公开(公告)号：US06242046B1

公开(公告)日：2001-06-05

申请号：US09446249

申请日：1999-12-20

申请人： Yoshinori Nakane ,  Shun Saito ,  Akihiro Osuka ,  Kishio Shibato

发明人： Yoshinori Nakane ,  Shun Saito ,  Akihiro Osuka ,  Kishio Shibato

IPC分类号： B05D302

CPC分类号： C09D1/00 ,  C09K3/18

摘要： The present invention relates to a stainproof-treating agent which comprises (A) 0.05 to 30 percent by weight of a nonvolatile resin ingredient, (B) 0.05 to 30 percent by weight of a nonvolatile ingredient of at least one oxide sol selected from the group consisting of an aluminum oxide sol, a silica sol, a zirconium oxide sol and an antimony oxide sol, (C) 1 to 50 percent by weight of an organic solvent and (D) 40 to 99 percent by weight of water, wherein the resin of the ingredient (A) has a solubility parameter of 10 or more and is insoluble in water at 25° C., a method for stainproof-treating by using the stainproof-treating agent and a stainproof-treated article obtained by the method for stainproof-treating. The stainproof-treating agent of the present invention can be applied on a substrate without requiring a special device and can provide excellent stain resistance by modifying a substrate surface hydrophilic by a simple work. Also, the method for stainproof-treating of the present invention can provide excellent stain resistance on the substrate by a simple work. Further, the stainproof-treated article of the present invention is an article obtained by the method for stainproof-treating described above and is excellent in stain resistance.

摘要翻译： 本发明涉及一种防污处理剂，其包含（A）0.05〜30重量％的不挥发性树脂成分，（B）0.05〜30重量％的至少一种选自下组的氧化物溶胶的不挥发成分： 由氧化铝溶胶，硅溶胶，氧化锆溶胶和氧化锑溶胶组成，（C）1〜50重量％的有机溶剂和（D）40〜99重量％的水，其中树脂 的成分（A）的溶解度参数为10以上，在25℃下不溶于水，使用防污处理剂进行防污处理的方法和通过防污染方法得到的防污处理物 打算 本发明的防污处理剂可以在不需要特殊装置的情况下施加在基材上，并且可以通过简单的工作改性亲水性的基材表面来提供优异的耐污性。 此外，本发明的防污处理方法可以通过简单的工作在基材上提供优异的耐污性。 此外，本发明的防污处理物是通过上述防污处理方法得到的制品，耐污染性优异。

公开(公告)号：US5908900A

公开(公告)日：1999-06-01

申请号：US693075

申请日：1996-08-13

申请人： Yasuhrio Momna ,  Yasushi Sugihara ,  Kishio Shibato

发明人： Yasuhrio Momna ,  Yasushi Sugihara ,  Kishio Shibato

IPC分类号： C09D5/00 ,  C09D7/12 ,  C08G18/28 ,  C08G18/06 ,  C08C19/22 ,  B05D5/00

CPC分类号： C09D7/1266 ,  C09D7/125 ,  C09D7/1275 ,  C09D7/1283

摘要： To obtain elasticity imparting agents for paints comprised of liquid non-aqueous polymer dispersions which, when added to paints, improve the scratch resistance without lowering the acid resistance of the hardened paint film. A liquid non-aqueous polymer dispersion which contains (a) 40-90 percent by weight organic solvent, (b) 10-50 percent by weight particle component comprised vinyl based copolymer which contains 30 percent by weight or more of structural units of formula (1), and (c) 5-40 percent by weight dispersion stabilizer for dispersing the (b) component in the (a) component. In formula (1) R.sup.1 -R.sup.5 are H or methyl groups, m is 0-2, n is 0-10, p is 0 or 1, q is 0-3 and r is 0-3.

