公开(公告)号：US06548956B2

公开(公告)日：2003-04-15

申请号：US09726482

申请日：2000-12-01

Applicant: Stephen R. Forrest ,  Mark E. Thompson ,  Paul E. Burrows ,  Vladimir Bulovic ,  Gong Gu

Inventor： Stephen R. Forrest ,  Mark E. Thompson ,  Paul E. Burrows ,  Vladimir Bulovic ,  Gong Gu

IPC: H01J162

CPC classification number: H01L27/3209 ,  C09K11/06 ,  H01L51/0034 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0038 ,  H01L51/0042 ,  H01L51/005 ,  H01L51/0051 ,  H01L51/0059 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0084 ,  H01L51/5012 ,  H01L51/5036 ,  H01L51/5048 ,  H01L51/5234 ,  H01L51/5253 ,  H01L2251/5323

Abstract: A multicolor organic light emitting device employs vertically stacked layers of double heterostructure devices which are fabricated from organic compounds. The vertical stacked structure is formed on a glass base having a transparent coating of ITO or similar metal to provide a substrate. Deposited on the substrate is the vertical stacked arrangement of three double heterostructure devices, each fabricated from a suitable organic material. Stacking is implemented such that the double heterostructure with the longest wavelength is on the top of the stack. This constitutes the device emitting red light on the top with the device having the shortest wavelength, namely, the device emitting blue light, on the bottom of the stack. Located between the red and blue device structures is the green device structure. The devices are configured as stacked to provide a staircase profile whereby each device is separated from the other by a thin transparent conductive contact layer to enable light emanating from each of the devices to pass through the semitransparent contacts and through the lower device structures while further enabling each of the devices to receive a selective bias. The devices are substantially transparent when de-energized, making them useful for heads-up display applications.

Abstract translation: 多色有机发光器件采用由有机化合物制成的双异质结构器件的垂直层叠层。 垂直堆叠结构形成在具有ITO或类似金属的透明涂层的玻璃基底上以提供基底。 沉积在衬底上的是三个双异质结构器件的垂直堆叠布置，每个由异质结构器件制成，每个由合适的有机材料制成。 实施堆叠，使得具有最长波长的双异质结构位于堆叠的顶部。 这构成在顶部发射红光的装置，其中装置具有最短波长，即发射蓝光的装置，在堆叠的底部。 位于红色和蓝色的设备结构之间是绿色设备结构。 这些器件被配置为堆叠以提供阶梯轮廓，由此每个器件通过薄的透明导电接触层与另一个分离，以使来自每个器件的光能够透过半透明触点并通过下部器件结构，同时进一步启用 每个设备接收选择性偏差。 当断电时，这些器件基本上是透明的，使得它们对于平视显示器应用是有用的。

公开(公告)号：US06458475B1

公开(公告)日：2002-10-01

申请号：US09449363

申请日：1999-11-24

Applicant: Chihaya Adachi ,  Stephen R. Forrest

Inventor： Chihaya Adachi ,  Stephen R. Forrest

IPC: H05B3314

CPC classification number: H01L51/0077 ,  H01L51/005 ,  H01L51/0059 ,  H01L51/0081 ,  H01L51/5012 ,  Y10S428/917

Abstract: Improved electroluminescent efficiency in organic light emitting diodes is obtained with an emitter layer comprising organic complexes of transition metals with benzoxazole derivatives. A dimethylated benzoxazole derivative with zinc shows blue fluorescence and phosphorescence.

Abstract translation: 通过具有过渡金属与苯并恶唑衍生物的有机络合物的发射极层获得有机发光二极管中的电致发光效率的提高。 具有锌的二甲基化苯并恶唑衍生物显示蓝色荧光和磷光。

公开(公告)号：US06458426B1

公开(公告)日：2002-10-01

申请号：US09717351

申请日：2000-11-22

Applicant: Vladimir Bulovic ,  Stephen R. Forrest

Inventor： Vladimir Bulovic ,  Stephen R. Forrest

IPC: B05D128

CPC classification number: B82Y10/00 ,  B01J2219/00382 ,  B05D1/007 ,  B05D1/283 ,  B82Y30/00 ,  B82Y40/00 ,  C40B60/14 ,  G03F7/0002

