Process of dyeing human hair based on pyrazolone compounds
    11.
    发明授权
    Process of dyeing human hair based on pyrazolone compounds 失效
    基于吡唑啉酮化合物染色人体毛发的方法

    公开(公告)号:US3820948A

    公开(公告)日:1974-06-28

    申请号:US16785571

    申请日:1971-07-30

    发明人: BERTH P

    IPC分类号: A61K8/49 A61Q5/10 A61K7/12

    CPC分类号: A61K8/494 A61Q5/10

    摘要: Process for the dyeing of human hair utilizing an aqueous solution containing from 0.1 to 5 percent by weight of dyes for application to hair, including living human hair, which contain as active components, a 3-substituted pyrazolone and an aromatic bi- or polyfunctional amine having at least one primary amino group and another functional group in para-position, or else a 4aminopyrazolone. These dyes are applied in aqueous solution or preferably in the form of an aqueous cream or emulsion and may contain thickeners, grooming agents, perfumes. They may be in the form of a shampoo. Application to the hair is carried out at temperatures of 15* to 40* C., preferably at room temperature, and the time required is approximately 20 to 25 minutes. The dyes, in contrast to conventional ones, can be removed from the hair with reducing agents.

    Dyeing human hair with oxidation dyes comprising heterocyclic amino compounds
    12.
    发明授权
    Dyeing human hair with oxidation dyes comprising heterocyclic amino compounds 失效
    用包含杂环氨基化合物的氧化染料染色人体毛发

    公开(公告)号:US3630655A

    公开(公告)日:1971-12-28

    申请号:US3630655D

    申请日:1968-10-22

    摘要: The novel means for dyeing human hair according to the invention are based on oxidation dyes and comprise heterocyclic amino compounds and suitable coupling components. For example, 2 parts of 6-aminotetrahydroquinoline hydrochloride, 1 part of Alpha naphthol, 1 part of hydrogen peroxide are mixed with 96 parts of water and adjusted to a pH of 9.5. By treating gray human hair with the resulting solution a dark blue coloration is obtained. The hair dyes according to the invention have, in addition to other favorable characteristics, the advantage of being easily removable from the hair, e.g., by reducing agents.

    Dyeing human hair with n-arylsulfon-amides and aromatic amines
    17.
    发明授权
    Dyeing human hair with n-arylsulfon-amides and aromatic amines 失效
    用N-ARYLSULFON-AMIDES和AROMATIC AMINES染色人体毛发

    公开(公告)号:US3695823A

    公开(公告)日:1972-10-03

    申请号:US3695823D

    申请日:1970-02-11

    IPC分类号: A61K7/12

    摘要: IN AN AQUEOUS COMPOSITION FOR DYEING HUMAN HAIR COMPRISING AN OXIDATION DYESTUFFS COMBINATION OF A DEVELOPER COMPONENT AND A COUPLING COMPONENT AND CUSTOMARY DYESTUFF ADJUVANTS, THE IMPROVEMENT WHICH COMPRISES UTILIZING AS SAID OXIDATION DYESTUFF COMBINATION, FROM 0.3% TO 5% BY WEIGHT OF AN OXIDATION DYESTUFF COMBINATION OF (A) A DEVELOPER COMPONENT COMPOUND HAVING THE FORMULA

    2-(R-O2S-NH-),4-(R1-N(-R2)-),R3-ANILINE

    WHEREIN R IS A MEMBER SELECTED FROM THE GROUP CONSISTING OF A HYDROCARBON HAVING FROM 1 TO 10 CARBON ATOMS AND AN OXYGENATED HYDROCARBON HAVING FROM 7 TO 10 CARBON ATOMS, R1 AND R2 ARE ALKYL HAVING FROM 1 TO 4 CARBON ATOMS AND R3 IS A MEMBER SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, ALKYL HAVING 1 TO 4 CARBON ATOMS AND ALKOXY HAVING FROM 1 TO 4 CARBON ATOMS, AND (B) A COUPLING COMPONENT COMPOUND, KNOW FOR HAIR DYES, HAVING THE FORMULA

    X-AR-Y

    WHEREIN AR REPRESENTS AN AROMATIC NUCLEUS, X REPRESENTS A MEMBER SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, AMINO, KIALKYLAMINO HAVING FROM 1 TO 4 CARBON ATOMS IN THE ALKYLS AND HYDROXYL, AND Y REPRESENTS A MEMBER SELECTED FROM THE GROUP CONSISTING OF AMINO, DIALKYLAMINO HAVING FROM 1 TO 4 CARON ATOMS IN THE ALKYLS AND HYDROXYL, AS WELL AS THE METHOD OF DYEING HUMAN HAIR UTILIZING SAID OXIDATION DYESTUFF COMBINATION OF A DEVELOPER COMPONENT AND A COUPLING COMPONENT.

    Methods and compositions containing 4-aminopyrazolones for the dyeing of human hair
    18.
    发明授权
    Methods and compositions containing 4-aminopyrazolones for the dyeing of human hair 失效
    含有4-氨基吡唑酮用于人发染色的方法和组合物

    公开(公告)号:US3617167A

    公开(公告)日:1971-11-02

    申请号:US3617167D

    申请日:1966-07-29

    CPC分类号: A61Q5/10 A61K8/494 C07D231/48

    摘要: WHEREIN R1 is a member selected from the group consisting of hydrogen, -CONH2, -COOH, -COOR'', alkyl having 1 to 10 carbon atoms, phenyl and nicotinoyl; R'' represents an alkyl having 1 to 4 carbon atoms; and R2 is a member selected from the group consisting of hydrogen, alkyl having 1 to 10 carbon atoms, phenyl and p-sulfonamidophenyl; and (b) a coupling component, said developer component compound being present in substantially equimolar to a slight excess with respect to said coupling component compound.

