公开(公告)号：US5464733A

公开(公告)日：1995-11-07

申请号：US009367

申请日：1993-01-26

Applicant: James A. Friday

Inventor： James A. Friday

IPC: G03C7/26 ,  G03C1/76 ,  G03C1/825 ,  G03C7/30 ,  G03C7/305 ,  G03C7/32 ,  G03C1/46

CPC classification number: G03C7/3029 ,  G03C1/7614 ,  G03C1/8255 ,  Y10S430/156

Abstract: Disclosed is a multilayer color photographic element comprising a support having coated thereon photographic silver halide emulsion layers, the layers including blue sensitive, green sensitive and red sensitive layers, the photographic element comprising at least one of a bleach accelerating releasing coupler and a bleach accelerating silver salt in at least one layer of the photographic element and a layer containing finely divided silver. An interlayer is disposed between the layer containing finely divided silver and a layer containing dye forming coupler.

Abstract translation: 公开了一种多层彩色照相元件，其中包括一个其上涂有照相卤化银乳剂层的载体，这些层包括蓝色敏感性，绿色敏感层和红色敏感层，照相元件包括漂白剂加速释放成色剂和漂白剂加速银中的至少一种 至少一层照相材料中的盐和含有细分银的层。 在包含细分银的层和含有染料形成成色剂的层之间设置中间层。

公开(公告)号：US5360703A

公开(公告)日：1994-11-01

申请号：US10689

申请日：1993-01-28

Applicant: Elizabeth P. Chang ,  James A. Friday

Inventor： Elizabeth P. Chang ,  James A. Friday

IPC: G03C7/20 ,  G03C1/035 ,  G03C7/26 ,  G03C7/30 ,  G03C1/46

CPC classification number: G03C7/3022 ,  G03C7/3029

Abstract: Multicolor photographic elements are disclosed containing at least three dye image forming layer units. An enhancement of the speed-granularity relationship of a dye image is obtained when the corresponding dye image forming layer unit contains at least three superimposed silver bromoiodide emulsion layers. The emulsion layer nearest the support containing an average iodide content of up to 60 percent the iodide content of the next overlying of the emulsion layers. The three emulsion layers each differ in speed from the next adjacent of the emulsion layers, with the fastest of the emulsion layers being located nearest the source of exposing radiation and being at least one half stop faster than the next adjacent layer and the slowest of the emulsion layers being located farthest from the source of exposing radiation and being at least one half stop slower than the next adjacent layer. The three emulsions layers are each tabular grain emulsion layers with tabularities of greater than 25. At least the two emulsion layers located nearest the sourch of exposing radiation exhibiting stimulated fluorescent emissions indicative of relatively uniform iodide distribution within the grains.

Abstract translation: 公开了包含至少三个染料成像层单元的多色照相元件。 当相应的染料图像形成层单元含有至少三个叠加的碘化银碘化银乳剂层时，获得染料图像的速度 - 粒度关系的增强。 最接近载体的乳剂层含有平均碘化物含量高达乳液层下一次覆盖的碘化物含量的60％。 三个乳剂层的速度与下一个相邻的乳剂层的速度不同，其中最快的乳剂层位于最接近曝光辐射源的位置，并且比下一个相邻层更快地至少一个半停止，而最慢的 乳剂层位于离曝光辐射源最远处，并且比下一相邻层慢至少一半。 三个乳剂层是每个片状颗粒大于25的片状颗粒乳剂层。至少两个位于最接近暴露辐射源的乳剂层，其表现出刺激的荧光发射，这表明晶粒内的相对均匀的碘分布。

公开(公告)号：US06756188B2

公开(公告)日：2004-06-29

申请号：US10244270

申请日：2002-09-16

Applicant: John E. Keevert ,  Stephen P. Singer ,  Kenneth J. Reed ,  Kenneth J. Lushington ,  Mary C. Brick ,  James A. Friday

Inventor： John E. Keevert ,  Stephen P. Singer ,  Kenneth J. Reed ,  Kenneth J. Lushington ,  Mary C. Brick ,  James A. Friday

IPC: G03C746

CPC classification number: G03C7/30594 ,  G03C1/0051 ,  G03C1/04 ,  G03C7/3022 ,  G03C7/3029 ,  G03C7/30541 ,  G03C2007/3034 ,  Y10S430/156

Abstract: This invention relates to a photographic element comprising a support and at least two silver halide emulsion layers further comprising, an electron transfer agent releasing compound represented by the formula (I): CAR1—(L)n—ETA  (I) wherein: CAR1 is a carrier moiety which is capable of releasing —(L)n-ETA on reaction with oxidized developing agent; L is a divalent linking group, n is 0, 1 or 2; and ETA is a releasable 1-aryl-3-pyrazolidinone electron transfer agent having a calculated log partition coefficient (c log P) greater than or equal to 2.40 and the total sum of the Hammett sigma(para) values of the substituents on the 1-aryl ring is 0.51 or less, the ETA being bonded to L or CAR1 through either the nitrogen atom in the 2-position or the oxygen attached to the 3-position of the pyrazolidinone ring; and a development accelerator releasing compound represented by the formula (II): CAR2—(SAM)—NX1—NX2X3  (II) wherein: CAR2 is a carrier moiety which is capable of releasing —(SAM)—NX1—NX2X3 on reaction with oxidized developing agent; SAM is a silver absorbable moiety attached to the carrier moiety and is released on reaction with oxidized development agent; and —NX1—NX2X3 is a hydrazine group wherein X1, X2 and X3 are individually hydrogen or a substituent chosen from alkyl, aryl, carbonyl or sulfonyl groups with the proviso that at least one of X1, X2 and X3 is hydrogen.