Abstract: This application relates to a method of depositing a patterned layer of material, such as organic material, over a substrate or organizing materials over a substrate. The method involves using a stamp having at least one conductive pathway and an insulating layer to transfer material from a solution to a substrate in a specified pattern. The stamp may be used multiple times to transfer a similar pattern of organic material to multiple substrates or to different portions of the same substrate. The transferred material may then be preferably used as a photolithographic mask for nano-patterning the substrate. This application also relates to a stamp that may be used in depositing a patterned layer of material onto a substrate, a method of forming such a stamp, and a method of depositing a layer of oriented molecules over a substrate.

Abstract translation: 本申请涉及在衬底上沉积诸如有机材料的图案化层材料层或在衬底上组织材料的方法。 该方法包括使用具有至少一个导电通路的印模和绝缘层以特定的图案将材料从溶液转移到基底。 印模可以多次使用以将相似图案的有机材料转移到多个基板或相同基底的不同部分。 然后可以将转移的材料用作用于纳米图案化衬底的光刻掩模。 本申请还涉及可以用于将图案化的材料层沉积到衬底上的印模，形成这种印模的方法以及在衬底上沉积定向分子层的方法。

公开(公告)号：US06451455B1

公开(公告)日：2002-09-17

申请号：US09053030

申请日：1998-04-01

Applicant: Mark Thompson ,  Yujian You ,  Andrei Shoustikov ,  Paul E. Burrows ,  Stephen R. Forrest

Inventor： Mark Thompson ,  Yujian You ,  Andrei Shoustikov ,  Paul E. Burrows ,  Stephen R. Forrest

IPC: H05B3312

CPC classification number: H01L51/5048 ,  C07D487/22 ,  C09K11/06 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1074 ,  C09K2211/185 ,  C09K2211/186 ,  H01L51/0059 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/0081 ,  H01L51/0082 ,  H01L51/5016 ,  H01L2251/5323 ,  H05B33/28 ,  Y10S428/917

Abstract: An organic light emitting device comprising a heterostructure for producing electro-luminescence. The heterostructure has a charge carrier layer that includes a compound having molecules having at least one electron transporting moiety that is a 2-methyl-8-quinolinolato ligand coordinated with a metal chosen from the group Al, Ga, and In, and at least one hole transporting moiety. For example, the compound may be bis(2-methyl-8-quinolinolato)[p-(N-phenyl-2-naphthylamino)phenolato]aluminum(III), bis(2-methyl-g-quinolinolato)p-carbazolphenolato)aluminum(III), or bis(2-methyl-8-quinolinolato)(m-carbazolphenolato)aluminum(III).

Abstract translation: 一种包括用于产生电致发光的异质结构的有机发光器件。 异质结构具有电荷载体层，其包含具有至少一个电子传输部分的分子的化合物，其是与选自Al，Ga和In的金属配位的2-甲基-8-羟基喹啉配体，和至少一个 空穴传输部分。 例如，化合物可以是双（2-甲基-8-羟基喹啉）[对（N-苯基-2-萘基氨基）苯酚]铝（III），双（2-甲基-g-羟基喹啉）对 - 咔唑酚） 铝（III）或双（2-甲基-8-羟基喹啉）（间 - 咔唑酚）铝（III）。

公开(公告)号：US06396860B1

公开(公告)日：2002-05-28

申请号：US09648156

申请日：2000-08-25

Applicant: Vladimir Kozlov ,  Stephen R. Forrest ,  Paul Burrows ,  Vladimir Bulovic

Inventor： Vladimir Kozlov ,  Stephen R. Forrest ,  Paul Burrows ,  Vladimir Bulovic

IPC: H01S316

CPC classification number: H01S3/0632 ,  H01S3/0635 ,  H01S3/168 ,  H01S5/041 ,  H01S5/36

Abstract: An optically-pumped laser having a small-molecule thin organic film of DCM doped Alq3. Carrier transport properties of the small-molecule organic materials, combined with a low lasing threshold provide a new generation of diode lasers employing organic thin films. An electrically-pumped variant is also described.

