公开(公告)号：US12281090B2

公开(公告)日：2025-04-22

申请号：US17778921

申请日：2020-12-18

Applicant: Furanix Technologies B.V.

Inventor： Hendrikus Jacob Baars ,  Jan Hendrik Blank ,  Jeffrey John Kolstad ,  Ana Sofia Vagueiro De Sousa Dias

IPC: C07D307/68

Abstract: A process for producing a carboxylic acid composition including 2,5-furandicarboxylic acid, including the steps: a) oxidizing an oxidizable compound including 5-alkoxymethylfurfural in an oxidation reactor in the presence of a saturated organic acid solvent having from 2 to 6 carbon atoms and a catalyst system comprising cobalt, manganese and bromine using an oxidizing gas at a temperature in the range of 160 to 210° C. to obtain a crude carboxylic acid composition including mono alkyl ester of 2,5-furandicarboxylic acid and solid 2,5-furandicarboxylic acid, b) isolating at least a portion of the solid 2,5-furandicarboxylic acid from the crude carboxylic acid composition in a solid-liquid separation zone to generate a solid cake and a mother liquor, c) determining the amount of manganese and/or cobalt in the cake, and d) increasing the amount of one or more controlling acids in the oxidation reactor.

公开(公告)号：US20240002592A1

公开(公告)日：2024-01-04

申请号：US18039526

申请日：2021-12-21

Applicant: Furanix Technologies B.V.

Inventor： Uitslag Tom John ,  Aberson Rene

IPC: C08G63/672 ,  C08G63/84 ,  C08G63/83

CPC classification number: C08G63/672 ,  C08G63/84 ,  C08G63/83

Abstract: A process for producing a polyester having 2,5-furandicarboxylate units, which process includes: a) providing or producing a starting composition including 2,5-furandicarboxylic acid or a diester thereof and an aliphatic diol, b) subjecting the starting composition to esterification conditions to produce an ester composition, and c) contacting the ester composition with an aluminum containing catalyst and a phosphorous compound at polycondensation conditions to produce a polyester comprising 2,5-furandicarboxylate units, where the phosphorous compound includes one or more compounds of phosphoric acid based compounds that include an aromatic moiety.

公开(公告)号：US20230272160A1

公开(公告)日：2023-08-31

申请号：US18017874

申请日：2021-08-27

Applicant: Furanix Technologies B.V.

Inventor： Matheus Adrianus Dam ,  Bing Wang ,  Hendawy Elfeki

IPC: C08G63/86 ,  C08G63/88 ,  C08G63/80 ,  C08G63/181

CPC classification number: C08G63/863 ,  C08G63/88 ,  C08G63/80 ,  C08G63/181

Abstract: A process for producing a polyester having 2,5-furandicarboxylate units includes: a) providing or producing a starting composition including 2,5-furandicarboxylic acid, an aliphatic diol and a suppressant for suppressing ether formation between the aliphatic diol molecules, b) subjecting the starting composition to esterification conditions to produce an ester composition, and c) contacting the ester composition with a germanium containing catalyst at polycondensation conditions to produce a polyester including 2,5-furandicarboxylate units, where the suppressant includes amines and lithium hydroxide.

公开(公告)号：US20230020208A1

公开(公告)日：2023-01-19

申请号：US17780063

申请日：2020-12-18

Applicant: Furanix Technologies B.V.

Inventor： Jeffrey John Kolstad ,  Ana Sofia Vagueiro De Sousa Dias ,  Johannes Maria Franciscus Sijben ,  Ana Rita Martins Guerreiro Rocha Almeida ,  Ines Dacil Gonzalez Jimenez

IPC: C07D307/68 ,  C08G63/672

Abstract: Thermal treatment of purified FDCA for producing a carboxylic acid composition, the process comprising the steps of providing or producing a thermal treatment composition comprising a purified carboxylic acid composition and an organic acid containing treatment solvent composition; subjecting the thermal treatment composition to an elevated temperature, wherein the FDCA is partially dissolved, and cooling the treated composition and separating at least a portion of the FDCA from the treated composition to obtain a carboxylic acid composition.

公开(公告)号：US20220403157A1

公开(公告)日：2022-12-22

申请号：US17773648

申请日：2020-10-29

Applicant: Furanix Technologies B.V.

Inventor： Francesco Acquasanta

IPC: C08L67/02

Abstract: A polyester composition includes (a) poly(alkylene-2,5-furandicarboxylate); and (b) an oxygen scavenger composition including (b1) a polybutadiene sacrificial material; (b2) an oxidation catalyst; (b3) optionally, a carrier; and (b4) optionally, a compatibilizer.

公开(公告)号：US11325363B2

公开(公告)日：2022-05-10

申请号：US16490307

申请日：2018-02-28

Applicant: TOYOBO CO., LTD. ,  Furanix Technologies B.V.

Inventor： Shota Hayakawa ,  Yukihiro Numata ,  Katsuya Ito ,  Jun Inagaki ,  Jesper Gabriel Van Berkel

IPC: B32B27/36 ,  B32B27/08 ,  C08G63/137 ,  C08L67/02 ,  C08G63/12 ,  C08G63/16 ,  C08G63/18 ,  C08G63/127 ,  C08G63/123 ,  C08J7/052

Abstract: An object is to provide a laminate having excellent lamination strength that includes a polyester film having a furandicarboxylate unit and a heat-sealable resin layer, and to provide a packaging bag including the same. A laminate including a polyester film and a heat-sealable resin layer, wherein the polyester film is a biaxially oriented polyester film containing a polyethylene furandicarboxylate resin composed of a furandicarboxylic acid and ethylene glycol, a plane orientation coefficient ΔP of the film is 0.100 or more and 0.160 or less, a thickness of the film is 1 μm or more and 300 μm or less, a heat shrinkage rate of the film is 10% or less when heated at 150° C. for 30 minutes, and lamination strength of the laminate is 2.0 N/15 mm or more.

