Abstract:
A dried film reinforced with coalescable water insoluble polymer particles which are substantially noncoalesced is disclosed. Also disclosed are dried films reinforced with noncoalesced water insoluble polymer particles which are readily water dispersible. Also disclosed are stable aqueous dispersions for formation of such films which comprise (a) a water insoluble component comprising coalescable polymer particles which have a T.sub.g less than 55.degree. C. and a majority of which have a particle size of less than 1 micron; and (b) a water soluble component which comprises a water soluble polymer capable of inhibiting coalescence of the polymer particles, or a water soluble polymer and a component capable of inhibiting coalescence of the polymer particles.
Abstract:
Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.
Abstract:
A dried film reinforced with coalescable water insoluble polymer particles which are substantially noncoalesced is disclosed. Also disclosed are dried films reinforced with noncoalesced water insoluble polymer particles which are readily water dispersible. Also disclosed are stable aqueous dispersions for formation of such films which comprise (a) a water insoluble component comprising coalescable polymer particles which have a T.sub.g less than 55.degree. C. and a majority of which have a particle size of less than 1 micron; and (b) a water soluble component which comprises a water soluble polymer capable of inhibiting coalescence of the polymer particles, or a water soluble polymer and a component capable of inhibiting coalescence of the polymer particles.
Abstract:
A method of improving tannin stain blocking in a tannin-containing substrate is disclosed which involves applying to the substrate a blend of:(a) an acid-functional polymer formed from about 0.1% by weight to about 20% by weight, based on the total weight of said polymer, of at least one acid-functional monomer; and(b) about 0.1% by weight to about 20% by weight, based on the weight of said acid-functional polymer, of at least one organosilane having a number average molecular weight of from about 100 to about 10,000.A method of improving the physical properties of the coating composition, including viscosity, adhesion, scrub resistance, water whitening resistance, corrosion resistance, hot block resistance and water, fire, smoke, nicotine, pen and ink stain blocking is also disclosed.
Abstract:
Provided are coating-forming coating compositions comprising the following components A and B, preferably further including the following component C and/or D, and having superior surface hardness, abrasion resistance, flexibility, dyeability and durability, as well as coatings formed by curing such coating compositions:A. A vinyl polymer having a group represented by the general formula R.sup.1.sub.m (R.sup.2 O).sub.3-m Si- wherein R.sup.1 is methyl or ethyl, R.sup.2 is an alkyl, alkoxyalkyl or acyl group having not more than 4 carbon atoms, with silicon being attached to the polymer by Si-C bond, and m is 0, 1 or 2.B. Fine particles of silica having an average diameter of particles in the range of about 1 to about 200 nm.C. A curing catalyst.D. At least one compound selected from the group consisting of acrylic resins, polyester resins, alkyd resins, epoxy resins, cellulose resins, amino resins and silicon compounds represented by the general formula R.sup.5.sub.a R.sup.6.sub.b Si(OR.sup.7).sub.4-(a+b) wherein R.sup.5 and R.sup.6 are each an alkyl, alkenyl, aryl, halogenated alkyl or alkenyl group having 1 to 10 carbon atoms or an epoxy, (meth)acryloxy or cyano group, bonded to silicon by Si-C bond, R.sup.7 is an alkyl, alkoxyalkyl or acyl group having 1 to 8 carbon atoms, a and b are each 0, 1 or 2 provided a+b equals 0, 1 or 2.
Abstract:
Amino-formaldehyde products with activated carboxylic ester groups cross-link compounds containing pendant primary or secondary amine groups.
Abstract:
A polymeric finely-divided powder coating composition comprising a homogeneous blend of certain quantities of a solid polymeric material having a comparatively low molecular weight and containing certain reactive groups blended with certain quantities of tetrakismethoxymethylglycoluril.
Abstract:
A heat-curable coating composition contains a polymer having pendant amine groups and a bis-maleimide cross-linking agent in aqueous dispersion. The amine groups of the polymer are protonated to render the polymer water dispersible. The amine groups are adapted to become de-protonated for cross-linking with the bis-maleimide under heating to form a fully cured film. In a preferred embodiment, the coating composition serves as a cathodic electrocoating composition.
Abstract:
RADIATION CURABLE POLYMERS HAVING THE VINYL -(5-NORBORNENE-2-YLMETHYL) CARBAMATE GROUP POLYMERIZED THEREIN ARE USEFUL FOR THE PRODUCTION OF CROSSLINKED COATINGS, FILMS, 2WIRE INSULATION AND FABRIC TREATMENT.