摘要翻译： PCT No.PCT / EP95 / 00412 Sec。 371日期：1996年8月13日 102（e）日期1996年8月13日PCT提交1995年2月6日PCT公布。 出版物WO95 / 21895 日期1995年8月17日为了获得由液体非水性聚合物分散体组成的涂料的弹性赋予剂，当添加到涂料中时，改善耐划伤性而不降低硬化漆膜的耐酸性。 一种液体非水性聚合物分散体，其包含（a）40-90重量％的有机溶剂，（b）10-50重量％的颗粒组分，包含乙烯基类共聚物，其含有30重量％以上的结构单元（式 1）和（c）5-40重量％的（b）成分分散在（a）成分中的分散稳定剂。 在式（1）中，R 1 -R 5为H或甲基，m为0-2，n为0-10，p为0或1，q为0-3，r为0-3。

公开(公告)号：US5352740A

公开(公告)日：1994-10-04

申请号：US680356

申请日：1991-04-04

申请人： Masahiro Ishidoya ,  Kishio Shibato ,  Keiji Komoto ,  Kenji Shibamoto ,  Mitsuyuki Mashita ,  Osamu Ohe

发明人： Masahiro Ishidoya ,  Kishio Shibato ,  Keiji Komoto ,  Kenji Shibamoto ,  Mitsuyuki Mashita ,  Osamu Ohe

IPC分类号： C08F299/02 ,  C07C69/00 ,  C08F8/14 ,  C08F290/00 ,  C08G18/42 ,  C08G18/82 ,  C08G59/00 ,  C08G59/20 ,  C08G59/32 ,  C08G59/40 ,  C08G59/68 ,  C08G63/00 ,  C08G63/91 ,  C08G69/00 ,  C08L33/02 ,  C08L63/00 ,  C08L67/00 ,  C08L67/02 ,  C08L67/06 ,  C09D163/00 ,  C09D167/00 ,  C09D167/06 ,  C09J167/00 ,  C09J167/06

CPC分类号： C09D167/00 ,  C08L67/00 ,  C09D163/00 ,  C09J167/00

摘要： Thermosetting composition is excellent in storage stability, useful as one component thermosetting composition, gives cured products having excellent chemical properties, physical properties and weathering resistance and is favorably utilized in coating compositions, ink, adhesive and molded plastics.The thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating and optionally a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.

摘要翻译： 热固性组合物的储存稳定性优异，可用作一种组分的热固性组合物，具有优异的化学性质，物理性能和耐候性的固化产物，并且有利地用于涂料组合物，油墨，粘合剂和模塑料中。 热固性组合物包含在分子中具有被乙烯基醚化合物封闭的两个或多个羧基，乙烯基硫醚化合物或具有乙烯基型双键的杂化合物和氧或硫作为杂原子的化合物，具有两个或多个 可以通过加热和任选的热潜酸催化剂与封端的羧基化合物形成化学键的更多的反应性官能团。 第一化合物的封端羧基和第二化合物的反应性官能团可以包含在相同的分子中。

公开(公告)号：US5319024A

公开(公告)日：1994-06-07

申请号：US683301

申请日：1991-04-10

申请人： Masahiro Ishidoya ,  Kishio Shibato ,  Keiji Komoto ,  Kenji Shibamoto ,  Yoshinori Nakane

发明人： Masahiro Ishidoya ,  Kishio Shibato ,  Keiji Komoto ,  Kenji Shibamoto ,  Yoshinori Nakane

IPC分类号： C08F299/02 ,  C08F290/00 ,  C08G18/62 ,  C08G59/00 ,  C08G59/20 ,  C08G59/32 ,  C08G59/40 ,  C08G59/68 ,  C08G63/00 ,  C08K5/00 ,  C08L63/00 ,  C08L67/00 ,  C08L67/06 ,  C08L101/02 ,  C09D167/00 ,  C09D167/06 ,  C09D187/00 ,  C09J159/00 ,  C09J167/00 ,  C09J167/06 ,  C09J187/00 ,  C08F8/30

CPC分类号： C08L101/02 ,  C08L63/00 ,  C08L67/00

摘要： Thermosetting compositions which are excellent in storage stability, useful as one component thermosetting compositions, give cured products having excellent chemical properties, physical properties and weathering resistance and favorably utilized in coating compositions, ink, adhesive and molded plastics. The thermosetting compositions comprises a compound having in the molecule two or more hydroxyl groups and/or thiol groups blocked by a vinyl ether compound, a vinyl thioether compound or a heterocyclic compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked hydroxyl and/or thiol compound by heating and a thermal latent acid catalyst. The blocked hydroxyl and/or thiol group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.