Abstract translation: 具有DCM掺杂Alq3的小分子薄有机膜的光泵浦激光器。 小分子有机材料的载流子传输特性，结合低激光阈值，提供了采用有机薄膜的新一代二极管激光器。 还描述了电泵送的变型。

公开(公告)号：US06352777B1

公开(公告)日：2002-03-05

申请号：US09136342

申请日：1998-08-19

Applicant: Vladimir Bulovic ,  Stephen R. Forrest

Inventor： Vladimir Bulovic ,  Stephen R. Forrest

IPC: H01L310256

CPC classification number: H01L51/4246 ,  B82Y10/00 ,  H01L27/302 ,  H01L51/0042 ,  H01L51/0046 ,  H01L51/0047 ,  H01L51/005 ,  H01L51/0053 ,  H01L51/0077 ,  H01L51/0078 ,  H01L51/4206 ,  H01L51/424 ,  Y02E10/549 ,  Y10S428/913 ,  Y10T428/24835 ,  Y10T428/24942 ,  Y10T428/31504

Abstract: An organic photosensitive optoelectronic device optimized to enhance desired characteristics such as external quantum efficiency is described. The photosensitive optoelectronic device has at least two transparent electrodes and one or more organic photoconductive layers disposed between the transparent electrodes. In other embodiments photosensitive optoelectronic devices with multilayer photoconductive structures and photosensitive optoelectronic devices with a reflective layer are disclosed.

公开(公告)号：US06330262B1

公开(公告)日：2001-12-11

申请号：US09073843

申请日：1998-05-07

Applicant: Paul E. Burrows ,  Stephen R. Forrest ,  Mark Thompson ,  Vladimir G. Kozlov ,  Gautam Parthasarathy

Inventor： Paul E. Burrows ,  Stephen R. Forrest ,  Mark Thompson ,  Vladimir G. Kozlov ,  Gautam Parthasarathy

IPC: H01S316

CPC classification number: H01S5/36 ,  H01S3/0632 ,  H01S3/0635 ,  H01S3/168 ,  H01S5/041

Abstract: Lasers comprising a substrate and a layer of organic material over the substrate. The organic material includes host and dopant materials that result in the laser emission of a desired color when pumped by optical pump energy. Host materials include CBP and tris-(8-hydroxyquinoline) aluminum, which when combined with dopant materials such as coumarin-47, coumarin-30, perylene, rhodamine-6G, DCM, DCM2, and pyrromethane-546 result in the efficient lasing of colors such as blue, green and yellow.

Abstract translation: 激光器包括衬底和衬底上的有机材料层。 有机材料包括主体和掺杂剂材料，当通过光泵能量泵浦时，其产生激光发射所需颜色。 主要材料包括CBP和三（8-羟基喹啉）铝，当与诸如香豆素-47，香豆素-30，苝，罗丹明-6G，DCM，DCM2和吡咯烷-446的掺杂剂材料组合时，可以有效地激发 颜色如蓝色，绿色和黄色。

公开(公告)号：US06297495B1

公开(公告)日：2001-10-02

申请号：US09136166

申请日：1998-08-19

Applicant: Vladimir Bulovic ,  Stephen R. Forrest

Inventor： Vladimir Bulovic ,  Stephen R. Forrest

IPC: H01L3106

CPC classification number: H01L51/424 ,  B82Y10/00 ,  H01L27/302 ,  H01L51/0046 ,  H01L51/0047 ,  H01L51/005 ,  H01L51/0053 ,  H01L51/0077 ,  H01L51/0078 ,  H01L51/4206 ,  H01L51/4246 ,  Y02E10/549

Abstract: An organic photosensitive optoelectronic device optimized to enhance desired characteristics such as external quantum efficiency is described. The photosensitive optoelectronic device has transparent electrode as the top electrode. The substrate may be the bottom electrode or there may be a bottom electrode distinct from the substrate. One or more organic photoconductive layers are disposed between the electrodes. In other embodiments photosensitive optoelectronic devices with multilayer photoconductive structures and photosensitive optoelectronic devices with a reflective layer or a reflective substrate are disclosed.

