Process and element for obtaining a photographic image
    111.
    发明授权
    Process and element for obtaining a photographic image 失效
    用于获取摄影图像的过程和元件

    公开(公告)号:US4812390A

    公开(公告)日:1989-03-14

    申请号:US115760

    申请日:1987-10-30

    申请人: Pier G. Giannesi

    发明人: Pier G. Giannesi

    摘要: A photographic image is formed with silver halide emulsions by using optically unsensitized light sensitive (coarse) silver halide grains. Optically (or spectrally) sensitized fine grains (or crystals or particles),--especially light insensitive or Lippmann silver halide grains--, can be reactively associated with optically (or spectrally) unsensitized light sensitive (coarse) silver halide grains to get a combination of Spectrally Sensitized Fine Grains with Spectrally Unsensitized Light Sensitive or Coarse Grains, --especially Tabular Grains--, which can be imagewise exposed (to the light absorbed by the dye sensitizer adsorbed on the surface of such fine grains) and developed with substantially the same sensitivity of the light sensitive optically sensitized (coarse) silver halide grains.

    摘要翻译: 通过使用光学未敏化的光敏(粗)卤化银颗粒,用卤化银乳剂形成摄影图像。 光学(或光谱)敏化的细晶粒(或晶体或颗粒),特别是不透光的或Lippmann卤化银颗粒,可以与光学(或光谱)未敏化的光敏(粗)卤化银颗粒反应相关,以获得 具有光谱不敏感的光敏或粗粒(特别是片状颗粒)的光谱敏化细粒,可以成像曝光(吸附在这种细晶粒表面的染料敏化剂吸收的光),并以基本上相同的灵敏度 光敏光敏(粗)卤化银颗粒。

    Heat-development color light-sensitive material
    112.
    发明授权
    Heat-development color light-sensitive material 失效
    热成型感光材料

    公开(公告)号:US4677051A

    公开(公告)日:1987-06-30

    申请号:US801727

    申请日:1985-11-26

    CPC分类号: G03C1/49854

    摘要: A heat-developable color light-sensitive material is provided comprising on a support at least a light-sensitive silver halide emulsion, a binder, a compound capable of producing or releasing a mobile dye in direct or inverse proportion to the reaction of the light-sensitive silver halide being reduced into silver at elevated temperatures, and a dye having the general formula: ##STR1## wherein each of R.sup.1 and R.sup.2 is a substituted or unsubstituted alkyl or alkenyl group,R.sup.3 is a hydrogen atom, or substituted or unsubstituted alkyl, alkoxy, aryl or alkenyl group,each of X.sup.1, X.sup.2, X.sup.3, and X.sup.4 is a hydrogen atom, halogen atom, hydroxyl, carboxyl, or substituted or unsubstituted alkyl, alkoxy, alkoxycarbonyl, acyl, acyloxyl, aryl, amino, or acylamino group,X.sup.1 and X.sup.2, and X.sup.3 and X.sup.4 can be mutually combined to form a benzene ring,A.sup.- is an anion, andn is equal to 0 or 1.

    摘要翻译: 提供了一种可热显色的感光材料,其包括至少一种感光卤化银乳剂,粘合剂,能够以与发光体的反应成直接或相反比例产生或释放可移动染料的化合物, 敏感卤化银在升高的温度下还原成银,以及具有以下通式的染料:其中R1和R2各自为取代或未取代的烷基或烯基,R3为氢原子或取代或未取代的烷基, 烷氧基,芳基或烯基,X 1,X 2,X 3和X 4各自为氢原子,卤素原子,羟基,羧基或取代或未取代的烷基,烷氧基,烷氧基羰基,酰基,酰氧基,芳基,氨基或酰氨基 X1和X2,X3和X4可以相互组合形成苯环,A-是阴离子,n等于0或1。

    Silver halide photographic emulsion
    113.
    发明授权
    Silver halide photographic emulsion 失效
    卤化银照相乳剂

