09K8/00 ,  E21B43/00

CPC分类号： C09K8/74 ,  C09K8/601 ,  C09K8/602 ,  C09K8/76 ,  C09K2208/26 ,  C09K2208/30 ,  Y10S507/922

摘要： A process for enhancing the productivity of a formation consists of introducing into the formation a viscoelastic fluid which contains at least one surfactant, at least one quaternary amine polyelectrolyte, water, and a non-aqueous solvent. The surfactant forms aggregation structures or vesicles. The fluid, which significantly enhances fluid viscosity and thermal stability, is particularly effective as a diverting fluid to divert an acid treatment package from a high permeability or undamaged portion of a formation to a low permeability or damaged portion of a formation as well as a fracturing fluid. In addition, the fluid is useful for sand control completion.

摘要翻译： 一种用于提高地层生产率的方法包括向地层中引入含有至少一种表面活性剂，至少一种季胺聚电解质，水和非水溶剂的粘弹性流体。 表面活性剂形成聚集结构或囊泡。 显着增强流体粘度和热稳定性的流体作为将酸处理包从地层的高渗透性或未损坏部分转移到地层的低渗透性或损坏部分以及压裂的转向流体是特别有效的 流体。 此外，该流体可用于防砂完成。

公开(公告)号：US07144512B2

公开(公告)日：2006-12-05

申请号：US10623044

申请日：2003-07-18

申请人： Qi Qu ,  Paul H. Javora ,  Joel L. Boles ,  Sandra L. Berry

发明人： Qi Qu ,  Paul H. Javora ,  Joel L. Boles ,  Sandra L. Berry

IPC分类号： B01D15/00

CPC分类号： E21B21/068 ,  B01D19/04 ,  B01J45/00 ,  Y10S210/912

摘要： A method of reclaiming a well completion brine solution by using an organic chelant that is capable of discriminating between (i) iron and non-zinc heavy metals; and (ii) calcium and zinc. The chelant contains a functional group selected from the group —CO2H or —PO(OH)R20 or a salt or ester thereof, —C(O)—, —OE, —SE, —N═C(R2)R3, EO—N═C(R2)R3, —N(R2)R3, and —N(C(O)R1)R2 group optionally substituted with a —COOH or —PO(OH)R20 or a salt or ester thereof, —SE or —OE group, wherein R2 and R3 are independently selected from E or forms, with nitrogen, phosphorous, oxygen or sulfur, a heterocyclic ring; E is R1 or —H; R1 is a C1–C30 alkyl or aralkyl group or a derivative thereof and R20 is —OH or R1.

摘要翻译： 通过使用能够区分（i）铁和非锌重金属的有机螯合剂回收完井盐水溶液的方法; 和（ii）钙和锌。 螯合剂含有选自-CO 2 H或-PO（OH）R 20的官能团或其盐或酯，-C（O） - ， -OE，-SE，-NC（R 2）R 3，EO-NC（R 2）R 3， -N（R 2）R 3，和-N（C（O）R 1）R 2， 任选被-COOH或-PO（OH）R 20或其盐或酯取代的-SE或-OE基团，其中R 2和R 3， 独立地选自E或其形式，具有氮，磷，氧或硫，杂环; E是R 1或-H; R 1是C 1 -C 30烷基或芳烷基或其衍生物，R 20是 - OH或R 1。

公开(公告)号：US20060042796A1

公开(公告)日：2006-03-02

申请号：US10932965

申请日：2004-09-02

申请人： Qi Qu ,  Richard Stevens ,  David Alleman

发明人： Qi Qu ,  Richard Stevens ,  David Alleman

IPC分类号： E21B37/06

CPC分类号： C09K8/524 ,  C09K8/52 ,  Y10S507/928 ,  Y10S507/93 ,  Y10S507/931

摘要： Fluid producing wells may be treated with a water-in-oil emulsion for the removal or inhibition of unwanted solid particulates, including pipe dope, asphaltenes and paraffins. Such emulsions are of particular applicability in the displacement of oil base drilling muds and/or residues from such muds from producing wells. The water-in-oil emulsions may optionally contain a dispersing agent as well as a surfactant.

