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    Antimony catalyst compositions
    161.
    发明授权
    Antimony catalyst compositions 有权
    锑催化剂组合物

    公开(公告)号：US06455459B1

    公开(公告)日：2002-09-24

    申请号：US09442565

    申请日：1999-11-18

    Applicant: Thomas Craig Bedard ,  Brian Terry Keen ,  Bradley Allen Sleadd

    Inventor： Thomas Craig Bedard ,  Brian Terry Keen ,  Bradley Allen Sleadd

    IPC: B01J3100

    CPC classification number: C08G65/266 ,  B01J31/0234 ,  B01J2231/48 ,  C07C41/03 ,  C07C43/13 ,  C07C43/11

    Abstract: Novel active catalyst compositions comprising a compound or mixture of compounds represented by the formula SbFXmY4−m a complex of such a compound or mixture of such compounds being represented by the formula R·SbFXmY4−m or a combination of such compounds and complexes where in each formula, X is an anionic moiety, Y is an anion or anions resulting from the deprotonation of an active hydrogen-containing compound(s), m is 0 to 3 and R is one or more active hydrogen containing compound acting as molecules of solvation. The catalyst compositions are useful to promote alkoxylation reactions.

    Abstract translation: 新型活性催化剂组合物，其包含化合物或化合物的混合物，所述化合物或这些化合物的混合物的化合物或其混合物由下式表示，或该化合物和络合物的组合，其中在每个式中，X为阴离子部分，Y为 由含活性氢的化合物去质子化产生的阴离子或阴离子，m为0-3，R为作为溶剂化分子的一种或多种含活性氢的化合物。 催化剂组合物可用于促进烷氧基化反应。

    Pre-polymerized catalyst components for the polymerization of olefins
    162.
    发明授权
    Pre-polymerized catalyst components for the polymerization of olefins 失效
    用于烯烃聚合的预聚合催化剂组分

    公开(公告)号：US06451726B1

    公开(公告)日：2002-09-17

    申请号：US09509657

    申请日：2000-03-30

    Applicant: Licio Zambon ,  Mario Sacchetti ,  Gianni Vitale

    Inventor： Licio Zambon ,  Mario Sacchetti ,  Gianni Vitale

    IPC: B01J3100

    CPC classification number: C08F10/00 ,  Y10S526/904 ,  Y10S526/908 ,  Y10S526/943 ,  C08F4/6492 ,  C08F4/651

    Abstract: Components of catalysts for the polymerization of olefins are obtained by contacting a Ti compound of formula Ti(OR)n−yXy, where n is the valence of titanium and y is a number between 1 and n, with a pre-polymer having a porosity higher than 0.3 cc/g and containing from 0.5 to 100 g of polymer per g of solid catalyst component, the pre-polymer being obtained by (co)polymerizing an olefin or a diolefin in the presence of a catalyst comprising a Ti, V, Zr of Hf compound supported on an Mg dihalide having a mean crystallite dimension lower than 30 nm.

    Abstract translation: 用于烯烃聚合的催化剂的组分是通过使式Ti（OR）n-yXy的Ti化合物与其具有孔隙率的预聚物接触而获得的，其中n是钛的化合价，y是1和n之间的数， 高于0.3cc / g并且每克固体催化剂组分含有0.5至100g聚合物，该预聚物通过在包含Ti，V， 负载在平均微晶尺寸小于30nm的二氢卤化镁上的Hf化合物的Zr。

    Unsaturated nitrogenous compounds as electron donors for use with ziegler-natta catalysts
    163.
    发明授权
    Unsaturated nitrogenous compounds as electron donors for use with ziegler-natta catalysts 失效
    不饱和含氮化合物作为电子给体用于齐格勒 - 纳塔催化剂

    公开(公告)号：US06436864B1

    公开(公告)日：2002-08-20

    申请号：US09414131

    申请日：1999-10-06

    Applicant: Christopher D. Tagge

    Inventor： Christopher D. Tagge

    IPC: B01J3100

    CPC classification number: C08F10/00 ,  C08F4/6495 ,  C08F4/651

    Abstract: Unsaturated nitrogenous compounds are used as electron donors in conjunction with catalytic polymerization of addition polymerizable monomers such as olefins, using supported Ziegler-Natta catalysts. The electron donors may be used in the preparation of catalyst systems, thus serving as “internal” electron donors, or they may be added during or just prior to polymerization, as an “external” electron donor.

    Abstract translation: 使用负载的齐格勒 - 纳塔催化剂，将不饱和含氮化合物用作电子给体结合可加聚的单体如烯烃的催化聚合。 电子给体可用于制备催化剂体系，因此用作“内部”电子给体，或者它们可以在聚合过程中或之前加入作为“外部”电子给体。

    Mixed metal catalysts
    164.
    发明授权
    Mixed metal catalysts 有权

    公开(公告)号：US06417129B1

    公开(公告)日：2002-07-09

    申请号：US09829188

    申请日：2001-04-09

    Applicant: Donna Marie Brown

    Inventor： Donna Marie Brown

    IPC: B01J3100

    Abstract: A catalyst composition for polymerization of olefins comprising: (ia) a catalyst precursor corresponding to the formula: MgdTi(ORe)eXf(ED)g, wherein Re is an aliphatic or aromatic hydrocarbon radical having 1 to 14 carbon atoms or COR′ wherein R′ is an aliphatic or aromatic hydrocarbon radical having 1 to 14 carbons atoms; X is halide; ED is an organic Lewis base electron donor; d is 0.5 to 56; e is 0, 1, or 2; f is 2 to 116; and g is 1.5d+2 (ib) an aluminum trialkyl or aluminum alkyl halide cocatalyst compound; and (ii) a lanthanide compound represented by the following formula: CpaLnRbbLc wherein Cp is a cyclopentadienyl or substituted cyclopentadienyl ligand; Ln is a lanthanide metal; Rb is a hydride, alkyl, silyl, halide, or aryl group; L is an electron donor; a+b is the valence of the lanthanide metal; and c is a number from 1 to 8.