    公开(公告)号:US4622290A

    公开(公告)日:1986-11-11

    申请号:US795254

    申请日:1985-11-05

    CPC分类号: G03C1/29

    摘要: Disclosed is a silver halide photographic emulsion made highly sensitive to white light by use of a combination of at least one sensitizing dye represented by the general formula: ##STR1## wherein R.sub.1 represents a hydrogen atom, an alkyl group, or an aralkyl group, R.sub.2 represents a sulfoalkyl group, or a sulfoaralkyl group, and R.sub.3 represents an unsubstituted or substituted alkyl group, and at least one sensitizing dye represented by the general formula: ##STR2## wherein W.sub.1 to W.sub.4 represent each an alkyl group, an alkoxy group, or a hydroxyl group, or a pair of W.sub.1 and W.sub.2 or a pair of W.sub.3 and W.sub.4 forms an alkylenedioxy group, provided that said pair of W.sub.1 and W.sub.2 and said pair of W.sub.3 and W.sub.4 have each at least one alkoxy or hydroxyl group or said alkylenedioxy group; R.sub.4 represents a hydrogen atom, an alkyl group, an aralkyl group, or an aryl group; R.sub.5 represents a sulfoalkyl group or a sulfoaralkyl group; and R.sub.6 represents an unsubstituted or substituted alkyl group.

    摘要翻译: 公开了通过使用由以下通式表示的至少一种敏化染料的组合对白光进行高度敏感的卤化银照相乳剂:其中R 1表示氢原子,烷基或芳烷基 基团,R 2表示磺基烷基或磺基烷基,R 3表示未取代或取代的烷基,以及至少一种由以下通式表示的敏化染料:其中W1至W4各自表示烷基 ,一个或多个W 1和W 2或一对W 3和W 4形成亚烷基二氧基,条件是所述一对W1和W2以及所述一对W3和W4各自具有至少一个烷氧基 或羟基或所述亚烷基二氧基; R4表示氢原子,烷基,芳烷基或芳基; R5表示磺基烷基或磺基烷基; R6表示未取代或取代的烷基。

    Photographic compositions and elements spectrally sensitized with new
methine dyes
    116.
    发明授权
    Photographic compositions and elements spectrally sensitized with new methine dyes 失效
    用新的次甲基染料光谱增感的摄影组合物和元素

    公开(公告)号:US4375508A

    公开(公告)日:1983-03-01

    申请号:US311586

    申请日:1981-10-15

    IPC分类号: G03C1/12 G03C1/18

    CPC分类号: G03C1/12 G03C1/18

    摘要: Photographic silver halide compositions and elements are provided which are spectrally sensitized with new methine dyes. The dyes are prepared from new intermediate compounds which have an acetylenically unsaturated hydrocarbon chain terminated with a nucleophilic group, the acetylenically unsaturated hydrocarbon chain being bonded to a nitrogen atom in a heterocyclic ring system of the type used in cyanine dyes. The new intermediates also provide alternative synthetic routes to known dyes.

    摘要翻译: 提供了使用新的次甲基染料进行光谱增感的照相卤化银组合物和元素。 染料由具有以亲核基团封端的炔属不饱和烃链的新中间体化合物制备,炔基不饱和烃链与花青染料中所用类型的杂环体系中的氮原子结合。 新的中间体还提供了已知染料的替代合成路线。

    Silver halide photographic emulsion
    117.
    发明授权
    Silver halide photographic emulsion 失效
    卤化银照相乳剂

