公开(公告)号：US07164037B2

公开(公告)日：2007-01-16

申请号：US10536968

申请日：2003-12-04

Applicant: Frank Dietsche ,  Dietmar Haering ,  Eva Wagner ,  Reinhold Schwalm ,  Heinz-Peter Rink ,  Erich Beck

Inventor： Frank Dietsche ,  Dietmar Haering ,  Eva Wagner ,  Reinhold Schwalm ,  Heinz-Peter Rink ,  Erich Beck

IPC: C07C261/00 ,  C08G73/00

CPC classification number: C12P7/62 ,  C08G71/04 ,  C09D133/14 ,  C12P13/02

Abstract: Enzymatic preparation of (meth)acrylic esters containing urethane groups, and their use in radiation-curable compositions.

Abstract translation: 包含氨基甲酸酯基团的（甲基）丙烯酸酯的酶制剂及其在可辐射固化组合物中的用途。

公开(公告)号：US07105206B1

公开(公告)日：2006-09-12

申请号：US10130599

申请日：2000-11-21

Applicant: Erich Beck ,  Oliver Deis ,  Peter Enenkel ,  Wolfgang Schrof

Inventor： Erich Beck ,  Oliver Deis ,  Peter Enenkel ,  Wolfgang Schrof

IPC: C08J7/04 ,  C08J7/18 ,  C08F2/46 ,  C08F2/48

CPC classification number: F26B3/283 ,  B05D3/0486 ,  B05D3/067 ,  B33Y70/00 ,  F26B21/14 ,  F26B2210/12

Abstract: A process is described for producing molding compounds and coatings on substrates by curing radiation-curable compositions under inert gas by exposure to light wherein said inert gas comprises a gas heavier than air, and lateral escape of the inert gas in the course of radiation curing is prevented by means of appropriate apparatus or other measures.

Abstract translation: 描述了一种用于通过暴露在光下在惰性气体下固化可辐射固化组合物来在基底上生产模塑料和涂层的方法，其中所述惰性气体包括比空气重的气体，并且在辐射固化过程中惰性气体的侧向逸出是 通过适当的装置或其他措施来防止。

公开(公告)号：US20060115602A1

公开(公告)日：2006-06-01

申请号：US11324559

申请日：2006-01-04

Applicant: Erich Beck ,  Oliver Deis ,  Peter Enenkel ,  Wolfgang Schrof

Inventor： Erich Beck ,  Oliver Deis ,  Peter Enenkel ,  Wolfgang Schrof

IPC: B05D3/00

CPC classification number: F26B3/283 ,  B05D3/0486 ,  B05D3/067 ,  B33Y70/00 ,  F26B21/14 ,  F26B2210/12

Abstract: A process is described for producing molding compounds and coatings on substrates by curing radiation-curable compositions under inert gas by exposure to light wherein said inert gas comprises a gas heavier than air, and lateral escape of the inert gas in the course of radiation curing is prevented by means of appropriate apparatus or other measures.

Abstract translation: 描述了一种用于通过暴露在光下在惰性气体下固化可辐射固化组合物来在基底上生产模塑料和涂层的方法，其中所述惰性气体包括比空气重的气体，并且在辐射固化过程中惰性气体的侧向逸出是 通过适当的装置或其他措施来防止。

公开(公告)号：US06500878B1

公开(公告)日：2002-12-31

申请号：US09619140

申请日：2000-07-18

Applicant: Wolfgang Reich ,  Peter Enenkel ,  Edmund Keil ,  Matthias Lokai ,  Erich Beck ,  Klaus Menzel

Inventor： Wolfgang Reich ,  Peter Enenkel ,  Edmund Keil ,  Matthias Lokai ,  Erich Beck ,  Klaus Menzel

IPC: C08J328

CPC classification number: C09D163/00 ,  C08L63/00 ,  C09D133/062 ,  G03F7/085 ,  C08L2666/04 ,  C08L2666/14

Abstract: In a process for improving the adhesive strength of radiation-cured films of acrylate resins which comprise compounds having at least one amine group and at least one unsaturated acrylate group and, in particular, an amino-modified acrylate resin having a molecular weight Mn of at least 300, on substrates, the acrylate resins are admixed with amine-hardenable polyepoxides having an epoxide value of from 1 to 15 mol/kg such as polyglycidyl esters or polyglycidyl ethers. Preferred curable mixtures of amine-modified acrylate resins with polyepoxides have amine numbers of from 1 to 250 mg KOH/g and epoxide values of from 0.1 to 4 mol/kg. The mixtures applied as coating films to metal substrates or plastics substrates, in particular, are radiation-cured with, e.g., UV light and an at least partial amine hardening of the polyepoxide compounds in the mixture is conducted by thermal conditioning at, e.g., from 50 to 120° C.

