公开(公告)号：US3816285A

公开(公告)日：1974-06-11

申请号：US20336271

申请日：1971-11-30

Applicant: UNION CARBIDE CORP

Inventor： OSBORN C ,  SANDNER M ,  TRECKER D

IPC: B01J19/12 ,  C07C2/42 ,  C07C17/02 ,  C07C17/14 ,  C07C51/567 ,  C07C303/04 ,  C07C309/25 ,  C07D305/14 ,  B01J1/10

CPC classification number: C07D305/14 ,  B01J19/122 ,  B01J2219/0894 ,  C07C2/42 ,  C07C17/02 ,  C07C17/14 ,  C07C51/567 ,  C07C303/04 ,  C07C13/64 ,  C07C23/12 ,  C07C22/06 ,  C07C61/29 ,  C07C309/25

Abstract: Non-ionizing high intensity predominantly continuum light radiation having a source intensity of at least about 350 watts per square centimeter steradian when integrated throughout the entire spectral range of said continuum light radiation is used as the energy source in photochemical reactions. A convenient source of this non-ionizing high intensity predominantly continuum light radiation is a swirl-flow plasma arc radiation apparatus. Among the photochemical reactions that can be carried out, at unexpectedly faster rates and at higher conversions, are photoreduction reactions, photocycloaddition reactions, oxetane formation reactions, halogen additions, halogen substitutions, photonitrosation reactions, photosulfoxidation reactions, bisulfite addition reactions, and many other photochemical addition and substitution reactions.

公开(公告)号：US3789042A

公开(公告)日：1974-01-29

申请号：US3789042D

申请日：1971-05-26

Applicant: UNION CARBIDE CORP

Inventor： COLOMB H ,  TRECKER D ,  BROTHERTON T

IPC: B01J19/12 ,  C08F291/18 ,  B01J1/10 ,  B01J1/12

CPC classification number: B01J19/123 ,  C08F291/18 ,  C08F232/08

Abstract: DINORBORNENE COMPOUNDS, MANY OF THEM NOVEL, HAVE BEEN FOUND TO FORM POLYMERS HAVING A LADDER STRUCTURE. THE DINORBORNENE COMPOUNDS AND DINORBORNENE POLYMERS WITH OTHER POLYMERS SUCH AS THE POLYOLEFINS, VINYL POLYMERS, ACRYLIC POLYMERS, POLYESTERS PPOLYAMIDES POLYEHERS, POLYUREAS, POLYURETHANES, NATURAL POLYMERS, ETC., ARE READILY CROSS-LINKED BY IRRADIATION.

公开(公告)号：US3759807A

公开(公告)日：1973-09-18

申请号：US3759807D

申请日：1972-01-19

Applicant: UNION CARBIDE CORP

Inventor： OSBORN C ,  TRECKER D

IPC: C08F2/46 ,  C08F20/62 ,  G03F7/031 ,  C08D1/00 ,  C08F1/16

CPC classification number: G03F7/031 ,  C08F2/46 ,  C08F20/62

Abstract: VARIOUS COMBINATIONS OF CERTAIN ORGANIC CARBONYL PHOTOSENSITIZER COMPOUNDS AND CERTAIN ORGANIC AMINE ACTIVATORS EXERT AN UNEXPECTED BENEFICIAL EFFECT ON THE PHOTOPOLYMERIZATION OF CERTAIN POLYMERIZABLE MONOMERS OR OLIGOMERS AND COATIN COMPOSITIONS CONTAINING THE SAME. THE SUITABLE CARBONYL COMPOUNDS CONTAIN A KETONIC OXYGEN, FOR EXAMPLE ONE CAN USE ACETOPHENONE OR XANTHONE, AND THE AMINES CAN BE PRIMARY, SECONDARY OR TERTIARY AMINES, FOR EXAMPLE, ONE CAN USE BUTYLDIETHANOLAMINE, TRIETHANOLAMINE, DI-N-BUTYLAMINE OR MORPHOLINE.

公开(公告)号：US3708495A

公开(公告)日：1973-01-02

申请号：US3708495D

申请日：1970-04-09

Applicant: UNION CARBIDE CORP

Inventor： BORDEN G ,  TRECKER D

IPC: C07D233/84 ,  C07D49/30

CPC classification number: C07D233/84

Abstract: COMPOUNDS REPRESENTED BY THE FORMULA:

1-(R-CH2-),3-(HO-CH2-),4,5-DI(HO-)-IMIDAZOLIDIN-2-ONE

WHEREIN R IS CYCLO-ALKENYL OR BICYCLO-ALKENYL CONTAINING 5 TO 8 CARBON ATOMS. THE COMPOUNDS HAVE UTILITY AS DURABLE PRESS ADDITIVIES FOR TEXTILE FABRICS.