摘要翻译： 流体生产井可以用油包水乳液处理，以去除或抑制不想要的固体颗粒，包括管道涂料，沥青质和石蜡。 这种乳液特别适用于油井钻井泥浆和/或来自生产井的这种泥浆的残留物的置换。 油包水乳液可以任选地含有分散剂以及表面活性剂。

公开(公告)号：US20050227875A1

公开(公告)日：2005-10-13

申请号：US11145281

申请日：2005-06-03

申请人： Paul Javora ,  Qi Qu

发明人： Paul Javora ,  Qi Qu

IPC分类号： E21B21/06 ,  E21B43/00

CPC分类号： E21B21/068 ,  B01D19/04 ,  B01J45/00 ,  C02F1/28 ,  C02F1/66 ,  C02F1/683 ,  C02F1/72 ,  C02F9/00 ,  C02F2101/20 ,  C02F2103/08 ,  Y10S210/912

摘要： A method of reclaiming a well completion brine solution by using an organic chelant that is capable of discriminating between (i) iron and/or non-zinc heavy metals; and (ii) calcium and zinc. The chelant is of the formula: and may be either a neutral compound, a corresponding salt, or a corresponding quaternary salt, wherein: D is F-A (Y3)u(Y4)v; R is independently selected from Cp or CpC(O); Cp is a C1-C36 hydrocarbyl group, optionally substituted with one or more substituents selected the group consisting of halogen, hydroxyl, sulfate, CH2CO2Z or —(CH2)nPO(OZ)2 groups; each A is independently selected from —N and —P; Y1 is independently selected from J, —[(F)-A(J)]wY6 and R; J, R1, Y2, Y3, Y4, Y5 and Y6 are independently selected from the group consisting of —H, R, —(F)nCO2Z and —(CH2)nPO(OZ)2; each F is independently selected from a C1-C12 hydrocarbyl group, optionally substituted with one or more substituents selected the group consisting of halogen, hydroxyl, sulfate, CH2CO2Z or —(CH2)nPO(OZ)2 groups; Z is —H or a balanced counterion of an alkali or alkaline earth metal or NH4+; m is 0 to 7; n is 1 to 7; r+s+t is 1 or 2; u+v is 1 or 2; and w is 0 to 7 provided when m is 0, no more than one of R1, Y1, Y2 and Y5 can be —H.

公开(公告)号：US06435277B1

公开(公告)日：2002-08-20

申请号：US09256980

申请日：1999-02-23

申请人： Qi Qu ,  Erik B. Nelson ,  Dean M. Willberg ,  Mathew M. Samuel ,  Jesse C. Lee, Jr. ,  Frank F. Chang ,  Roger J. Card ,  Palathinkara S. Vinod ,  J. Ernest Brown ,  Ronnie L. Thomas

发明人： Qi Qu ,  Erik B. Nelson ,  Dean M. Willberg ,  Mathew M. Samuel ,  Jesse C. Lee, Jr. ,  Frank F. Chang ,  Roger J. Card ,  Palathinkara S. Vinod ,  J. Ernest Brown ,  Ronnie L. Thomas

IPC分类号： E21B4326

CPC分类号： C09K8/68 ,  C09K8/74 ,  C09K2208/30 ,  E21B43/26 ,  Y10S507/923 ,  Y10S507/933

摘要： The improved recovery of hydrocarbons from subterranean formations by hydraulically fracturing a subterranean formation is accomplished. Fracturing fluids using a viscosifying surfactant fluid containing viscosifying micelles, for example, wormlike micelles, are useful to improve recovery of hydrocarbons and limit the loss of fracturing fluid into the formation fracture face. The invention further relates to novel fracturing and acidizing methods useful for increasing hydrocarbon production, limiting water production, resisting fracturing fluid loss into the subterranean formation, and reducing the equipment requirements in mixing and pumping fracturing fluid. The action of viscosifying micelles of surfactant in aqueous zones of the subterranean formation diverts fracturing fluid or acid from the aqueous zones to the hydrocarbon-bearing zones and also facilitates the flowback of increased amounts of hydrocarbons once a fractured well is placed back on production. These methods selectively block the pore structure in a water-bearing zone and do not blocking the pore structure of a hydrocarbon zone at the formation face. The step for selectively blocking forms a plug of a viscous fluid containing viscosifying micelles in the pore structure of the water-bearing zone at the formation face.