    In the process of dyeing the living human hair which comprises treating the hair at a temperature of from 15* C. to 40* C. with an aqueous composition for dyeing human hair comprising an oxidation dyestuff and customary dyestuff adjuvants in the presence of an oxidizing agent, and thereafter rinsing the hair, the improvement which comprises utilizing as said oxidation dyestuff, from 0.1 percent to 5 percent by weight of an oxidation dyestuff combination of (a) a developer component compound having the formula

    摘要翻译: 1,146,061。 染发。 THERACHEMIE CHEMISCH THERAPEUTISCHE G.m.b.H. 1966年8月4日[1965年8月5日; 1966年5月18日],第34906/66号。 标题D1B。 基于氧化染料的新型染发剂包括以下通式的4-氨基吡唑酮:其中R 1和R 2表示氢原子或含有不超过10个碳原子的有机残基和已知的用于染发的偶联组分。 吡唑啉酮化合物可以以盐的形式使用,特别是盐酸盐,偶联组分包括胺,二胺,酚,萘酚,多酚和氨基苯酚。 在上述式中,R 1和R 2优选为烷基,芳基或杂环基。

    Dyeing human hair with diazonium salts
    19.
    发明授权
    Dyeing human hair with diazonium salts 失效
    用DIAZONIUM SALTS染色人体毛发

    公开(公告)号:US3582253A

    公开(公告)日:1971-06-01

    申请号:US3582253D

    申请日:1968-02-20

    IPC分类号: D06P3/30 A61K7/12

    CPC分类号: D06P3/3075

    摘要: AGENTS FOR THE DYEING OF HAIR, AND PARTICULARLY OF LIVING HUMAN HAIR, BASED ON AZO DYES. THE DYES CONSIST OF A DIAZO- AND A COUPLING COMPONENT, WHICH ARE CAUSED TO REACT WITH EACH OTHER WHILE ON THE HAIR. THE DIAZO COMPONENT CONSISTS OF STABLE DIAZONIUM SALTS. BOTH COMPONENTS ARE APPLIED IN THE FORM OF AQUEOUS SOLUTIONS. APPLICATION TO THE HAIR CAN BE CARRIED OUT WITHIN 5 TO 30 MINUTES AND AT TEMPERATURES OF SUBSTANTIALLY 15 TO 35* C., I.E., SUBSTANTIALLY AT ROOM TEMPERATURE.

    Hair dye comprising substituted anthraquinones in shampoo base
    20.
    发明授权
    Hair dye comprising substituted anthraquinones in shampoo base 失效
    包含洗发水基质中的取代的蒽醌的染发剂

    公开(公告)号:US3192117A

    公开(公告)日:1965-06-29

    申请号:US17437762

    申请日:1962-02-20

    摘要: Anthraquinone dyes for hair are made by reacting halogenated, nitrated or sulphonated anthraquinones which may also contain one or two primary amino groups with mono- or polyglycols or their monoalkyl ehters or with thioglycols, for example by reacting dichlorinated 1 : 4 - diamino - anthraquinone or 1 : 4-diamino-5 - nitro - anthraquinone with ethyl diethylene glycol or monochlorinated 1 : 4-diamino - anthraquinone with sodium diethylene glycol, by reacting 1 : 4-diamino-anthraquinone with p-toluenesulphonic esters of monoethyldiethylene glycol or by reacting 1 : 4-diamino-2-bromoanthraquinone or 1 : 4 - diamino - 5 - nitroanthraquinone with NH(C2H4OC2H4OC2H5)2. Dyes if the following formulae are specified: ALSO:Hair such as human hair or fur is dyed by applying a dyeing agent containing an anthraquinone dye which is free from acid groups and has attached to the anthraquinone nucleus no hydroxyl groups but at least one aliphatic residue attached via a hetero-atom, the said aliphatic residue being (a) a hydroxy-alkyl or alkyl ether residue, the alkylene chain of which is interrupted at least once by a hetero-atom or in which ether residue the alkylene chain is attached to a cyclic ether group of (b) an alkyl residue on which the alkylene chain is interrupted by an acid amide group. Representative of dyes specified are those of the formulae:- The dyeing agent may also contain wetting or washing agents such as alkylbenzene-sulphonates, fatty alcohol sulphates, alkyl sulphonates, fatty acid ethanolamides and addition products of ethylene oxide with fatty acids and fatty alcohols; permanent waving agents such as thioglycollic acid, thiolactic acid, mercaptopropane- and mercaptobutanesulphonic acids; thickeners such as methyl cellulose, starch, fatty alcohols, petroleum jelly, paraffin oil and fatty acids; and other dyes. The dyeing agent may be in the form of a cream shampoo. In examples the dyes are incorporated into creams containing cetyl-stearyl alcohol, coconut alcohol, fatty alcohol sulphate and ammonia, which may also contain sodium 2 : 4-dinitronaphthol sulphonate (3), the sodium salt of the mono-(4-amino-3-nitro-anilide) of maleic acid (5), 4-amino-3-nitro-phenyl urea (8) or ammonium thioglycollate (13) or in which the fatty alcohol sulphate is replaced by an ethylene oxide/fatty alcohol addition product (10). In a further example the cream contains paraffin oil, fatty alcohol sulphate and ammonia. German Specification 1,087,565 is referred to.