Abstract translation: 在改进丙烯酸酯树脂的辐射固化膜的粘合强度的方法中，该方法包括具有至少一个胺基和至少一个不饱和丙烯酸酯基的化合物，特别是分子量为Mn的氨基改性丙烯酸酯树脂 至少300个，在基材上，丙烯酸酯树脂与环氧化物值为1至15mol / kg的胺可硬化聚环氧化物混合，例如聚缩水甘油酯或多缩水甘油醚。 胺改性丙烯酸酯树脂与聚环氧化物的优选可固化混合物具有1至250mg KOH / g的胺值和0.1至4mol / kg的环氧化物值。 特别是作为涂膜施加到金属基材或塑料基材上的混合物，例如用UV光进行辐射固化，并且混合物中聚环氧化物化合物的至少部分胺硬化通过热调节进行，例如从 50〜120℃

公开(公告)号：US06242101B1

公开(公告)日：2001-06-05

申请号：US09283864

申请日：1999-04-01

Applicant: Reinhold Schwalm ,  Rainer Königer ,  Erich Beck ,  Klaus Menzel ,  Wolfgang Paulus ,  Peter Enenkel

Inventor： Reinhold Schwalm ,  Rainer Königer ,  Erich Beck ,  Klaus Menzel ,  Wolfgang Paulus ,  Peter Enenkel

IPC: C08F246

CPC classification number: C09D175/16 ,  C08F290/06 ,  C08F290/14 ,  C08G18/282 ,  C08G18/672 ,  C08G18/792 ,  C08G18/8175 ,  C09D4/00 ,  C09D4/06 ,  Y10T428/31551 ,  Y10T428/31605 ,  C08F222/1006 ,  C08F290/147

Abstract: Radiation-curable formulations based on ethylenically unsaturated prepolymers and difunctional esters of ethylenically unsaturated carboxylic acids with diols having a linear alkylene chain of 7 to 14 carbon atoms, a process for coating substrates using these radiation-curable formulations, and their use as automotive topcoats.

Abstract translation: 基于烯键式不饱和预聚物和烯键式不饱和羧酸的双官能酯与具有7-14个碳原子的直链亚烷基链的二醇的可辐射固化制剂，使用这些可辐射固化制剂涂覆基质的方法及其作为汽车面漆的用途。

公开(公告)号：US6143233A

公开(公告)日：2000-11-07

申请号：US142171

申请日：1998-09-22

Applicant: Wolfgang Reich ,  Reinhold Schwalm ,  Erich Beck ,  Lukas Haussling ,  Oskar Nuyken ,  Roman-Benedikt Raether

Inventor： Wolfgang Reich ,  Reinhold Schwalm ,  Erich Beck ,  Lukas Haussling ,  Oskar Nuyken ,  Roman-Benedikt Raether

IPC: C08J7/04 ,  C08F2/46 ,  C08F8/00 ,  C08F8/14 ,  C08F220/18 ,  C09D133/14 ,  G03F7/038 ,  C08G65/14 ,  C08G65/16

CPC classification number: C08F8/14

Abstract: A polymer which can be crosslinked by high-energy radiation and contains from 0.1 to 50% by weight, based on the polymer, of 2,3-dihydrofuran groups or derivatives thereof, each calculated as 2,3-dihydrofuran.

Abstract translation: PCT No.PCT / EP97 / 01206 Sec。 371日期：1998年9月22日 102（e）1998年9月22日PCT 1997年3月10日PCT公布。 公开号WO97 / 35907 日期1997年10月2日一种可以通过高能辐射交联并且基于聚合物含有0.1至50重量％的2,3-二氢呋喃基或其衍生物的聚合物，其分别计算为2,3-二氢呋喃 。

公开(公告)号：US6136383A

公开(公告)日：2000-10-24

申请号：US123461

申请日：1998-07-28

Applicant: Manfred Schwartz ,  Klaus Menzel ,  Bertold Bechert ,  Erich Beck ,  Wolfgang Reich

Inventor： Manfred Schwartz ,  Klaus Menzel ,  Bertold Bechert ,  Erich Beck ,  Wolfgang Reich

IPC: B05D7/24 ,  C04B41/48 ,  C04B41/52 ,  C04B41/63 ,  C04B41/70 ,  C08F2/46 ,  C09D175/16 ,  C09D183/07 ,  C08F2/48

CPC classification number: C04B41/009 ,  C04B41/4884 ,  C04B41/52 ,  C04B41/63 ,  C04B41/70 ,  C09D175/16 ,  C04B2111/21

Abstract: Radiation-curable preparations comprise at least one polymer which has ethylenically unsaturated double bonds and are used for the coating of mineral moldings.A process for coating mineral moldings, and also mineral moldings which have a coating cured by radiation, are also described.