摘要翻译： 通过水力压裂地下地层来改善地下地层烃类的回收。 使用含有增粘胶束（例如蠕虫状胶束）的增粘表面活性剂流体的压裂液可用于改善烃的回收并限制压裂流体进入地层断裂面的损失。 本发明还涉及用于增加碳氢化合物生产，限制水的产生，抵抗压裂液渗入地层的压裂和酸化方法，以及减少混合和泵送压裂液的设备要求。 表面活性剂粘附在地下水层中的胶束的作用将压裂液或酸从含水区转移到含烃区，并且一旦断裂的井放回生产中，也有利于增加量的烃的回流。 这些方法选择性地阻挡含水区中的孔结构，并且不阻塞在形成面上的烃区的孔结构。 选择性阻塞的步骤在形成面上的含水区的孔结构中形成含有粘胶束的粘性流体塞。

公开(公告)号：US09033040B2

公开(公告)日：2015-05-19

申请号：US13328032

申请日：2011-12-16

申请人： Thomas J. Pisklak ,  Elizabeth G. Morillo ,  Qi Qu

发明人： Thomas J. Pisklak ,  Elizabeth G. Morillo ,  Qi Qu

IPC分类号： E21B33/13 ,  C04B14/10 ,  C04B14/24

CPC分类号： C09K8/473 ,  C04B14/104 ,  C04B14/24 ,  C04B18/027 ,  C04B20/12 ,  C04B38/009 ,  C04B38/08 ,  C09K8/467 ,  E21B33/13 ,  Y10T428/2991 ,  Y10T428/2996 ,  C04B33/04 ,  C04B33/13 ,  C04B38/02 ,  C04B20/002 ,  C04B20/1029 ,  C04B20/1077 ,  C04B14/22 ,  C04B14/28 ,  C04B14/30 ,  C04B18/026 ,  C04B28/02

摘要： A lightweight composite having an activated surface contains a lightweight hollow core particle having cement grains which may be adhered to the hollow core or embedded in the surface of the hollow core. The hollow core particle may be prepared from calcium carbonate and a mixture of clay, such as bentonite, and a glassy inorganic material, such as glass spheres, glass beads, glass bubbles, borosilicate glass and fiberglass.

摘要翻译： 具有活化表面的轻质复合材料包含具有水泥颗粒的轻质中空芯颗粒，其可以粘附到中空芯或嵌入在中空芯的表面中。 中空芯颗粒可以由碳酸钙和粘土如膨润土和玻璃状无机材料如玻璃球，玻璃珠，玻璃泡，硼硅酸盐玻璃和玻璃纤维的混合物制备。

公开(公告)号：US08921597B2

公开(公告)日：2014-12-30

申请号：US13153805

申请日：2011-06-06

申请人： Hong Sun ,  Qi Qu

发明人： Hong Sun ,  Qi Qu

IPC分类号： C07F5/02

CPC分类号： C07F5/025

摘要： Methods for making polyaminoboric acid compounds are provided. The polyaminoboric acid compounds are made by reacting a polyamine with boric acid in the presence of a solvent to produce polyaminoboric acid compounds with more than one boron-nitrogen bond. The polyaminoboric acid compounds are useful as crosslinking agents for fracturing fluids.