    公开(公告)号:US4179296A

    公开(公告)日:1979-12-18

    申请号:US860919

    申请日:1977-12-15

    CPC分类号: G03C1/29

    摘要: A silver halide photographic emulsion containing, in supersensitizing amounts, a combination ofat least one benzimidazolocarbocyanine dye wherein an aralkyl group substituted with an acidic group is connected to at least one nitrogen atom in the imidazole ring, which is represented by the following general formula (I): ##STR1## wherein V.sub.1, V.sub.2, V.sub.3 and V.sub.4, which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an acyl group, an acyloxy group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a trifluoromethyl group or a hydroxy group; R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, each represents an aliphatic group; A represents a sulfo group of a carboxy group; X.sub.1 represents an acid residue; h represents an integer from 1 to 6; and i represents 0 or 1; andat least one cyanine dye represented by the following general formula (II): ##STR2## wherein Z.sub.1 represents the atoms necessary to complete a thiazole ring or a selenazole ring; Z.sub.2 represents the atoms necessary to complete a thiazole ring, a selenazole ring or an oxazole ring; R.sub.4 represents a hydrogen atom, an aliphatic group or an aryl group; R.sub.5 and R.sub.6, which may be the same or different, each represents an aliphatic group; X.sub.2 represents an acid residue; and l and n each represents 0 or 1; which demonstrates reduced fog, reduced residual color and high sensitivity, and, further, which is endowed with desirable spectral sensitization distribution and minimized deterioration with the lapse of time under high temperature and humidity conditions.

    摘要翻译: 一种卤化银感光乳剂,其以超敏量的量含有至少一种苯并咪唑羰花青染料的组合,其中由酸性基团取代的芳烷基与咪唑环中的至少一个氮原子连接,其由以下通式( I):其中V1,V2,V3和V4可以相同或不同,各自表示氢原子,卤素原子,烷基,烯基,环烷基,酰基 基团,酰氧基,烷氧基羰基,氨基甲酰基,氨磺酰基,氰基,三氟甲基或羟基; R 1,R 2和R 3可以相同或不同,各自表示脂族基团; A表示羧基的磺基; X1表示酸残基; h表示1〜6的整数, i表示0或1; 和由以下通式(II)表示的至少一种花青染料:其中Z1表示完成噻唑环或硒唑环所需的原子; Z2表示完成噻唑环,硒咯环或恶唑环所需的原子; R4表示氢原子,脂族基或芳基; R 5和R 6可以相同或不同,各自表示脂族基团; X2表示酸残基; l和n各自表示0或1; 这表明减少了雾,降低了残留颜色和高灵敏度,并且进一步地,其具有期望的光谱增感分布,并且在高温和高湿条件下随时间流逝的最小化劣化。

    Lith-type silver halide photographic light-sensitive material
    119.
    发明授权
    Lith-type silver halide photographic light-sensitive material 失效
    Lith型卤化银照相感光材料

    公开(公告)号:US4121935A

    公开(公告)日:1978-10-24

    申请号:US822601

    申请日:1977-08-08

    IPC分类号: G03C1/18 G03C5/04 G03C1/06

    CPC分类号: G03C1/18

    摘要: A lith-type silver halide photographic light-sensitive material for forming halftone dot images is disclosed which contains a sensitizing dye represented by the following general formula: ##STR1## WHEREIN Z.sub.1 is an atomic group necessary for forming a naphthothiazole ring, Z.sub.2 is an atomic group necessary for forming a member selected from a group consisting of substituted or unsubstituted, benzothiazole, benzoselenazole, naphthothiazole and naphthoselenazole nucleus, R.sub.1 and R.sub.2 are respectively a substituted or unsubstituted alkyl group, X.sup..theta. is an anion, and n is a positive integer of 1 or 2 with the proviso that when the dye is an inner salt, n is 1.

    摘要翻译: 公开了一种用于形成半色调点图像的锂型卤化银摄影感光材料,其包含由以下通式表示的增感染料:其中Z1是形成萘并噻唑环所必需的原子团,Z 2是原子 形成选自取代或未取代的苯并噻唑,苯并硒唑,萘并噻唑和萘并恶唑核的成员所需的基团,R1和R2分别为取代或未取代的烷基,X是阴离子,n是正整数 1或2,条件是当染料为内盐时,n为1。