公开(公告)号：US20110237821A1

公开(公告)日：2011-09-29

申请号：US12661720

申请日：2010-03-23

申请人： James F. Brazdil ,  Mark A. Toft ,  Michael J. Seely ,  Charles J. Besecker ,  Robert A. Gustaferro

发明人： James F. Brazdil ,  Mark A. Toft ,  Michael J. Seely ,  Charles J. Besecker ,  Robert A. Gustaferro

IPC分类号： C07C253/18 ,  B01J23/10 ,  B01J21/02 ,  B01J27/192

CPC分类号： C07C253/26 ,  B01J23/002 ,  B01J23/8871 ,  B01J23/8876 ,  B01J23/8878 ,  B01J35/002 ,  B01J37/031 ,  B01J2523/00 ,  Y02P20/52 ,  B01J2523/12 ,  B01J2523/13 ,  B01J2523/15 ,  B01J2523/22 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/14 ,  B01J2523/67 ,  C07C255/08

摘要： A catalytic composition useful for the conversion of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile, and mixtures thereof. The catalytic composition comprising a complex of metal oxides comprising bismuth, molybdenum, iron, cerium and other promoters, wherein the ratio of cerium to iron in the composition is greater than or equal to 0.8 and less than or equal to 5.

摘要翻译： 用于将选自丙烯，异丁烯或其混合物的烯烃转化成丙烯腈，甲基丙烯腈及其混合物的催化组合物。 所述催化剂组合物包含包含铋，钼，铁，铈和其它助催化剂的金属氧化物的复合物，其中所述组合物中铈与铁的比例大于或等于0.8且小于或等于5。

公开(公告)号：US20110233460A1

公开(公告)日：2011-09-29

申请号：US13065134

申请日：2011-03-15

申请人： James F. Brazdil ,  Mark A. Toft ,  Charles J. Besecker ,  Michael J. Seely

发明人： James F. Brazdil ,  Mark A. Toft ,  Charles J. Besecker ,  Michael J. Seely

IPC分类号： C09K3/00 ,  B01J23/10 ,  B01J21/08 ,  B01J23/887

CPC分类号： C07C253/26 ,  B01J23/002 ,  B01J23/883 ,  B01J35/002 ,  B01J37/031 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  Y02P20/52 ,  B01J2523/12 ,  B01J2523/13 ,  B01J2523/15 ,  B01J2523/22 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/14 ,  B01J2523/67 ,  C07C255/08

摘要： A process and novel catalyst for the production of acrylonitrile, acetonitrile and hydrogen cyanide characterized by the relative yields of acrylonitrile, acetonitrile and hydrogen cyanide produced in the process and by the catalyst, which are defined by the following: α=[(% AN+(3×% HCN)+(1.5×% ACN))+% PC]×100 wherein % AN is the Acrylonitrile Yield and % AN≧81, % HCN is the Hydrogen Cyanide Yield, % ACN is the Acetonitrile Yield, % PC is the Propylene Conversion, and α is greater than 100.

摘要翻译： 用于生产丙烯腈，乙腈和氰化氢的方法和新型催化剂，其特征在于在该方法和催化剂中产生的丙烯腈，乙腈和氰化氢的相对产率，其由下列定义：α= [（％AN +（ 3×％HCN）+（1.5×ACN））+％PC]×100其中％AN为丙烯腈收率，％AN≥81，％HCN为氰化氢产率，％ACN为乙腈产率，％PC为 丙烯转化率，α大于100。

公开(公告)号：US07125528B2

公开(公告)日：2006-10-24

申请号：US10154704

申请日：2002-05-24

申请人： Charles J. Besecker ,  Terry J. Mazanec ,  Sherman J. Xu ,  Erling Rytter

发明人： Charles J. Besecker ,  Terry J. Mazanec ,  Sherman J. Xu ,  Erling Rytter

IPC分类号： B01J8/02 ,  B01J8/04 ,  B01D53/22 ,  B01D59/12

CPC分类号： B01D69/141 ,  B01D53/228 ,  B01D71/024 ,  B01D2325/26 ,  B01J12/007 ,  B01J19/2475 ,  C01B3/386 ,  C01B13/0255 ,  C01B2203/0261 ,  C01B2203/1029 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2210/0046 ,  C01B2210/0053 ,  Y02P20/52

摘要： An apparatus for separating oxygen from an oxygen-containing gas and facilitating a chemical reaction with the separated oxygen includes a mixed conducting membrane, a porous body, and a material for catalyzing the reaction. The mixed conducting membrane has respective oxidation and reduction surfaces and is made of a non-porous, gas-impermeable, solid material capable of simultaneously conducting oxygen ions and electrons. At least the membrane and the catalyzing material are non-reactive with each other or are physically separated from each other during oxygen separation and the chemical reaction. The apparatus can be embodied by tubes, and a plurality of such tubes can form part of a reaction vessel in which various chemical reactions can occur benefiting from the apparatus design.