摘要翻译： 提供了制备聚氨基硼酸化合物的方法。 多氨基酸化合物通过在溶剂存在下使多胺与硼酸反应制备具有多于一个硼 - 氮键的多氨基硼酸化合物来制备。 聚氨基硼酸化合物可用作压裂液的交联剂。

公开(公告)号：US20140332214A1

公开(公告)日：2014-11-13

申请号：US14169698

申请日：2014-01-31

申请人： Jia Zhou ,  Qi Qu ,  Scott G. Nelson ,  Hong Sun ,  Leiming Li

发明人： Jia Zhou ,  Qi Qu ,  Scott G. Nelson ,  Hong Sun ,  Leiming Li

IPC分类号： C09K8/80 ,  E21B43/267

CPC分类号： E21B43/267 ,  C09K8/685 ,  C09K2208/26

摘要： A hydraulic fracturing composition includes: a superabsorbent polymer in an expanded state; a plurality of proppant particles disposed in the superabsorbent polymer; an additive comprising a surfactant, a viscose polymer, or a combination thereof, and a fluid to expand the superabsorbent polymer into the expanded state. A process for disposing a plurality of proppant particles in a fracture comprises: disposing a hydraulic fracturing composition in a downhole environment; forming a fracture; disposing the hydraulic fracturing composition in the fracture; breaking the superabsorbent polymer after forming the fracture; and releasing the plurality of proppant particles from superabsorbent polymer. The process also comprises injecting a proppant-free fluid and a proppant-containing fluid in an alternating order into a subterranean formation.

摘要翻译： 水力压裂组合物包括：膨胀状态的超吸收性聚合物; 设置在超吸收性聚合物中的多个支撑剂颗粒; 包含表面活性剂，粘胶聚合物或其组合的添加剂以及将超吸收性聚合物膨胀成膨胀状态的流体。 在断裂中配置多个支撑剂颗粒的方法包括：在井下环境中设置水硬性压裂组合物; 形成骨折; 将水力压裂组合物置于裂缝中; 在形成断裂之后破坏超吸收性聚合物; 并从超吸收聚合物中释放多个支撑剂颗粒。 该方法还包括将不含支撑剂的流体和含支撑剂的流体以交替顺序注入到地层中。

公开(公告)号：US20140332213A1

公开(公告)日：2014-11-13

申请号：US13888457

申请日：2013-05-07

申请人： Jia Zhou ,  Hong Sun ,  Qi Qu ,  Michael Guerin

发明人： Jia Zhou ,  Hong Sun ,  Qi Qu ,  Michael Guerin

IPC分类号： C09K8/80

CPC分类号： C09K8/805 ,  C09K8/685

摘要： A hydraulic fracturing composition includes: a superabsorbent polymer in an expanded state and configured to break in response to a breaking condition; a plurality of proppant particles disposed in the superabsorbent polymer prior to release of the plurality of proppant particles from the superabsorbent polymer in response to breaking the superabsorbent polymer; and a fluid to expand the superabsorbent polymer into the expanded state. The hydraulic fracturing composition can be made by contacting a superabsorbent polymer with a fluid to expand the superabsorbent polymer into an expanded state; and disposing a plurality of proppant particles in the superabsorbent polymer to make the hydraulic fracturing composition. A process for disposing a plurality of proppant particles in a fracture comprises: disposing a hydraulic fracturing composition in a downhole environment; forming a fracture in the downhole environment; disposing the hydraulic fracturing composition in the fracture; breaking the superabsorbent polymer after forming the fracture; and releasing the plurality of proppant particles from superabsorbent polymer to dispose the plurality of proppant particles in the fracture.

摘要翻译： 水力压裂组合物包括：膨胀状态的超吸收性聚合物，其构造成响应于断裂条件而断裂; 在响应于破坏超吸收性聚合物之前，从超吸收性聚合物释放多个支撑剂颗粒之前，将多个支撑剂颗粒设置在超吸收聚合物中; 以及将超吸收性聚合物膨胀成膨胀状态的流体。 水解压裂组合物可以通过使超吸收性聚合物与流体接触来制造，以将超吸收性聚合物膨胀成膨胀状态; 并将多个支撑剂颗粒设置在超吸收聚合物中以制造水力压裂组合物。 在断裂中配置多个支撑剂颗粒的方法包括：在井下环境中设置水硬性压裂组合物; 在井下环境中形成裂缝; 将水力压裂组合物置于裂缝中; 在形成断裂之后破坏超吸收性聚合物; 并且从超吸收性聚合物中释放多个支撑剂颗粒以将多个支撑剂颗粒置于断裂中。