Solid pigment preparations containing pigment derivatives and surface-active additives

    公开(公告)号:US07198667B2

    公开(公告)日:2007-04-03

    申请号:US10534298

    申请日:2003-11-28

    IPC分类号: C09B67/20 C09C3/08 C08K9/04

    摘要: Solid pigment preparations containing the following ingredients as substantial components: (A) 60–85 wt. % of at least one organic pigment, (B) 0.1–15 wt. % of at least one pigment derivative of general formula I wherein the variables have the following meanings: P is the radical of the parent substance of an organic pigment; T1, T2 independently represent a chemical bond, —CONR1— or —SO2NR1—; B1, B2 independently represent a chemical bond, C1–C8-alkylene or phenylene; X, Y independently represent similar or different groups —SO3— Ka+ or —COO— Ka+; m, n represent a rational number from 0 to 3, whereby 1=m+n=4; Ka+ H+, Li+, Na+, K+, N+R2R3 R4 R5 or a mixture of said cations; R1 represents hydrogen; C1–C4-alkyl; phenyl or naphthyl which can be respectively substituted by C1–C18-alkyl; R2, R3, R4, R5 independently represent hydrogen; C1–C30-alkyl; C3–C30-alkenyl; C5–C6-cycloalkyl which can be substituted by C1–C24-alkyl; phenyl or naphthyl which can be respectively substituted by C1–C24-alkyl or C2–C24-alkenyl; a radical of formula —[CHR6—CHR7—O]x—R8, wherein the repeating units —[CHR6—CHR7—O] for x >1 can vary; R6, R7, R8 independently represent hydrogen or C1–C6-alkyl; x is a whole number =1, and (C) 14.9 39.9 wt. % of at least one surface active additive from the group of non-ionic polyethers containing no primary amino groups, the acidic phosphoric acid esters, phosphonic acid esters, sulphuric acid esters and/or sulfonic acid esters thereof, the salts thereof and the condensation produces thereof with formaldehyde.

    Preparation of metal-free phthalocyanines
    13.
    发明授权
    Preparation of metal-free phthalocyanines 失效
    无金属酞菁的制备

    公开(公告)号:US5569758A

    公开(公告)日:1996-10-29

    申请号:US356954

    申请日:1994-12-16

    IPC分类号: C09B47/30

    CPC分类号: C09B47/30

    摘要: A process for preparing metal-free phthalocyanines which can carry up to 16 halogen atoms, cyano groups, carboxyl groups, sulfo groups, C.sub.1 -C.sub.18 -alkyl groups and/or aryl radicals as substituents by reductive cyclization of ortho-phthalodinitrile substituted ortho-phthalodinitriles or mixtures thereof comprises effecting the cyclization in C.sub.2 -C.sub.4 -alkylene monoglycols, oligoglycols or polyglycols, their mono-C.sub.1 -C.sub.4 -alkyl or -aryl ethers or their mixtures in the presence of an aromatic compound of the formula I ##STR1## where the substituents X can be identical or different and each denotes hydroxyl, mercapto, amino or C.sub.1 -C.sub.6 -alkylamino, the substituents Y can likewise be identical or different and each denotes halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or C.sub.1 -C.sub.6 -alkoxycarbonyl, m is from 1 to 4 and n is from 0 to 5, subject to the proviso that m+n .ltoreq.6, and the benzene ring A can be fused to a further benzene ring,and of an inorganic base.

    摘要翻译: 一种制备金属酞菁的方法,该方法可以通过邻苯二甲腈取代的邻苯二腈二腈的还原环化,最多可携带16个卤素原子,氰基,羧基,磺基,C 1 -C 18烷基和/或芳基作为取代基 或其混合物包括在式I的芳族化合物存在下,使C2-C4-亚烷基单糖,低聚乙二醇或聚二醇,它们的单C 1 -C 4烷基或芳基醚或其混合物环化,其中 取代基X可以相同或不同,各自表示羟基,巯基,氨基或C 1 -C 6 - 烷基氨基,取代基Y同样可以相同或不同,各自表示卤素,C 1 -C 6 - 烷基,C 1 -C 6 - 烷氧基或C 1 -C 1-6烷氧基羰基,m为1至4,n为0至5,条件是m + n = 6,并且苯环A可以与另一个苯环稠合,并且具有无机 基础。

    Solid pigment preparations containing anionic and non-ionic surface-active additives
    16.
    发明授权
    Solid pigment preparations containing anionic and non-ionic surface-active additives 有权
    含有阴离子和非离子表面活性添加剂的固体颜料制剂