摘要翻译： 作为一种组分的热固性组合物，具有优异的储存稳定性的热固性组合物，得到具有优异的化学性质，物理性能和耐候性的固化产物，并且有利地用于涂料组合物，油墨，粘合剂和模制塑料中。 热固性组合物包含在分子中具有由乙烯基醚化合物，乙烯基硫醚化合物或具有乙烯基型双键和氧或硫作为杂原子的杂环化合物封闭的羟基和/或硫醇基的分子中的化合物， 具有两个或更多个反应性官能团的化合物，其可以通过加热与封闭的羟基和/或硫醇化合物形成化学键和热潜酸催化剂。 第一化合物的封端羟基和/或硫醇基团和第二化合物的反应性官能团可以包含在相同的分子中。

公开(公告)号：US06689839B1

公开(公告)日：2004-02-10

申请号：US08952566

申请日：1998-09-11

申请人： Takehi Hayakawa ,  Kishio Shibato ,  Yasuhiro Monma

发明人： Takehi Hayakawa ,  Kishio Shibato ,  Yasuhiro Monma

IPC分类号： C08F830

CPC分类号： C08G18/6279 ,  C08G18/4063 ,  C08G18/6229 ,  C08G18/6233 ,  C09D175/04 ,  C08L2666/16

摘要： Thermoset paint compositions with which paint films can be formed which have excellent acid resistance, abrasion resistance and adhesion, and with which the water repelling properties and staining resistance can be retained for a longer period of time than with the conventional fluorine resin based paint films, are obtained. Constitution: Thermoset paint film compositions which contain (a) from 20 to 80% by weight of fluorine containing copolymer, comprising fluoro-olefin and vinyl based monomer, of which the solubility parameter value is from 9.0 to 10.5 and the hydroxy group value is within the range from 60 to 150 mgKOH/g; (b) from 20-80% by weight of vinyl based (co)polymer, comprising vinyl based monomer which contains at least 10% by weight of monomer which can be repesented by formula (1), of which the solubility parameter is from 9.0 to 10.5 and the hydroxy group value is within the range from 60 to 150 mgKOH/g; (c) from 5 to 40% by weight of alkyl etherified melanine resin; and (d) from 2 to 40% by weight of blocked polyisocyanate compound, and with which the glass transition temperature of the paint film after hardening is at least 50° C. In formula (1), R1 to R5 each independantly represent H or methyl group, i is 0-2, j is 0 or 1, k is 0-3, m is 0-3 and n is 0-10.

摘要翻译： 可以形成具有优异的耐酸性，耐磨性和粘附性的涂膜的热固性涂料组合物，并且与常规的氟树脂基漆膜相比，可以在较长的时间内保持防水性和耐污染性， 获得。 结构：热固性漆膜组合物，其含有（a）20〜80重量％的含氟共聚物，包含氟代烯烃和乙烯基类单体，溶解度参数值为9.0-10.5，羟基值在 范围为60至150 mgKOH / g; （b）20-80重量％的乙烯基（共）聚合物，其包含含有至少10重量％可通过式（1）重新反应的单体的乙烯基类单体，其溶解度参数为9.0 至10.5，羟基值在60〜150mgKOH / g的范围内; （c）5至40重量％的烷基醚化的蜜胺树脂; 和（d）2〜40重量％的封端多异氰酸酯化合物，硬化后的漆膜的玻璃化转变温度为至少50℃。在式（1）中，R 1〜R 5 各自独立代表H或甲基，i为0-2，j为0或1，k为0-3，m为0-3，n为0-10。