公开(公告)号：US3836509A

公开(公告)日：1974-09-17

申请号：US25545872

申请日：1972-05-22

Applicant: UNION CARBIDE CORP

Inventor： COLOMB H ,  TRECKER D

IPC: C08B15/06 ,  C08F283/01 ,  C08G18/62 ,  C08G18/64 ,  C08G18/67 ,  C08G18/81 ,  C08G63/553 ,  C08G69/02 ,  C08G69/26 ,  C08G69/48 ,  C08G85/00 ,  C08J3/28 ,  C09D201/02 ,  C08G22/04

CPC classification number: C09D201/02 ,  C08B15/06 ,  C08F283/01 ,  C08G18/6212 ,  C08G18/6484 ,  C08G18/676 ,  C08G18/81 ,  C08G63/553 ,  C08G69/02 ,  C08G69/26 ,  C08G69/48 ,  C08G85/002 ,  C08J3/28 ,  Y10S525/93 ,  C08F2/46

Abstract: RADIATION CURABLE POLYMERS HAVING THE VINYL
-(5-NORBORNENE-2-YLMETHYL) CARBAMATE GROUP POLYMERIZED THEREIN ARE USEFUL FOR THE PRODUCTION OF CROSSLINKED COATINGS, FILMS, 2WIRE INSULATION AND FABRIC TREATMENT.

公开(公告)号：US3821131A

公开(公告)日：1974-06-28

申请号：US30990672

申请日：1972-11-27

Applicant: UNION CARBIDE CORP

Inventor： PRIEST D ,  SANDNER M ,  TRECKER D

IPC: C08G18/00 ,  C08G18/18 ,  C08G22/38 ,  C08G22/34

CPC classification number: C08G18/1841

Abstract: Provided as catalysts for the formation of cellular urethane polymers ranging from flexible to rigid foams, are beta-amino carbonyl compounds wherein carbonyl is present as an amido or carboxylic acid ester group and the beta-amino group is present as dialkylamino or an N-morpholino or N,N''-piperazino heterocyclic nucleus. Effective in the catalysis of the waterisocyanate reaction, these beta-amino amides and beta-amino esters are used with particular advantage in the manufacture of water-blown flexible foams, both molded and free-rise, including high-resilience and flame-retarded foam. The beta-amino carbonyl catalysts allow for the formation of foam products essentially free of the odor associated with amines such as Nethylmorpholine. In view of this highly desirable characteristic and their other beneficial properties, the catalysts of the invention are advantageously employed as direct replacements for N-ethylmorpholine in high-resilience and other foam formulations.

公开(公告)号：US3784492A

公开(公告)日：1974-01-08

申请号：US3784492D

申请日：1972-05-22

Applicant: UNION CARBIDE CORP

Inventor： COLOMB H ,  TRECKER D

IPC: C08B15/06 ,  C08F283/01 ,  C08G18/62 ,  C08G18/64 ,  C08G18/67 ,  C08G18/81 ,  C08G63/553 ,  C08G69/02 ,  C08G69/26 ,  C08G69/48 ,  C08G85/00 ,  C08J3/28 ,  C09D201/02 ,  C08G22/00

CPC classification number: C09D201/02 ,  C08B15/06 ,  C08F283/01 ,  C08G18/6212 ,  C08G18/6484 ,  C08G18/676 ,  C08G18/81 ,  C08G63/553 ,  C08G69/02 ,  C08G69/26 ,  C08G69/48 ,  C08G85/002 ,  C08J3/28 ,  Y10S521/915 ,  C08F2/46

Abstract: THE N-(5-NORBORNEN-2-YLMETHYL)CARBAMATE OF CELLULOSE ACETATE.

公开(公告)号：US3715342A

公开(公告)日：1973-02-06

申请号：US3715342D

申请日：1970-09-15

Applicant: UNION CARBIDE CORP

Inventor： COLOMB H ,  TRECKER D

IPC: C08G18/64 ,  C08G18/67 ,  C08G18/68 ,  C08G18/81 ,  C08G63/06 ,  C08G63/553 ,  C08G65/06 ,  C08G65/08 ,  C08G65/16 ,  C08G69/02 ,  C08F15/40

CPC classification number: C08G18/68 ,  C08G18/6484 ,  C08G18/6795 ,  C08G18/8125 ,  C08G63/06 ,  C08G63/553 ,  C08G65/06 ,  C08G65/08 ,  C08G65/16 ,  C08G69/02

Abstract: Polymers containing a norbornenyl group are readily crosslinked by irradiation to produce insoluble products. The crosslinked products are useful as coatings on wood, metal, etc., as selfsupporting films, wire insulation, for the treatment of fabrics to render them more durable and crease resistant, as well as in the many known areas in which synthetic polymers are employed such as the production of molded and extruded shaped articles.

Abstract translation: 含有降冰片烯基的聚合物通过照射容易交联以产生不溶性产物。 交联产物可用作木材，金属等上的涂层，作为自支撑膜，电线绝缘，用于处理织物以使其更耐用和抗折皱，以及许多已知的合成聚合物领域 被使用，例如生产模塑和挤出成型制品。