公开(公告)号：US4921985A

公开(公告)日：1990-05-01

申请号：US260634

申请日：1988-10-21

申请人： Charles J. Besecker ,  William A. Marritt

发明人： Charles J. Besecker ,  William A. Marritt

IPC分类号： C07F9/90

CPC分类号： C07F9/902

摘要： Disclosed is a method of making a tri- or tetrahydrocarbylammonium hexahydroxyantimonate,[R.sub.3 R'N]Sb(OH).sub.6.xH.sub.2 O formula (1)containing 3 to 30 C atoms, which process comprises the steps of (1) contacting a compound selected fromR.sub.3 N and R.sub.4 NOHwith the H.sup.+ form of a solid cation exchange resin, and allowing the amine or the tetrahydrocarbylammonium hydroxide to react with the cation exchange resin, and thereafter (2) contacting the reacted resin with an aqueous solution of KSb(OH).sub.6,wherein each R contains 1-10 C atoms and is independently selected from alkyl, aralkyl and alkylaralkyl, R' is H or R, and wherein x is an indeterminate number of moles of H.sub.2 O.

摘要翻译： 公开了一种制备含有3至30个C原子的六羟基锑酸六烷基铵六羟基锑酸盐[R3R'N] Sb（OH）6.xH2O配方（1）的方法，该方法包括以下步骤：（1）使选自 R3N和R4NOH与H +形式的固体阳离子交换树脂反应，并使胺或四氢碳鎓氢氧化铵与阳离子交换树脂反应，然后（2）使反应的树脂与KSb（OH）6的水溶液接触， 其中每个R包含1-10个C原子，并且独立地选自烷基，芳烷基和烷基烷基，R'是H或R，并且其中x是H 2 O的不确定摩尔数。

公开(公告)号：US08455388B2

公开(公告)日：2013-06-04

申请号：US12661720

申请日：2010-03-23

申请人： James F. Brazdil ,  Mark A. Toft ,  Michael J. Seely ,  Charles J. Besecker ,  Robert A. Gustaferro

发明人： James F. Brazdil ,  Mark A. Toft ,  Michael J. Seely ,  Charles J. Besecker ,  Robert A. Gustaferro

IPC分类号： C07C51/16 ,  C07C51/215 ,  B01J27/128 ,  B01J27/132 ,  B01J27/06 ,  B01J23/28 ,  B01J23/76 ,  B01J23/887

CPC分类号： C07C253/26 ,  B01J23/002 ,  B01J23/8871 ,  B01J23/8876 ,  B01J23/8878 ,  B01J35/002 ,  B01J37/031 ,  B01J2523/00 ,  Y02P20/52 ,  B01J2523/12 ,  B01J2523/13 ,  B01J2523/15 ,  B01J2523/22 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/14 ,  B01J2523/67 ,  C07C255/08

摘要： A catalytic composition useful for the conversion of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile, and mixtures thereof. The catalytic composition comprising a complex of metal oxides comprising bismuth, molybdenum, iron, cerium and other promoters, wherein the ratio of cerium to iron in the composition is greater than or equal to 0.8 and less than or equal to 5.

摘要翻译： 用于将选自丙烯，异丁烯或其混合物的烯烃转化成丙烯腈，甲基丙烯腈及其混合物的催化组合物。 所述催化剂组合物包含包含铋，钼，铁，铈和其它助催化剂的金属氧化物的复合物，其中所述组合物中铈与铁的比例大于或等于0.8且小于或等于5。

公开(公告)号：US08420566B2

公开(公告)日：2013-04-16

申请号：US13065134

申请日：2011-03-15

申请人： James F. Brazdil ,  Mark A. Toft ,  Charles J. Besecker ,  Michael J. Seely

发明人： James F. Brazdil ,  Mark A. Toft ,  Charles J. Besecker ,  Michael J. Seely

IPC分类号： B01J21/08 ,  B01J23/04 ,  B01J23/887

CPC分类号： C07C253/26 ,  B01J23/002 ,  B01J23/883 ,  B01J35/002 ,  B01J37/031 ,  B01J37/04 ,  B01J37/08 ,  B01J2523/00 ,  Y02P20/52 ,  B01J2523/12 ,  B01J2523/13 ,  B01J2523/15 ,  B01J2523/22 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/14 ,  B01J2523/67 ,  C07C255/08

摘要： A process and novel catalyst for the production of acrylonitrile, acetonitrile and hydrogen cyanide characterized by the relative yields of acrylonitrile, acetonitrile and hydrogen cyanide produced in the process and by the catalyst, which are defined by the following: α=[(% AN+(3×% HCN)+(1.5×% ACN))÷% PC]×100 wherein % AN is the Acrylonitrile Yield and % AN≧81, % HCN is the Hydrogen Cyanide Yield, % ACN is the Acetonitrile Yield, % PC is the Propylene Conversion, and α is greater than 100.