公开(公告)号：US5660937A

公开(公告)日：1997-08-26

申请号：US401368

申请日：1995-03-09

申请人： Masahiro Ishidoya ,  Kishio Shibato ,  Keiji Komoto ,  Kenji Shibamoto ,  Mitsuyuki Mashita ,  Osamu Ohe

发明人： Masahiro Ishidoya ,  Kishio Shibato ,  Keiji Komoto ,  Kenji Shibamoto ,  Mitsuyuki Mashita ,  Osamu Ohe

IPC分类号： B32B27/30 ,  B32B27/36 ,  B32B27/38 ,  C08L29/00 ,  C08L33/00 ,  C08L33/02 ,  C08L33/06 ,  C08L37/00 ,  C08L63/00 ,  C08L67/00 ,  C08L67/02 ,  C08L101/02 ,  C09D133/10 ,  C09D163/00 ,  C09D167/00 ,  C09D201/02 ,  C09J167/00

CPC分类号： C08L67/00 ,  C08L101/02 ,  C09D133/10 ,  C09D163/00 ,  C09D167/00 ,  C09D201/02 ,  C09J167/00 ,  C08L33/06 ,  C08L63/00 ,  Y10T428/31511 ,  Y10T428/31518 ,  Y10T428/31529 ,  Y10T428/31551 ,  Y10T428/31699 ,  Y10T428/31786 ,  Y10T428/31794 ,  Y10T428/31797 ,  Y10T428/31928 ,  Y10T428/31935

摘要： Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.

摘要翻译： 热固性组合物包含在分子中具有被乙烯基醚化合物封闭的两个或多个羧基的化合物，乙烯基硫醚化合物或具有乙烯基型双键的杂化合物和氧或硫作为杂原子的化合物，具有两个或更多个 可通过加热与封端的羧基化合物形成化学键的反应性官能团，特定的乙烯基醚或乙烯基硫醚和热潜在酸催化剂。 第一化合物的封端羧基和第二化合物的反应性官能团可以包含在相同的分子中。 热固性组合物提供具有优异的化学性质，物理性能，耐候性和储存稳定性的固化产物，并且有利地用于涂料组合物，油墨，粘合剂和模制塑料。

公开(公告)号：US5516839A

公开(公告)日：1996-05-14

申请号：US260002

申请日：1994-06-15

申请人： Masahiro Ishidoya ,  Kishio Shibato ,  Keiji Komoto ,  Kenji Shibamoto ,  Mitsuyuki Mashita ,  Osamu Ohe

发明人： Masahiro Ishidoya ,  Kishio Shibato ,  Keiji Komoto ,  Kenji Shibamoto ,  Mitsuyuki Mashita ,  Osamu Ohe

IPC分类号： C08F299/02 ,  C07C69/00 ,  C08F8/14 ,  C08F290/00 ,  C08G18/42 ,  C08G18/82 ,  C08G59/00 ,  C08G59/20 ,  C08G59/32 ,  C08G59/40 ,  C08G59/68 ,  C08G63/00 ,  C08G63/91 ,  C08G69/00 ,  C08L33/02 ,  C08L63/00 ,  C08L67/00 ,  C08L67/02 ,  C08L67/06 ,  C09D163/00 ,  C09D167/00 ,  C09D167/06 ,  C09J167/00 ,  C09J167/06

CPC分类号： C09D167/00 ,  C08L67/00 ,  C09D163/00 ,  C09J167/00

摘要： A thermal latent compound which is prepared by a reaction of a polycarboxyl compound having two or more carboxyl groups in the molecule, having an acid equivalent of not more than 1000 g/mole and a number average molecular weight of not more than 4000, with a monovinyl ether compound, wherein at least two carboxyl groups are transformed into a functional group of the formula (1): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are each a hydrogen atom or an organic group of 1 to 18 carbon atoms, R.sup.4 is an organic group of 1 to 18 carbon atoms, Y.sup.1 is an oxygen atom or R.sup.3 and R.sup.4 are bonded together to form a heterocyclic with Y.sup.1 as a heteroatom.