    公开(公告)号:US07384473B2

    公开(公告)日:2008-06-10

    申请号:US10515345

    申请日:2003-06-18

    摘要: Solid pigment preparations comprising as essential constituents (A) from 60% to 10% to 40% by weight of at least one anionic surface-active additive based on acid phosphoric, phosphonic, sulfuric and/or sulfonic esters of polyalkylene oxides or of reaction products of alkylene oxides with aliphatic alcohols, with phenol or naphthol, which may each be alkyl substituted if desired, with aliphatic or aromatic amines or with aliphatic carboxylic acids or carboxamides or on salts thereof, the fraction of the phosphorus-containing additive in a mixture of phosphorus- and sulfur-containing additives being not less than 50% by weight, and (C) from 0% to

    摘要翻译: 含有60%至90%重量的至少一种颜料,(B)> 10%至40%重量的至少一种基于酸性磷酸的阴离子表面活性添加剂的必要组分(A)的固体颜料制剂, 聚氧化烯的膦酸,硫酸和/或磺酸酯或烯化氧与脂族醇的反应产物与苯酚或萘酚,如果需要,它们各自可以被烷基取代,与脂族或芳族胺或与脂族羧酸或羧酰胺或与 其含磷添加剂在含磷和硫的添加剂的混合物中的分数不小于50重量%,(C)0重量%至30重量%的至少一种非离子表面 活性添加剂,前提条件是当组分(C)的份数为0重量%时,组分(B)是磷酸和/或膦酸酯,并用于着色大分子有机和无机材料。

    Liquid formulations of direct dyes
    19.
    发明授权
    Liquid formulations of direct dyes 失效
    直接染料的液体配方

    公开(公告)号:US07331998B2

    公开(公告)日:2008-02-19

    申请号:US10994287

    申请日:2004-11-23

    IPC分类号: C09B67/44 C09B67/00 C09B67/36

    摘要: The present invention relates to aqueous liquid formulations comprising 5-25% by weight of a dye composition comprising 70-95% by weight of a dye obtainable by reduction or thermal treatment of Direct Yellow 11 1-30% by weight of a blue direct dye and 0-20% by weight of a red direct dye (all based on the dye composition) 1-15% by weight of a saturated, cyclic or acyclic water-soluble amine comprising a primary, secondary or tertiary amino group and at least one further functional group selected from primary, secondary and tertiary amino groups, OH groups and ether groups, and 1-30% by weight of urea based on the total weight of the aqueous liquid formulation, wherein the total amount of water-soluble amine and urea does not exceed 40% by weight, and also their use for dyeing cellulose material especially paper.

    摘要翻译: 本发明涉及包含5-25重量%的包含70-95重量%染料的染料组合物的水性液体制剂,所述染料可通过还原或热处理直接黄111-30重量%的蓝色直接染料 和0-20重量%的红色直接染料(均基于染料组合物)1-15重量%的饱和,环状或非环状水溶性胺,其包含伯,仲或叔氨基和至少一个 基于水性液体制剂的总重量,选自伯,仲和叔氨基,OH基和醚基的另外的官能团和1-30重量%的尿素,其中水溶性胺和尿素的总量 不超过40重量%,也用于染色纤维素材料,特别是纸张。

    Solid pigment preparations containing pigment derivatives and surface-active additives

    公开(公告)号:US20060112852A1

    公开(公告)日:2006-06-01

    申请号:US10534298

    申请日:2003-11-28

    IPC分类号: C09D11/00

    摘要: Solid pigment preparations containing the following ingredients as substantial components: (A) 60-85 wt. % of at least one organic pigment, (B) 0.1-15 wt. % of at least one pigment derivative of general formula I wherein the variables have the following meanings: P is the radical of the parent substance of an organic pigment; T1, T2 independently represent a chemical bond, —CONR1— or —SO2NR1—; B1, B2 independently represent a chemical bond, C1-C8-alkylene or phenylene;X, Y independently represent similar or different groups —SO3— Ka+ or —COO— Ka+; m, n represent a rational number from 0 to 3, whereby 1=m+n=4; Ka+ H+, Li+, Na+, K+, N+R2R3 R4 R5 or a mixture of said cations; R1 represents hydrogen; C1-C4-alkyl; phenyl or naphthyl which can be respectively substituted by C1-C18-alkyl; R2, R3, R4, R5 independently represent hydrogen; C1-C30-alkyl; C3-C30-alkenyl; C5-C6-cycloalkyl which can be substituted by C1-C24-alkyl; phenyl or naphthyl which can be respectively substituted by C1-C24-alkyl or C2-C24-alkenyl; a radical of formula —[CHR6—CHR7—O]x—R8, wherein the repeating units —[CHR6—CHR7—O] for x>1 can vary; R6, R7, R8 independently represent hydrogen or C1-C6-alkyl; x is a whole number=1, and (C) 14.9 39.9 wt. % of at least one surface active additive from the group of non-ionic polyethers containing no primary amino groups, the acidic phosphoric acid esters,phosphonic acid esters, sulphuric acid esters and/or sulfonic acid esters thereof, the salts thereof and the condensation produces thereof with formaldehyde.