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    Silver-carboxylate/1,2-diazine compounds as silver sources in photothermographic and thermographic elements
    1.
    发明授权
    Silver-carboxylate/1,2-diazine compounds as silver sources in photothermographic and thermographic elements 失效
    银 - 羧酸盐/ 1,2-二嗪化合物作为光热照相和热成像元素中的银源

    公开(公告)号：US5350669A

    公开(公告)日：1994-09-27

    申请号：US183486

    申请日：1994-01-19

    申请人： David R. Whitcomb ,  William C. Frank

    发明人： David R. Whitcomb ,  William C. Frank

    IPC分类号： C07F1/00 ,  C07F1/10 ,  G03C1/498

    CPC分类号： G03C1/4989 ,  C07F1/005 ,  G03C1/49809

    摘要： Novel silver-carboxylate/1,2-diazine compounds having the formula: ##STR1## wherein: R.sup.1 represents either an alkyl, aralkyl, cycloalkyl, or alkenyl group of up to 29 carbon atoms; or an aryl group of up to 14 carbon atoms; andand R.sup.2 represents either hydrogen, an alkyl group, a cycloalkyl group fused to the 1,2-diazine ring, or the atoms necessary to complete a 5- or 6-membered aromatic ring fused to the 1,2-diazine ring.The novel silver-carboxylate/1,2-diazine compounds are coordination compounds of two silver-carboxylate molecules and two molecules comprising a 1,2-diazine nucleus. These compounds can serve as the silver source in a black-and-white thermographic or photothermographic element or as the oxidizing agent for a dye-based thermographic or photothermographic color-imaging construction.

    摘要翻译： 具有下式的新型羧酸银/ 1,2-二嗪化合物：其中：R1代表具有至多29个碳原子的烷基，芳烷基，环烷基或链烯基; 或至多14个碳原子的芳基; R2表示与1,2-二嗪环稠合的氢，烷基，环烷基，或完全与1,2-二嗪环稠合的5元或6元芳环所必需的原子。 新型羧酸银/ 1,2-二嗪化合物是两个银 - 羧酸盐分子和包含1,2-二嗪核的两个分子的配位化合物。 这些化合物可以作为黑白色热成像或光热敏成像元件中的银源或用作染料基热成像或光热成像彩色成像结构的氧化剂。

    Silver-carboxylate/1,2-diazine compounds as silver sources in photothermographic and thermographic elements
    2.
    发明授权
    Silver-carboxylate/1,2-diazine compounds as silver sources in photothermographic and thermographic elements 失效
    银 - 羧酸盐/ 1,2-二嗪化合物作为光热照相和热成像元素中的银源

    公开(公告)号：US5466804A

    公开(公告)日：1995-11-14

    申请号：US254552

    申请日：1994-06-06

    申请人： David R. Whitcomb ,  William C. Frank

    发明人： David R. Whitcomb ,  William C. Frank

    IPC分类号： C07F1/00 ,  C07F1/10 ,  G03C1/498

    CPC分类号： G03C1/4989 ,  C07F1/005 ,  G03C1/49809

    摘要： Novel silver-carboxylate/1,2-diazine compounds having the formula: ##STR1## wherein: R.sup.1 represents either an alkyl, aralkyl, cycloalkyl, or alkenyl group of up to 29 carbon atoms; or an aryl group of up to 14 carbon atoms; andand R.sup.2 represents either hydrogen, an alkyl group, a cycloalkyl group fused to the 1,2-diazine ring, or the atoms necessary to complete a 5- or 6-membered aromatic ring fused to the 1,2-diazine ring.The novel silver-carboxylate/1,2-diazine compounds are coordination compounds of two silver-carboxylate molecules and two molecules comprising a 1,2-diazine nucleus. These compounds can serve as the silver source in a black-and-white thermographic or photothermographic element or as the oxidizing agent for a dye-based thermographic or photothermographic color-imaging construction.

    摘要翻译： 具有下式的新型羧酸银/ 1,2-二嗪化合物：其中：R1代表具有至多29个碳原子的烷基，芳烷基，环烷基或链烯基; 或至多14个碳原子的芳基; R2表示与1,2-二嗪环稠合的氢，烷基，环烷基或完全与1,2-二嗪环稠合的5元或6元芳环所必需的原子。 新型羧酸银/ 1,2-二嗪化合物是两个银 - 羧酸盐分子和包含1,2-二嗪核的两个分子的配位化合物。 这些化合物可以作为黑白色热成像或光热敏成像元件中的银源或用作染料基热成像或光热成像彩色成像结构的氧化剂。

    High speed photothermographic materials with combined chemical sensitizers and methods of using same
    8.
    发明授权
    High speed photothermographic materials with combined chemical sensitizers and methods of using same 失效
    具有组合化学敏化剂的高速光热成像材料及其使用方法

    公开(公告)号：US06423481B1

    公开(公告)日：2002-07-23

    申请号：US09768094

    申请日：2001-01-23

    申请人： Sharon M. Simpson ,  David R. Whitcomb ,  Steven M. Shor

    发明人： Sharon M. Simpson ,  David R. Whitcomb ,  Steven M. Shor

    IPC分类号： G03C1498

    CPC分类号： G03C1/49845 ,  G03C1/09 ,  G03C1/49827 ,  G03C1/49854 ,  G03C1/49881 ,  G03C2001/091 ,  G03C2001/096 ,  G03C2001/098

    摘要： Photothermographic materials have increased photospeed provided by gold(III)-containing chemical sensitizers that are used combination with sulfur- and/or tellurium-containing chemical sensitizers. Increased photographic speed is achieved with minimal increase in Dmin. The gold(III)-containing chemical sensitizers are represented by the following Structure GOLD: Au(III)L′rYq GOLD wherein L′ represents the same or different ligands, each ligand comprising at least one heteroatom that is capable of forming a bond with gold, Y is an anion, r is an integer of from 1 to 8, and q is an integer of from 0 to 3.

    摘要翻译： 光热成像材料具有增加的由含金（III）的化学敏化剂提供的感光速率，其与含硫和/或含碲化学敏化剂结合使用。 以Dmin的最小增加实现提高的照相速度。 含金（III）的化学增感剂由以下结构金表示：其中L'表示相同或不同的配体，每个配体包含至少一个能够与金形成键的杂原子，Y是阴离子，r 为1〜8的整数，q为0〜3的整数。

    Positive-acting thermographic materials
    10.
    发明授权
    Positive-acting thermographic materials 失效
    正效热成像材料

    公开(公告)号：US4910186A

    公开(公告)日：1990-03-20

    申请号：US280569

    申请日：1988-12-06

    申请人： David R. Whitcomb

    发明人： David R. Whitcomb

    IPC分类号： B41M5/32

    CPC分类号： B41M5/32 ,  Y10S428/913

    摘要： A positive-acting thermographic material which is black or dark colored in the unexposed condition turns white or light colored when exposed to elevated temperatures. The material comprises a binder, a dark colored complex of ferric iron with a ligand chosen from organothiophosphorus acids, and a white organophosphorus acid or its alkali or alkaline earth metal salt. At elevated temperatures a double decomposition reaction occurs giving the light colored complex of ferric iron with the organophosphorus acid.

    摘要翻译： 在未暴露的状态下呈黑色或深色的正性温度记录材料在暴露于升高的温度时变为白色或浅色。 该材料包括粘合剂，三价铁与选自有机硫代磷酸的配体的深色络合物，以及白色有机磷酸或其碱金属或碱土金属盐。 在升高的温度下，发生双重分解反应，得到三价铁与有机磷酸的浅色络合物。