Abstract:
Non-photosensitive direct thermographic materials comprise a reducing agent that is a specific ortho-amino-phenol, para-amino-phenol, or hydroquinone compound. These compounds can reduce silver(I) ion to metallic silver to produce a dense black silver image under the short time and high temperature conditions that occur when using thermal print-heads during direct thermal printing. The materials are characterized by their calculated aqueous deprotonation and their calculated anion HOMO energies.
Abstract:
Novel silver compounds can include a primary core of a photosensitive silver halide and a shell covering the primary core. This shell includes one or more non-photosensitive silver salts, each silver salt including an organic silver coordinating ligand. Other novel silver compounds are homogeneous silver salts of organic silver coordinating ligands throughout (non-core-shell). Still other silver compounds can include a primary core of a non-photosensitive metal salt and a shell covering the primary core. This shell includes one or more non-photosensitive silver salts, each silver salt including an organic silver coordinating ligand. These types of silver compounds can be used as sources of reducible silver ions in thermally developable imaging materials including thermographic and photothermographic materials.
Abstract:
Novel silver compounds can include a primary core of a photosensitive silver halide and a shell covering the primary core. This shell includes one or more non-photosensitive silver salts, each silver salt including an organic silver coordinating ligand. Other novel silver compounds are homogeneous silver salts of organic silver coordinating ligands throughout (non-core-shell). Still other silver compounds can include a primary core of a non-photosensitive metal salt and a shell covering the primary core. This shell includes one or more non-photosensitive silver salts, each silver salt including an organic silver coordinating ligand. These types of silver compounds can be used as sources of reducible silver ions in thermally developable imaging materials including thermographic and photothermographic materials.
Abstract:
Novel silver-carboxylate/1,2-diazine compounds having the formula: ##STR1## wherein: R.sup.1 represents either an alkyl, aralkyl, cycloalkyl, or alkenyl group of up to 29 carbon atoms; or an aryl group of up to 14 carbon atoms; andand R.sup.2 represents either hydrogen, an alkyl group, a cycloalkyl group fused to the 1,2-diazine ring, or the atoms necessary to complete a 5- or 6-membered aromatic ring fused to the 1,2-diazine ring.The novel silver-carboxylate/1,2-diazine compounds are coordination compounds of two silver-carboxylate molecules and two molecules comprising a 1,2-diazine nucleus. These compounds can serve as the silver source in a black-and-white thermographic or photothermographic element or as the oxidizing agent for a dye-based thermographic or photothermographic color-imaging construction.
Abstract:
Claimed methods do not rely on highly reactive reagents, highly corrosive solutions, high temperatures, or long reaction times. Nanowires produced from such methods are free of large attached nanoparticles that have accompanied previously disclosed copper nanowires. Such nanowires are useful for electronics applications.
Abstract:
Nanowire preparation methods, compositions, and articles are disclosed. Such nanowires may be thicker than other nanowires and may be useful in devices requiring high electrical current densities.
Abstract:
Nanomaterial preparation methods, compositions, and articles are disclosed and claimed. Such methods can provide nanomaterials with improved morphologies relative to previous methods. Such materials are useful in electronic applications.
Abstract:
Nanowire preparation methods, compositions, and articles are disclosed. Such nanowires may be thicker than other nanowires and may be useful in devices requiring high electrical current densities.
Abstract:
Non-photosensitive direct thermographic materials comprise a reducing agent that is a catechol borate compound. These compounds can reduce silver(I) ion to metallic silver to produce a dense black silver image under the short time and high temperature conditions that occur when using thermal print-heads during direct thermal printing.
Abstract:
Photothermographic materials have increased photospeed provided by gold(III)-containing chemical sensitizers that are used combination with sulfur- and/or tellurium-containing chemical sensitizers. Increased photographic speed is achieved with minimal increase in Dmin. The gold(III)-containing chemical sensitizers are represented by the following Structure GOLD: Au(III)L′rYq GOLD wherein L′ represents the same or different ligands, each ligand comprising at least one heteroatom that is capable of forming a bond with gold, Y is an anion, r is an integer of from 1 to 8, and q is an integer of from 0 to 3.