摘要翻译： 用于生产丙烯腈，乙腈和氰化氢的方法和新型催化剂，其特征在于在该方法和催化剂中产生的丙烯腈，乙腈和氰化氢的相对产率，其由下列定义：α= [（％AN +（ 3×％HCN）+（1.5×ACN））÷％PC]×100其中％AN为丙烯腈收率，％AN≥81，％HCN为氰化氢产率，％ACN为乙腈产率，％PC为 丙烯转化率，α大于100。

公开(公告)号：US08350075B2

公开(公告)日：2013-01-08

申请号：US13351292

申请日：2012-01-17

申请人： James F. Brazdil ,  Mark A. Toft ,  Michael J. Seely ,  Charles J. Besecker ,  Robert A. Gustaferro

发明人： James F. Brazdil ,  Mark A. Toft ,  Michael J. Seely ,  Charles J. Besecker ,  Robert A. Gustaferro

IPC分类号： C07C253/26

CPC分类号： B01J23/8878 ,  B01J23/002 ,  B01J23/8871 ,  B01J23/8876 ,  B01J35/002 ,  B01J37/031 ,  B01J2523/00 ,  C07C253/26 ,  Y02P20/52 ,  B01J2523/12 ,  B01J2523/13 ,  B01J2523/15 ,  B01J2523/22 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/14 ,  B01J2523/67 ,  C07C255/08

摘要： Olefins selected from the group consisting of propylene, isobutylene or mixtures thereof, are converted to acrylonitrile, methacrylonitrile, and mixtures thereof in a process comprising reacting in the vapor phase at an elevated temperature and pressure said olefin with a molecular oxygen containing gas and ammonia in the presence of a catalytic composition comprising a complex of metal oxides comprising bismuth, molybdenum, iron, cerium and other promoter elements, wherein the X-ray diffraction pattern of the catalytic composition has X-ray diffraction peaks at 2θ angle 28±0.3 degrees and 2θ angle 26.5±0.3 degrees, and wherein the ratio of the intensity of the most intense x-ray diffraction peak within 2θ angle 28±0.3 degrees to the intensity of most intense x-ray diffraction peak within 2θ angle 26.5±0.3 degrees is defined as X/Y, and wherein X/Y is greater than or equal to 0.7.

摘要翻译： 将选自丙烯，异丁烯或其混合物的烯烃转化为丙烯腈，甲基丙烯腈及其混合物，其方法包括在高温和高压下在气相中使所述烯烃与含分子氧的气体和氨反应 含有铋，钼，铁，铈等助催化剂元素的金属氧化物络合物的催化剂组合物的存在，其中催化剂组合物的X射线衍射图在2θ处具有X射线衍射峰; 角度28±0.3度和2度; 角度26.5±0.3度，并且其中最强烈的x射线衍射峰的强度在2θ范围内; 角度28±0.3度，最大强度x射线衍射峰值在2和之内; 角度26.5±0.3度被定义为X / Y，并且其中X / Y大于或等于0.7。

公开(公告)号：US08153546B2

公开(公告)日：2012-04-10

申请号：US12661705

申请日：2010-03-23

申请人： James F. Brazdil ,  Mark A. Toft ,  Michael J. Seely ,  Charles J. Besecker ,  Robert A. Gustaferro

发明人： James F. Brazdil ,  Mark A. Toft ,  Michael J. Seely ,  Charles J. Besecker ,  Robert A. Gustaferro

IPC分类号： B01J23/10 ,  B01J21/08

CPC分类号： B01J23/8878 ,  B01J23/002 ,  B01J23/8871 ,  B01J23/8876 ,  B01J35/002 ,  B01J37/031 ,  B01J2523/00 ,  C07C253/26 ,  Y02P20/52 ,  B01J2523/12 ,  B01J2523/13 ,  B01J2523/15 ,  B01J2523/22 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/14 ,  B01J2523/67 ,  C07C255/08

摘要： A catalytic composition useful for the conversion of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile, and mixtures thereof. The catalytic composition comprising a complex of metal oxides comprising bismuth, molybdenum, iron, cerium and other promoter elements, wherein the X-ray diffraction pattern of the catalytic composition has X-ray diffraction peaks at 2θ angle 28±0.3 degrees and 2θ angle 26.5±0.3 degrees, and wherein the ratio of the intensity of the most intense x-ray diffraction peak within 2θ angle 28±0.3 degrees to the intensity of most intense x-ray diffraction peak within 2θ angle 26.5±0.3 degrees is defined as X/Y, and wherein X/Y is greater than or equal to 0.7.

