摘要:
Compounds of the formulae I and II ##STR1## are prepared by an addition reaction of a compound of the formula IIIR.sup.1 OH IIIwith an acetylene or allene of the formula IV or V ##STR2## where R.sup.1 and R are as defined, in the gas phase at elevated temperatures in the presence of a heterogeneous, silicate-containing catalyst, by a process in which the catalyst used is one which contains or consists of, as the active component, a zinc silicate obtained by precipitation in aqueous solution from a soluble silicon compound and zinc compound, zinc silicate beinga) an essentially X-ray amorphous zinc silicate of the formula VIZn.sub.a Si.sub.c O.sub.a+2c-0.5e (OH).sub.e.fH.sub.2 O VI, where e is from 0 to 2a+4c and the ratio a:c is from 1 to 3.5, and the ratio f:a is from 0 to 200, and/orb) a crystalline zinc silicate having the structure of hemimorphite of the formula Zn.sub.4 Si.sub.2 O.sub.7 (OH).sub.2.H.sub.2 O.
摘要翻译:式I和II的化合物通过在存在下在升高的温度下在气相中通过式III R1OHIII的化合物与式IV或V的炔或其中R1和R如所定义的二烯的加成反应来制备, 的不均一硅酸盐催化剂,其中使用的催化剂是含有或由作为活性组分的组成的方法,所述方法是通过在可溶性硅化合物和锌化合物的水溶液中沉淀而获得的硅酸锌,硅酸锌 a)基本上是式VI ZnaSicOa + 2c-0.5e(OH)e.fH2OVI的X射线无定形硅酸锌,其中e为0至2a + 4c,a:c为1至3.5,以及 比例f:a为0至200,和/或b)具有式Zn 4 Si 2 O 7(OH)2·H 2 O的半偏氟结构的结晶硅酸锌。
摘要:
A magneto-optical disk having at least one optically transparent, dimensionally stable substrate and at least one magneto-optical recording layer of a chromium-containing lanthanide/transition metal alloy, wherein the chromium concentration changes in the horizontal direction, and a process for the producton of the magneto-optical disks.
摘要:
The optical recording medium comprises at least one substrate and at least one storage layer of the phase change type with at least three reversibly interswitchable states of differing optical behavior, the difference in reflectivity between at least one pair of states being greater than between the amorphous and the crystalline state.
摘要:
In a magnetooptical computer disk having one or more optically transparent dimensionally stable substrates and one or more double layer systems consisting of two exchange-coupled magnetic layers which consist of alloys of rare earth metals with transition metals and have vertical magnetic anisotropy, the first magnetic layer adjacent to the substrate has a composition corresponding to the formula IRE.sub.x TM.sub.100-x-y-a Pt.sub.y A.sub.a Iand the second magnetic layer, which is arranged on that side of the first magnetic layer which faces away from the substrate, has a composition corresponding to the formula IIRE.sub.u TM.sub.100-u-b B.sub.b IIwhereRE is one or more elements from the group consisting of Gd, Tb, Dy and Ho,TM is one or more elements from the group consisting of Fe and Co,A and B independently of one another are elements from the group consisting of Cr, Nb, Ta, Al, Si, Ni and Mo,and5.ltoreq.x.ltoreq.30,0.5.ltoreq.y.ltoreq.20,15.ltoreq.u.ltoreq.30,0.ltoreq.a.ltoreq.25 and0.5.ltoreq.b.ltoreq.25.