摘要翻译： 通过在分子中具有两个以上羧基的多羧基化合物反应制备的热潜组合物，其酸当量不大于1000克/摩尔，数均分子量不大于4000，与 其中至少两个羧基被转化成式（1）的官能团：其中R 1，R 2和R 3各自为氢原子或1至18个碳原子的有机基团 R4是1〜18个碳原子的有机基团，Y1是氧原子，R3和R4键合在一起形成与Y1作为杂原子的杂环。

公开(公告)号：US20110274844A1

公开(公告)日：2011-11-10

申请号：US12744169

申请日：2008-10-22

申请人： Kishio Shibato ,  Tsuyoshi Shinjo ,  Takeshi Nomoto

发明人： Kishio Shibato ,  Tsuyoshi Shinjo ,  Takeshi Nomoto

IPC分类号： B05D7/24 ,  B05D3/00 ,  C09D5/00

CPC分类号： C09G1/16 ,  C09D5/1675 ,  C09D5/1687 ,  C09D183/08

摘要： An agent for imparting stain resistance to a top-coat paint film that has (a) from 3 to 10 mass % of a compound represented by Formula (1) or a partial hydrolysis condensate thereof, wherein Formula (1) is R1—(OCH2CH2)n—O—Si(OR2)3 wherein R1 is an alkyl group having 1 to 6 carbon atoms or a hydrogen atom, R2 is the same or different and is an alkyl group having 1 to 6 carbon atoms, and n is an integer value from 2 to 4, (b) from 0.01 to 1 mass % of a catalyst with which the aforementioned (a) component can be hydrolyzed, (c) 0.5 to 3 mass % of an alkylsulfosuccinic acid salt based surfactant, and (d) from 86 to 96.49 mass % of an alcohol based solvent which has not more than 3 carbon atoms. A method for imparting stain resistance to a top-coat paint film employing the disclosed agent is also provided.

摘要翻译： 具有（a）3〜10质量％的式（1）所示的化合物或其部分水解缩合物的表面漆膜赋予耐污染性的试剂，式（1）为R1-（OCH2CH2 ）n-O-Si（OR2）3，其中R1是具有1至6个碳原子的烷基或氢原子，R2相同或不同，并且是具有1至6个碳原子的烷基，n是整数 值为2〜4，（b）0.01〜1质量％的上述（a）成分可以水解的催化剂，（c）0.5〜3质量％的烷基磺基琥珀酸盐系表面活性剂，（d） 86〜96.49质量％的碳原子数为3以下的醇系溶剂。 还提供了使用所公开的试剂赋予顶涂漆膜耐污性的方法。

公开(公告)号：US06797391B2

公开(公告)日：2004-09-28

申请号：US10111132

申请日：2002-04-23

申请人： Kishio Shibato ,  Yoshinori Nakane ,  Shinichi Ikehara ,  Keisuke Kojima

发明人： Kishio Shibato ,  Yoshinori Nakane ,  Shinichi Ikehara ,  Keisuke Kojima

IPC分类号： B32B2520

CPC分类号： C09D163/00 ,  C08F283/12 ,  C08K5/42 ,  C09D151/08 ,  C09D151/085 ,  C09D151/10 ,  Y10T428/31663 ,  C08L2666/28 ,  C08L2666/02

摘要： A nonstaining coating composition which comprises as essential components (A) a specific aliphatic sulfonic acid compound or amine salt thereof, (B) a compound having per molecule at least one functional group selected among carboxly, a carboxly anhydride group, and a carboxyl group blocked with an alkyl vinyl ether, (C) a specific organosilicate and/or a condensate thereof, and (D) a resin having epoxy groups and/or alkoxysilyl groups in the molecule; and a method of finish coating. They give a cured coating film which has nonstaining properties based on a high degree of hydrophilicity from immediately after the formation thereof and has satisfactory long-term weatherability, water resistance, and chemical resistance. The film can impart an excellent finish appearance to the article