Abstract translation: 描述了优化以增强期望特性（例如外部量子效率）的有机光敏光电器件。 光敏光电器件具有透明电极作为顶电极。 衬底可以是底部电极，或者可以存在与衬底不同的底部电极。 一个或多个有机光电导层设置在电极之间。 在其它实施例中，公开了具有多层光电导结构的光敏光电器件和具有反射层或反射衬底的光敏光电器件。

公开(公告)号：US06294398B1

公开(公告)日：2001-09-25

申请号：US09447793

申请日：1999-11-23

Applicant: Changsoon Kim ,  Paul E. Burrows ,  Stephen R. Forrest

Inventor： Changsoon Kim ,  Paul E. Burrows ,  Stephen R. Forrest

IPC: H01L1200

CPC classification number: H01L27/3281 ,  H01L27/32 ,  H01L51/0013 ,  H01L51/0016 ,  H01L51/0017 ,  H01L51/0021 ,  H01L51/5012 ,  H01L51/5206 ,  H01L51/5231 ,  H01L51/56

Abstract: The present invention relates to patterning methods for organic devices, and more particularly to patterning methods using a die. The method includes depositing a first layer of organic materials over a substrate; depositing a second layer of an electrode material over the first layer of organic materials; pressing a patterned die having a raised portion onto the second layer; and removing the patterned die. Preferably the patterned die is coated with a metal. Optionally the method includes depositing additional layers over the substrate prior to pressing the patterned die.

Abstract translation: 本发明涉及有机器件的图案化方法，更具体地涉及使用模具的图案化方法。 该方法包括在衬底上沉积第一层有机材料; 在所述第一有机材料层上沉积第二层电极材料; 将具有凸起部分的图案化模具压到第二层上; 并去除图案的模具。 优选地，图案化的模具被金属涂覆。 可选地，该方法包括在压制图案化的模具之前在衬底上沉积附加层。

公开(公告)号：US06198091B1

公开(公告)日：2001-03-06

申请号：US09136164

申请日：1998-08-19

Applicant: Stephen R. Forrest ,  Vladimir Bulovic

Inventor： Stephen R. Forrest ,  Vladimir Bulovic

IPC: H01L3100

CPC classification number: H01L27/302 ,  B82Y10/00 ,  H01L27/307 ,  H01L51/0046 ,  H01L51/0053 ,  H01L51/0078 ,  H01L51/4206 ,  H01L51/424 ,  Y02E10/549

Abstract: A stacked organic photosensitive optoelectronic device optimized to enhance desired characteristics such as external quantum efficiency, current and voltage. The photosensitive optoelectronic device has a plurality of photosensitive optoelectronic subcells electrically configured in subassemblies of two or more subcells electrically configured in series or in parallel. The subassemblies may be electrically configured in series or parallel. The substrate may be the bottom electrode or there may be a bottom electrode distinct from the substrate. Each subcell comprises one or more organic photoconductive layers between electrode layers or charge transfer layers. In one embodiment the top electrode is transparent. In other embodiments two or more electrodes are tarnsparent. In other embodiments photosensitive optoelectronic devices with multilayer photoconductive structures and photosensitive optoelectronic devices with a reflective layer or a reflective substrate are disclosed.

Abstract translation: 优化的层叠有机光敏光电器件，以增强所需特性，如外部量子效率，电流和电压。 光敏光电子器件具有多个光电子电子元件，电子配置为串联或并联电气配置的两个或多个子电池的子组件。 子组件可以串联或并联电气配置。 衬底可以是底部电极，或者可以存在与衬底不同的底部电极。 每个子电池在电极层或电荷转移层之间包括一个或多个有机光电导层。 在一个实施例中，顶部电极是透明的。 在其它实施例中，两个或多个电极是恍然的。 在其它实施例中，公开了具有多层光电导结构的光敏光电器件和具有反射层或反射衬底的光敏光电器件。