公开(公告)号：US20210032217A1

公开(公告)日：2021-02-04

申请号：US16965756

申请日：2019-01-31

Applicant: Furanix Technologies B.V.

Inventor： Robert-Jan van Putten ,  Benjamin McKay ,  Gerardus Johannes Maria Gruter ,  Jan Cornelis van der Waal

IPC: C07D307/50 ,  C07B63/00

Abstract: A process includes the following steps: a) converting a solid material containing hemicellulose, cellulose and lignin, by: (i) hydrolyzing at least part of the hemicellulose of the solid material with a first aqueous hydrochloric acid solution, yielding a remaining solid material and a hydrochloric acid- containing, aqueous, first hydrolysate product solution; (ii) hydrolyzing at least part of the cellulose of the remaining solid material with a second aqueous hydrochloric acid solution, yielding a residue and a hydrochloric acid-containing, aqueous, second hydrolysate product solution; (b) forwarding to step (c) a, hydrochloric acid-containing, aqueous intermediate product solution comprising: a part of or the whole of the hydrochloric acid-containing, aqueous first and/or second hydrolysate product solution of step (a); and (c) heating at least part of the hydrochloric acid-containing, aqueous intermediate product solution to yield a product solution containing 5-(chloromethyl)furfural, and extracting the 5-(chloromethyl)furfural from the product solution into an extraction solvent.

公开(公告)号：US20210016484A1

公开(公告)日：2021-01-21

申请号：US16490205

申请日：2018-02-28

Applicant: TOYOBO CO., LTD. ,  FURANIX TECHNOLOGIES B.V.

Inventor： Shota HAYAKAWA ,  Yukihiro NUMATA ,  Katsuya ITO ,  Jun INAGAKI ,  Toshiyuki SHIMIZU ,  Shoichi GYOBU ,  Chikao MORISHIGE ,  Jesper Gabriel VAN BERKEL

IPC: B29C48/00 ,  B29C48/305 ,  B29C48/08 ,  B29C55/12

Abstract: It is provided that a method for producing a biaxially oriented polyester film that can be used for industrial and packaging applications. A method for producing a biaxially oriented polyester film, comprising: a step of feeding a polyester resin into an extruder, a step of extruding the molten polyester resin from an extruder to obtain a molten resin sheet at 250 to 310° C., a step of attaching the molten resin sheet closely to a cooling roll by an electrostatic application method to obtain an unstretched sheet, and a step of biaxially stretching the unstretched sheet, wherein the polyester resin fulfills the following (A) to (C): (A) the polyester resin comprises a polyethylene furandicarboxylate resin composed of a furandicarboxylic acid and ethylene glycol; (B) an intrinsic viscosity of the polyester resin is 0.50 dL/g or more; (C) a melt specific resistance value at 250° C. of the polyester resin is 3.0×107 ω·cm or less.

公开(公告)号：US10316140B2

公开(公告)日：2019-06-11

申请号：US15127596

申请日：2015-03-23

Applicant: Furanix Technologies B.V. ,  Roquette Frères

Inventor： Laszlo Sipos ,  Gerardus Johannes Maria Gruter ,  Jeffrey John Kolstad ,  Gabriel Degand ,  Nicolas Jacquel ,  René Saint-Loup ,  Matheus Adrianus Dam ,  Joseph D. Schroeder

IPC: C08G63/672 ,  C08G63/78

Abstract: A polyester including at least one furandicarboxylate unit, at least one saturated, linear or branched, diol unit including from 2 to 10 carbon atoms, and at least one bicyclic diol unit, the said bicyclic diol being chosen from: isosorbide, isoidide, isomannide, 2,3:4,5-di-O-methylene-galactitol, and 2,4:3,5-di-O-methylene-D-mannitol. The glass transition temperature of the polyester is greater than or equal to 90° C. Processes for preparing this polyester are also described.

公开(公告)号：US09902750B2

公开(公告)日：2018-02-27

申请号：US14895027

申请日：2014-06-06

Applicant: Furanix Technologies B.V.

Inventor： Benjamin McKay ,  Ana Sofia Vagueiro De Sousa Dias ,  Sarwat Iqbal ,  Gerardus Johannes Maria Gruter ,  Robert-Jan Van Putten

IPC: C07H1/00 ,  C07H3/02 ,  C07H15/04 ,  C13K11/00

CPC classification number: C07H3/02 ,  C07H1/00 ,  C07H15/04 ,  C13K11/00

Abstract: A fructoside-containing product is manufactured from a glucose-rich feedstock, in a process where glucose to fructose is isomerized by contacting the glucose-rich feedstock with a basic isomerization catalyst in an alcoholic medium at a temperature of at least 75° C., to yield a fructose-containing product; and where at least part of the fructose-containing product obtained therefrom is reacted with an alcohol in the presence of an acid catalyst to yield a fructoside-containing product.