摘要翻译:在具有一个或多个光学透明的尺寸稳定的基板和一个或多个双层系统的磁光计算机盘中,所述双层系统由由稀土金属与过渡金属的合金构成并且具有垂直的磁各向异性的两个交换耦合磁性层组成,第一磁性层 与基板相邻的具有对应于式I的组成RExTM100-xy-aPtyAa和布置在第一磁性层背离基板的那侧的第二磁性层具有对应于式II的组成 REuTM100-u-bBb II其中RE是由Gd,Tb,Dy和Ho组成的组中的一种或多种元素,TM是由Fe和Co组成的组中的一种或多种元素,A和B彼此独立地是元素 来自由Cr,Nb,Ta,Al,Si,Ni和Mo组成的组,5≤x≤30,0.5≤y≤20,15 u> 30, 0 = a = 25和0.5 = b = 25。
摘要:
A magnetic recording medium, essentially consisting of a polymeric, web-like substrate and a coherent thin layer of a ferromagnetic material, is produced in a chamber under reduced pressure by depositing a vapor jet of the ferromagnetic material onto the moving substrate surface guided over a roller-like cooling element.
摘要:
Dispersion comprising functionalized metal oxide particles, polymerizable compounds and if appropriate a solvent and their use for stabilizing polymers.
摘要:
In a device and a method for extracting non-magnetic ores from a pulp comprising non-magnetic ore particles and having a solid fraction of at least 30 mass percent, the pulp flows continuously through a reactor in the direction of flow and magnetic or magnetizable magnet particles that form ore magnetic particle agglomerations with the non-magnetic ore particles are added to said pulp. The ore magnetic particle agglomerations are moved by a magnetic field into an accumulation range of the reactor, and are then discharged out of reactor range and separated into ore and magnetic particles. In a device and a method, the separated magnetic particles are treated, in particular hydrophobized, such that during a new interaction with non-magnetic ore particles, new ore magnetic particle agglomerations are formed. Accordingly, a high yield of ores can be obtained and the mine can be operated in an economical and environmentally friendly manner.
摘要:
The present invention relates to a process for separating at least one first material from a mixture comprising this at least one first material and at least one second material, which comprises the steps: (A) production of a suspension of the mixture comprising at least one first material and at least one second material and at least one magnetic particle in a suitable suspension medium, (B) setting of the pH of the suspension obtained in step (A) to a value at which the at least one first material and the at least one magnetic particle bear opposite surface charges so that these agglomerate, (C) separation of the agglomerate obtained in step (B) from the suspension by application of a magnetic field and (D) dissociation of the agglomerate separated off in step (C) by setting of the pH to a value at which the at least one first material and the at least one magnetic particle bear the same surface charges in order to obtain the at least one first material.
摘要:
The present invention relates to a process for separating at least one first material from a mixture comprising this at least one first material and at least one second material, which comprises the following steps: (A) contacting of the mixture comprising at least one first material and at least one second material with at least one surface-active substance, if appropriate in the presence of at least one dispersant, resulting in the surface-active substance becoming attached to the at least one first material, (B) if appropriate, addition of at least one dispersant to the mixture obtained in step (A) to give a dispersion having a suitable concentration, (C) treatment of the dispersion from step (A) or (B) with at least one hydrophobic magnetic particle so that the at least one first material to which the at least one surface-active substance is bound and the at least one magnetic particle become attached to one another, (D) separation of the addition product from step (C) from the mixture by application of a magnetic field, (E) cleavage of the addition product which has been separated off in step (D) to obtain the at least one first material and the at least one magnetic particle separately.
摘要:
The invention relates to a catalyst for partially oxidizing hydrocarbons in the gas phase, containing a multi-metal oxide of the general formula (I), AgaMObVcMdOe.f H2O (I), wherein M stands for at least one element selected from among Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, B, Al, Ga, In, Si, Sn, Pb, P, Sb, Bi, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Au, Zn, Cd, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and U, a has a value of 0.5 to 1.5, b has a value of 0.5 to 1.5, c has a value of 0.5 to 1.5, a+b+c has the value 3, d has a value of less than 1, e means a number that is determined by the valence and frequency of the elements other than oxygen in the formula (I), f has a value of 0 to 20, which multi-metal oxide exists in a crystal structure, the X-ray powder diffractogram of which is characterized by diffraction reflections at a minimum of 5 lattice distances selected from among d=4.53, 3.38, 3.32, 3.23, 2.88, 2.57, 2.39, 2.26, 1.83, 1.77 AA (+−0.04 AA).