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    Method for preparation of alkenylsilanes
    11.
    发明授权
    Method for preparation of alkenylsilanes 失效
    烯基硅烷的制备方法

    公开(公告)号：US5756796A

    公开(公告)日：1998-05-26

    申请号：US861311

    申请日：1997-05-19

    Applicant: Sean Patrick Davern ,  Binh Thanh Nguyen

    Inventor： Sean Patrick Davern ,  Binh Thanh Nguyen

    IPC: C07F7/08 ,  C07F9/08

    CPC classification number: C07F7/0827

    Abstract: A method for preparation of alkenylsilanes comprising contacting magnesium metal with a mixture comprising diethylene glycol dibutyl ether, an alkenyl halide, and a halosilane at a temperature within a range of about 5.degree. C. to 200.degree. C. The method provides a high yield of alkenylsilane product that is easily recoverable and also provides for high ratios of alkenylsilane to diethylene glycol dibutyl ether.

    Abstract translation: 一种制备烯基硅烷的方法，包括使镁金属与包含二甘醇二丁基醚，链烯基卤化物和卤代硅烷的混合物在约5℃至200℃的温度范围内接触。该方法提供了高产率 烯基硅烷产物易于回收，并且还提供了高比例的烯基硅烷与二甘醇二丁醚。

    Method of Making Phenyl-Containing Chlorosilanes with Aliphatic or Cycloparaffinic Hydrocarbon Solvents
    15.
    发明申请
    Method of Making Phenyl-Containing Chlorosilanes with Aliphatic or Cycloparaffinic Hydrocarbon Solvents 审中-公开
    制备含有苯基的氯硅烷与脂族或环烷烃溶剂的方法

    公开(公告)号：US20080139834A1

    公开(公告)日：2008-06-12

    申请号：US11883151

    申请日：2006-01-25

    Applicant: Dana C. Bauer ,  Curtis John Bedbury ,  Binh Thanh Nguyen

    Inventor： Dana C. Bauer ,  Curtis John Bedbury ,  Binh Thanh Nguyen

    IPC: C07F7/16

    CPC classification number: C07F7/122

    Abstract: Phenylmethyldichlorosilanes and diphenylmethylchlorosilanes are prepared by a Grignard process involving the step of contacting a phenyl Grignard reagent, an ether solvent, a trichlorosilane, and an aliphatic or cycloparaffinic hydrocarbon coupling solvent; in a mole ratio of the ether solvent to the phenyl Grignard reagent is 2 to 5, the mole ratio of the trichlorosilane to the phenyl Grignard reagent is 0.1 to 10, and the mole ratio of the aliphatic or cycloparaffinic hydrocarbon coupling solvent to the phenyl Grignard reagent is 3 to 7. Preferred reactants include phenylmagnesium chloride as the phenyl Grignard reagent; diethyl ether as solvent; n-heptane as the aliphatic hydrocarbon coupling solvent, or cyclohexane as the cycloparaffinic hydrocarbon coupling solvent; and methyltrichlorosilane.

    Abstract translation: 苯甲基二氯硅烷和二苯基甲基氯硅烷通过格氏方法制备，该方法包括使格利雅试剂，醚溶剂，三氯硅烷和脂族或环烷烃偶联溶剂接触的步骤; 醚溶剂与苯基格氏试剂的摩尔比为2至5，三氯硅烷与苯基格氏试剂的摩尔比为0.1至10，脂族或环烷烃耦合溶剂与苯基格利雅的摩尔比 试剂为3至7.优选的反应物包括苯基氯化镁作为苯基格氏试剂; 乙醚为溶剂; 正庚烷作为脂族烃偶联溶剂，或环己烷作为环烷烃耦合溶剂; 和甲基三氯硅烷。

    Grignard processes with increased content of diphenylchlorosilanes
    16.
    发明授权
    Grignard processes with increased content of diphenylchlorosilanes 失效
    格利雅法处理二苯基氯硅烷含量增加

    公开(公告)号：US07351847B2

    公开(公告)日：2008-04-01

    申请号：US10585155

    申请日：2004-12-17

    Applicant: Binh Thanh Nguyen

    Inventor： Binh Thanh Nguyen

    IPC: C07F7/04 ,  C07F7/08

    CPC classification number: C07B49/00 ,  C07F7/122

    Abstract: Three improved Grignard processes are used for preparing phenyl-containing chlorosilane products wherein the yield of diphenylchlorosilanes as a product is maximized, while the yield of phenylchlorosilanes as a product is minimized. In one embodiment, the process involves contacting a phenyl Grignard reagent, an ether solvent, an aromatic halogenated coupling solvent and a trichlorosilane. In another embodiment, the process involves contacting a phenyl Grignard reagent, an ether solvent, an aromatic halogenated coupling solvent, a trichlorosilane, and a phenylchlorosilane. In yet another embodiment, the process involves contacting a phenyl Grignard reagent, an ether solvent, an aromatic halogenated coupling solvent, and a phenylchlorosilane. In each embodiment, the reactants are present in particular mole ratios of the components.