摘要翻译： 一种不污染涂料组合物，其包含作为必要组分（A）的特定脂族磺酸化合物或其胺盐，（B）每分子至少一个选自羧基，羧酸酐基和羧基中的官能团的化合物封闭 烷基乙烯基醚，（C）特定的有机硅酸盐和/或其缩合物，和（D）在分子中具有环氧基和/或烷氧基甲硅烷基的树脂; 和一种完成涂覆的方法。 它们得到一种固化涂膜，其具有基于其形成后立即具有高亲水性的不污染性，并且具有令人满意的长期耐候性，耐水性和耐化学性。 该片可以赋予该物品优异的完美外观

公开(公告)号：US5521011A

公开(公告)日：1996-05-28

申请号：US444160

申请日：1995-05-18

申请人： Masahiro Ishidoya ,  Kishio Shibato ,  Keiji Komoto ,  Kenji Shibamoto ,  Mitsuyuki Mashita ,  Osamu Ohe

发明人： Masahiro Ishidoya ,  Kishio Shibato ,  Keiji Komoto ,  Kenji Shibamoto ,  Mitsuyuki Mashita ,  Osamu Ohe

IPC分类号： B32B27/30 ,  B32B27/36 ,  B32B27/38 ,  C08L29/00 ,  C08L33/00 ,  C08L33/02 ,  C08L33/06 ,  C08L37/00 ,  C08L63/00 ,  C08L67/00 ,  C08L67/02 ,  C08L101/02 ,  C09D133/10 ,  C09D163/00 ,  C09D167/00 ,  C09D201/02 ,  C09J167/00

CPC分类号： C08L67/00 ,  C08L101/02 ,  C09D133/10 ,  C09D163/00 ,  C09D167/00 ,  C09D201/02 ,  C09J167/00 ,  C08L33/06 ,  C08L63/00 ,  Y10T428/31511 ,  Y10T428/31518 ,  Y10T428/31529 ,  Y10T428/31551 ,  Y10T428/31699 ,  Y10T428/31786 ,  Y10T428/31794 ,  Y10T428/31797 ,  Y10T428/31928 ,  Y10T428/31935

摘要： An article coated by a method of coating which comprises coating a substrate with a top coating material comprising at least one pigment and a thermosetting composition, the at least one pigment being in an amount of 0 to 100 weight parts based on 100 weight parts of the thermosetting composition, the thermosetting composition comprising (A) a compound having in the molecule two or more functional groups of the formula (I): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are each selected from the group consisting of a hydrogen atom and an organic group of 1 to 18 carbon atoms, R.sup.4 is an organic group of 1 to 18 carbon atoms, Y.sup.1 is oxygen or sulfur, or R.sup.3 and R.sup.4 are bonded with each other to form a heterocyclic structure which comprises Y.sup.1 as the hetero atom; (B) a compound having in the molecule two or more reactive functional groups which can form chemical bonds with the functional groups of the compound (A) by heating, the reactive functional groups of the compound (B) are epoxy groups; and (F) a complex compound formed by coordination of a conjugated base of a Bronsted acid or a Bronsted salt to a vacant orbital of a Lewis acid in a mol ratio of the Bronsted acid or Bronsted salt to the vacant orbital of the Lewis acid of 0.1 to 4.

摘要翻译： 一种通过涂覆方法涂覆的制品，其包括用包含至少一种颜料和热固性组合物的顶部涂料涂覆基材，所述至少一种颜料的量为0至100重量份，基于100重量份的 所述热固性组合物包含（A）分子中具有式（I）的两个或多个官能团的化合物：其中R 1，R 2和R 3各自选自氢 原子和1至18个碳原子的有机基团，R 4是1至18个碳原子的有机基团，Y 1是氧或硫，或者R 3和R 4彼此键合，形成杂环结构，其包含Y1作为杂原子 原子; （B）化合物在分子中具有两个或更多个可通过加热与化合物（A）的官能团形成化学键的反应性官能团，化合物（B）的反应性官能团是环氧基; 和（F）通过将布朗斯台德酸或布朗斯台德盐的共轭碱与布朗斯台德酸或布朗斯特盐的摩尔比与路易斯酸的空位轨道配位的络合物与路易斯酸的空位轨道 0.1至4。