    Catalyst comprising nitrogen-containing heterocyclic compound, and process for producing organic compound using the catalyst
    167.
    发明授权
    Catalyst comprising nitrogen-containing heterocyclic compound, and process for producing organic compound using the catalyst 失效
    包含含氮杂环化合物的催化剂，以及使用该催化剂制备有机化合物的方法

    公开(公告)号：US06403521B1

    公开(公告)日：2002-06-11

    申请号：US09653953

    申请日：2000-09-01

    Applicant: Yasutaka Ishii ,  Tatsuya Nakano

    Inventor： Yasutaka Ishii ,  Tatsuya Nakano

    IPC: B01J3100

    CPC classification number: C07D253/08 ,  B01J31/006 ,  B01J31/0247 ,  B01J2231/70 ,  B01J2231/72 ,  C07D249/18

    Abstract: A catalyst is for use in a reaction using an oxygen-atom-containing reactant and includes a nitrogen-containing heterocyclic compound of the following formula (1): wherein each of R1 and R2 is, identical to or different from each other, a hydrogen atom, a halogen atom, an alkyl group, a haloalkyl group, an aryl group, a cycloalkyl group, a hydroxyl group, an alkoxy group, a carboxyl group, an alkoxycarbonyl group, or an acyl group, and R1 and R2 may be combined to form a double bond or to form an aromatic or non-aromatic ring with the adjacent two carbon atoms, where one or two of heterocyclic ring containing three nitrogen atoms indicated in the formula may be further formed on the R1 or R2, or on the double bond or aromatic or non-aromatic ring formed by R1 and R2; X is an oxygen atom or a hydroxyl group; and Y is a single bond, a methylene group, or a carbonyl group. This catalyst can introduce an oxygen-atom-containing group into an organic substrate under mild conditions.

    Abstract translation: 催化剂用于使用含氧原子反应物的反应中，并且包括下式（1）的含氮杂环化合物：其中R 1和R 2各自彼此相同或不同，为氢 原子，卤素原子，烷基，卤代烷基，芳基，环烷基，羟基，烷氧基，羧基，烷氧基羰基或酰基，R1和R2可以组合 形成双键或与相邻的两个碳原子形成芳族或非芳香族环，其中可以在R1或R2上进一步形成式中所示的含有三个氮原子的一个或两个杂环，或在 由R1和R2形成的双键或芳香或非芳香环; X是氧原子或羟基; Y是单键，亚甲基或羰基。 该催化剂可以在温和条件下将含氧原子的基团引入有机底物。

    Metallocene compositions
    168.
    发明授权
    Metallocene compositions 有权

    公开(公告)号：US06399723B1

    公开(公告)日：2002-06-04

    申请号：US09619752

    申请日：2000-07-19

    Applicant: Terry John Burkhardt ,  William T. Haygood, Jr. ,  Robert Tan Li ,  James Charles Vizzini ,  Matthew Cornyn Kuchta ,  Udo M. Stehling ,  James R. Hart

    Inventor： Terry John Burkhardt ,  William T. Haygood, Jr. ,  Robert Tan Li ,  James Charles Vizzini ,  Matthew Cornyn Kuchta ,  Udo M. Stehling ,  James R. Hart

    IPC: B01J3100

    CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/15 ,  C08F2500/21

    Abstract: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization. The metallocene compositions may be represented by the formula: wherein M1 is selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten; R1 and R2 are identical or different, and are one of a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a C6-C10 aryl group, a C6-C10 aryloxy group, a C2-C40 alkenyl group, a C7-C40 arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, an OH group or a halogen atom, or a conjugated diene which is optionally substituted with one or more hydrocarbyl, tri(hydrocarbyl)silyl groups or tri(hydrocarbyl)silylhydrocarbyl groups, said diene having up to 30 atoms not counting hydrogen; R3 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C10 alkyl group which may be halogenated, a C6-C10 aryl group which may be halogenated, a C2-C10 alkenyl group, a C7-C40-arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, a —NR′2, —SR′, —OR′, —OSiR′3 or —PR′2 radical, wherein R′ is one of a halogen atom, a C1-C10 alkyl group, or a C6-C10 aryl group; R4 to R7 are identical or different and are hydrogen, as defined for R3 or two or more adjacent radicals R5 to R7 together with the atoms connecting them form one or more rings;  —B(R14)—, −Al(R14)—, —Ge—, —Sn—, —O—, —S—, —SO—, —SO2—, —N(R14)—, —CO—, —P(R14)—, or —P(O)(R14)—, or an amidoborane radical; wherein: R14, R15 and R16 are identical or different and are a hydrogen atom, a halogen atom, a C1-C20 alkyl group, a C1-C20 fluoroalkyl or silaalkyl group, a C6-C30 aryl group, a C6-C30 fluoroaryl group, a C1-C20 alkoxy group, a C2-C20 alkenyl group, a C7-C40 arylalkyl group, a C8-C40 arylalkenyl group, a C7-C40 alkylaryl group, or R14 and R15, together with the atoms binding them, form a cyclic ring; or, R13 is represented by the formula:  wherein R17 to R24 are as defined for R1 and R2, or two or more adjacent radicals R17 to R24, including R20 and R21, together with the atoms connecting them form one or more rings; M2 is one or more carbons, silicon, germanium or tin; R8, R10 and R12 are identical or different and have the meanings stated for R4 to R7; R9 and R11 are identical or different and are a Group 14 radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, trialkyl silyl groups, or other groups of similar size.

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