    Abstract translation: 三种改进的Grignard方法用于制备苯基氯硅烷产物，其中作为产物的二苯基氯硅烷的产率最大化，而作为产物的苯基氯硅烷的产率最小化。 在一个实施方案中，该方法包括使苯基格氏试剂，醚溶剂，芳族卤化偶联溶剂和三氯硅烷接触。 在另一个实施方案中，该方法包括使苯基格氏试剂，醚溶剂，芳族卤化偶合溶剂，三氯硅烷和苯基氯硅烷接触。 在另一个实施方案中，该方法包括使苯基格氏试剂，醚溶剂，芳族卤代偶联溶剂和苯基氯硅烷接触。 在每个实施方案中，反应物以组分的特定摩尔比存在。

    Method for preparing organofunctional silanes
    17.
    发明授权
    Method for preparing organofunctional silanes 失效
    有机官能硅烷的制备方法

    公开(公告)号：US06878839B2

    公开(公告)日：2005-04-12

    申请号：US10269241

    申请日：2002-10-11

    Applicant: Binh Thanh Nguyen ,  John Patrick Cannady

    Inventor： Binh Thanh Nguyen ,  John Patrick Cannady

    IPC: C07F7/18

    CPC classification number: C07F7/188

    Abstract: Alkenylalkoxysilanes such as allyltrimethoxysilane can be made by reacting the corresponding monoalkenyldichlorosilane, i.e., allyldichlorosilane, with a monohydroxy alcohols, i.e., methyl alcohol. No catalyst is required and the reactions can be carried out at room temperature.

    Abstract translation: 烯丙基烷氧基硅烷如烯丙基三甲氧基硅烷可以通过使相应的单烯基二氯硅烷，即烯丙基二氯硅烷与单羟基醇，即甲醇反应来制备。 不需要催化剂，反应可以在室温下进行。

    Polymerization of vinyl monomers from silanes and siloxanes
    18.
    发明授权
    Polymerization of vinyl monomers from silanes and siloxanes 失效
    乙烯基单体由硅烷和硅氧烷聚合

    公开(公告)号：US5789503A

    公开(公告)日：1998-08-04

    申请号：US888595

    申请日：1997-07-07

    Applicant: Daniel Graiver ,  Aaron Quoc Khieu ,  Binh Thanh Nguyen

    Inventor： Daniel Graiver ,  Aaron Quoc Khieu ,  Binh Thanh Nguyen

    IPC: C07F7/08 ,  C07F7/12 ,  C07F7/18 ,  C08F4/16 ,  C08F4/42 ,  C08F283/12 ,  C08G77/38 ,  C08F2/00

    CPC classification number: C08G77/38 ,  C07F7/12 ,  C07F7/1836 ,  C08F4/42

    Abstract: A method in which radical polymerization of a vinyl monomer is initiated by an ozonide group attached to a silane or a siloxane polymer. The method is particularly useful for preparing organic polymers having a silicone chain end, or for preparing wide ranges of silicone/organic polymers and copolymers with varied architecture, i.e., ABA block copolymers, comb polymers, star polymers, and hyper-branched polymers. In one embodiment, the method is carried out by simply heating a vinyl monomer in the presence of a silane containing ozonide functionality. The ozonide silane is obtained by exposing silanes or siloxanes having an alkyl group containing a double bond to ozone. Surprisingly, an ozonide attached to an organosilicon compound was found to be stable, and capable of initiating vinyl polymerization upon heating to moderate temperatures, i.e., about 70.degree. C.

    Abstract translation: 乙烯基单体的自由基聚合由与硅烷或硅氧烷聚合物连接的臭氧化物基团引发的方法。 该方法特别可用于制备具有硅酮链端的有机聚合物，或用于制备宽范围的具有不同结构的有机硅/有机聚合物和共聚物，即ABA嵌段共聚物，梳形聚合物，星形聚合物和超支化聚合物。 在一个实施方案中，该方法通过简单地在含有硅氧烷的臭氧化物官能团的存在下加热乙烯基单体进行。 通过将具有含有双键的烷基的硅烷或硅氧烷暴露于臭氧而获得臭氧化物硅烷。 令人惊奇地发现，附着于有机硅化合物的臭氧化物是稳定的，并且能够在加热到中等温度即约70℃时引发乙烯基聚合。

    Preparation of carbonyl functional polysiloxanes
    19.
    发明授权
    Preparation of carbonyl functional polysiloxanes 失效
    羰基官能聚硅氧烷的制备

    公开(公告)号：US5739246A

    公开(公告)日：1998-04-14

    申请号：US812808

    申请日：1997-03-06

    Applicant: Daniel Graiver ,  Aaron Quoc Khieu ,  Binh Thanh Nguyen

    Inventor： Daniel Graiver ,  Aaron Quoc Khieu ,  Binh Thanh Nguyen

    IPC: C07F7/08 ,  C08G77/38 ,  C08G77/20

    CPC classification number: C08G77/38 ,  C07F7/0889

    Abstract: Polysiloxanes having pendant and/or telechelic carbonyl functionality, i.e., aldehyde functionality .tbd.Si--R--CH.dbd.O or ketone functionality .tbd.Si--R--CR.dbd.O, are manufactured in high yield by ozonolysis of polydiorganosiloxanes containing alkenyl groups, followed by treatment with a reducing agent such as zinc and acetic acid. The process is relatively fast and economical using readily available starting materials such as hexenyl-functional polymers. In particular, aldehyde functionality on the polymer can be used as a polymeric crosslinking agent.

    Abstract translation: 具有侧基和/或遥爪羰基官能团的聚硅氧烷，即醛官能团3BOND Si-R-CH = O或酮官能团3BOND Si-R-CR = O以高产率通过含有烯基的聚二有机硅氧烷的臭氧分解制备，然后进行处理 与还原剂如锌和乙酸。 使用容易获得的原料如己烯基官能聚合物，该方法相对快速和经济。 特别地，聚合物上的醛官能团可用作聚合物交联剂。

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