摘要翻译： 用于将选自丙烯，异丁烯或其混合物的烯烃转化成丙烯腈，甲基丙烯腈及其混合物的催化组合物。 所述催化剂组合物包含包含铋，钼，铁，铈和其它助催化剂元素的金属氧化物的复合物，其中所述催化剂组合物的X射线衍射图在2θ处具有X射线衍射峰; 角度28±0.3度和2度; 角度26.5±0.3度，并且其中最强烈的x射线衍射峰的强度在2θ范围内; 角度28±0.3度，最大强度x射线衍射峰值在2和之内; 角度26.5±0.3度被定义为X / Y，并且其中X / Y大于或等于0.7。

公开(公告)号：US4990638A

公开(公告)日：1991-02-05

申请号：US135206

申请日：1987-12-21

申请人： Charles J. Besecker ,  William A. Marritt

发明人： Charles J. Besecker ,  William A. Marritt

IPC分类号： C07F9/90

CPC分类号： C07F9/902

摘要： Disclosed is a method of making a tri- or tetrahydrocarbylammonium hexahydroxyantimonate,[R.sub.3 R'N]Sb(OH).sub.6 .multidot.xH.sub.2 O (1)containing 3 to 30 C atoms, which process comprises the steps of (1) contacting a compound selected fromR.sub.3 N and R.sub.4 NOHwith the H.sup.+ form of a solid cation exchange resin, and allowing the amine or the tetrahydrocarbylammonium hydroxide to react with the cation exchange resin, and thereafter (2) contacting the reacted resin with an aqueous solution of KSb(OH).sub.6,wherein each R contains 1-10 C atoms and is independently selected from alkyl, aralkyl and alkylaralkyl, R' is H or H, and wherein x is an indeterminate number of moles of H.sub.2 O.

摘要翻译： 公开了一种制备含有3至30个C原子的三羟基锑酸六烷基铵六羟基锑酸盐的方法，该方法包括以下步骤：（1）使选自R3N和R4NOH的化合物 与H +形式的固体阳离子交换树脂，并使胺或四氢碳鎓氢氧化铵与阳离子交换树脂反应，然后（2）使反应的树脂与KSb（OH）6的水溶液接触，其中每个R 含有1-10个C原子，独立地选自烷基，芳烷基和烷基烷基，R'是H或H，其中x是H 2 O的不确定摩尔数。

公开(公告)号：US4900853A

公开(公告)日：1990-02-13

申请号：US81842

申请日：1987-08-05

申请人： Charles J. Besecker ,  William A. Marritt

发明人： Charles J. Besecker ,  William A. Marritt

IPC分类号： C07F9/78 ,  C23F11/00

CPC分类号： C07F9/78 ,  C23F11/00

摘要： Tetraalkylammonium salts of 1:4 organoarsonate molybdenum polyoxoanions and resinoid products thereof. The salts have the formula[R.sub.4 N].sub.2 {[R.sup.1 As(OH)O.sub.2 ]Mo.sub.4 O.sub.13 H}where R is an alkyl group having from one to about 18 carbon atoms and R.sup.1 is an aryl group having the formula ##STR1## where G is selected from the group consisting of --NH.sub.2, --NH(CH.sub.3), --N(CH.sub.3).sub.2, --OH, --OCH.sub.3 and --H and at least one G is --NH.sub.2 to form 3-, 4-, 3,4-, 3,5- or 3,4,5-substituted aryl-arsonic acids. The resinoids comprise from about 7 to 17 parts by weight of the salt and from about 1 to 3 parts by weight of a dicarboxylic acid halide having the formula ##STR2## where R.sup.2 is selected from the group consisting of all organic radicals and X is Cl or Br. Processes for the preparation of the salts and resinoids are provided as is a method for the treatment of steel surfaces with the resinoids.

摘要翻译： 1：4有机锇酸酯钼聚氧阴离子和其树脂产物的四烷基铵盐。 这些盐具有式[R 4 N] 2 {[R 1 As（OH）O 2] Mo 4 O 13 H}，其中R是具有1至约18个碳原子的烷基，R 1是具有式“IMAGE”的芳基，其中G选自 由-NH 2，-NH（CH 3），-N（CH 3）2，-OH，-OCH 3和-H组成的基团和至少一个G是-NH 2，以形成3-，4-，3,4-，3 5-或3,4,5-取代的芳基 - 芳香酸。 树脂类包括约7至17重量份的盐和约1至3重量份具有式“IMAGE”的二羧酸卤化物，其中R 2选自全部有机基团，X为Cl 或Br。 提供了用于制备盐和树脂类的方法，如用酚类处理钢表面的方法。