Abstract translation: 可辐射固化的制剂包含至少一种具有烯键式不饱和双键的聚合物，并用于矿物模塑的涂覆。 还描述了用于涂覆矿物模制品的方法以及具有通过辐射固化的涂层的矿物模制品。

公开(公告)号：US06066746A

公开(公告)日：2000-05-23

申请号：US266913

申请日：1999-03-12

Applicant: Wolfgang Reich ,  Reinhold Schwalm ,  Erich Beck ,  Lukas Haussling ,  Oskar Nuyken ,  Roman-Benedikt Raether

Inventor： Wolfgang Reich ,  Reinhold Schwalm ,  Erich Beck ,  Lukas Haussling ,  Oskar Nuyken ,  Roman-Benedikt Raether

IPC: C08F34/00 ,  C08F34/02 ,  C08G59/24 ,  C08G61/10 ,  C08G61/12 ,  C08G65/14 ,  C08G65/16 ,  C09D4/00 ,  C09D163/00 ,  C07D307/26 ,  C07D307/32

CPC classification number: C09D4/00 ,  C08F34/02 ,  C08G59/24 ,  C08G65/14 ,  C08G65/16 ,  C09D163/00

Abstract: Process for producing coatings or moldings by radiation curing, which involves using high-energy light to irradiate radiation-curable compositions containing 1-100% by weight, based on the total amount of free-radically or cationically polymerizable compounds, of compounds A) containing at least one cationically polymerizable 2,3-dihydrofuran group.

Abstract translation: 用于通过辐射固化生产涂层或模制品的方法，其涉及使用高能量光以基于自由基或阳离子聚合化合物的总量计，含有1-100重量％的可辐射固化组合物含有化合物A） 至少一种阳离子可聚合的2,3-二氢呋喃基。

公开(公告)号：US5602191A

公开(公告)日：1997-02-11

申请号：US455621

申请日：1995-05-31

Applicant: Wolfgang Reich ,  Erich Beck ,  Edmund Keil ,  Ulrich Erhardt ,  Adolf Nuber

Inventor： Wolfgang Reich ,  Erich Beck ,  Edmund Keil ,  Ulrich Erhardt ,  Adolf Nuber

IPC: C08F20/26 ,  C07C67/26 ,  C07C67/60 ,  C08F2/46 ,  C08F2/48 ,  C08F290/00 ,  C08F299/02 ,  C08G59/17 ,  C08G63/47

CPC classification number: C08G63/47 ,  C07C67/26 ,  C07C67/60

Abstract: Radiation-curable acrylates are prepared by a process in which the hydroxy compound is reacted with acrylic acid or methacrylic acid in a first stage and, in a second stage, the reaction product of the first stage is reacted with an epoxide compound in the presence of, as a catalyst, a quaternary ammonium or phosphonium compound of the general formula ##STR1## where X.sup.- is an opposite ion and R.sup.1 to R.sup.4 independently of one another are each C.sub.1 -C.sub.18 -alkyl which may be substituted by one or two phenyl groups or are each C.sub.6 -C.sub.12 -aryl which may be substituted by one or two C.sub.1 -C.sub.6 -alkyl groups.

Abstract translation: 可辐射固化的丙烯酸酯通过在第一阶段中羟基化合物与丙烯酸或甲基丙烯酸反应的方法制备，并且在第二阶段中，使第一阶段的反应产物与环氧化合物在 作为催化剂，通式为“IMAGE”I或“IMAGE”II的季铵或鏻化合物，其中X + E，crc - + EE是相反的离子，R1至R4彼此独立地为C1-C18 - 烷基，其可以被一个或两个苯基取代，或各自可被一个或两个C 1 -C 6 - 烷基取代的C 6 -C 12 - 芳基。

公开(公告)号：US5096938A

公开(公告)日：1992-03-17

申请号：US504087

申请日：1990-04-03

Applicant: Erich Beck ,  Wolfram Weiss ,  Horst Schmidt

Inventor： Erich Beck ,  Wolfram Weiss ,  Horst Schmidt

IPC: C08F20/26 ,  C07C67/60 ,  C08F2/50 ,  C08F299/00 ,  C08F299/04 ,  C08L63/00 ,  C09D167/07

CPC classification number: C07C67/60 ,  C09D167/07 ,  C08L63/00 ,  Y10S525/922

Abstract: Radiation-curable catalysts are obtainable by reactingA) 1 equivalent of a dihydric to hexahydric oxyalkylated C.sub.2 -C.sub.10 -alcohol withB) from 0.05 to 1 equivalent of a dibasic to tetrabasic C.sub.3 -C.sub.36 -carboxylic acid or its anhydride andC) from 0.1 to 1.5 equivalents of acrylic acid and/or methacrylic acidand reacting the excess carboxyl groups with an equivalent amount of epoxide compound, and are used in radiation-curable coating materials.

Abstract translation: 可辐射固化的催化剂可通过使A）1当量的二羟基至六价烷氧基化的C 2 -C 10醇与B）0.05至1当量的二价至三价C 3 -C 36羧酸或其酸酐反应，C）为0.1 至1.5当量的丙烯酸和/或甲基丙烯酸，并使过量的羧基与等量的环氧化合物反应，并用于可辐射固化的涂料中。