Abstract translation: 本发明涉及一种照相元件，其中包含支持体和至少两个卤化银乳剂层，还包含由式（I）表示的电子转移剂释放化合物：其中：CAR 1是能够释放的载体部分 - （L）n-ETA与氧化显影剂反应; L为二价连接基团，n为0,1或2; 和ETA是具有大于或等于2.40的计算对数分配系数（c log P）的可释放的1-芳基-3-吡唑烷酮电子转移剂，并且1-位的取代基的哈米特σ（对）值的总和， 芳基环为0.51以下，ETA通过2位的氮原子或与吡唑烷酮环的3位相连的氧键连接至L或CAR 1;以及由吡唑烷酮环的3位表示的显影促进剂释放化合物 式（II）：其中：CAR 2是能够与氧化显影剂反应释放 - （SAM）-NX 1 -XX 2 X 3的载体部分; SAM是银 与载体部分连接的可吸收部分，与氧化显影剂反应释放; 和-X 1 -NX 2 X 3是其中X 1，X 2和X 3独立地为氢或选自烷基，芳基，羰基或磺酰基的取代基的肼基团 条件是X 1，X 2和X 3中的至少一个是氢。

公开(公告)号：US06518008B1

公开(公告)日：2003-02-11

申请号：US09236818

申请日：1999-01-25

Applicant: James A. Friday ,  Roger A. Bryant ,  Annabel A. Muenter ,  Jerome R. Lenhard

Inventor： James A. Friday ,  Roger A. Bryant ,  Annabel A. Muenter ,  Jerome R. Lenhard

IPC: G03C108

CPC classification number: G03C1/10 ,  G03C1/0051 ,  G03C7/3022 ,  G03C7/392 ,  G03C2200/24

Abstract: A multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said silver halide emulsion layers contains a tabular grain silver halide emulsion having a halide content of at least 95% bromide and less than about 5% iodide, said iodide being substantially uniformly distributed in the silver halide grains of said emulsion, and said emulsion is sensitized with a fragmentable electron donor of the formula X—Y′ or an electron donor which contains an —XY′ moiety; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, &bgr;−, is covalently linked directly or indirectly to X, and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X—Y′ fragments to give the radical X* and the leaving fragment Y′;  and, optionally, 3) the radical X* has an oxidation potential

Abstract translation: 一种多色照相元件，其特征在于，包含支持青色染料成像单元的载体，所述载体包括至少一种与其相关联的至少一种形成青色染料的成色剂的红色感光卤化银乳剂层，品红色染料影像形成单元包括至少一种绿色 具有与至少一种品红色染料形成成色剂相关联的感光卤化银乳剂层，黄色染料成像单元，其包含至少一种感蓝卤化银乳剂层，其具有至少一种形成黄色染料的成色剂，其中在 所述卤化银乳剂层中的至少一种含有卤化物含量为至少95％溴化物和小于约5％碘化物的片状粒状卤化银乳剂，所述碘化物基本均匀地分布在所述乳液的卤化银颗粒中，所述 用式XY'的可裂解电子给体或含有-XY'部分的电子给体使乳液敏化; 其中X是电子给体部分，Y'是离开质子H或离去基团Y，条件是如果Y'是质子，则碱，β - 与X直接或间接共价连接，并且其中：1 ）XY'具有介于0和约1.4V之间的氧化电位; 和2）X-Y'片段的氧化形式，得到基团X *和离去片段Y'; 和任选地，3）基团X *具有<-0.7V的氧化电位。

公开(公告)号：US06509144B1

公开(公告)日：2003-01-21

申请号：US09236821

申请日：1999-01-25

Applicant: Kenneth J. Reed ,  Joseph P. Pepe ,  James A. Friday ,  Jon N. Eikenberry ,  Yun C. Chang ,  Annabel A. Muenter ,  Jerome R. Lenhard

Inventor： Kenneth J. Reed ,  Joseph P. Pepe ,  James A. Friday ,  Jon N. Eikenberry ,  Yun C. Chang ,  Annabel A. Muenter ,  Jerome R. Lenhard

IPC: G03C110

CPC classification number: G03C1/10 ,  G03C1/0053 ,  G03C1/28 ,  G03C1/29

Abstract: This invention comprises a photographic element comprising a support and at least one blue sensitive silver halide emulsion layer containing a tabular grain silver halide emulsion, or an emulsion in which the halide content is at least 50% chloride and no more than 5% iodide, wherein the emulsion is spectrally sensitized with at least one dye providing a peak sensitization between 446 and 500 nm and at least one dye providing a peak sensitization between 400 and 445 nm and additionally sensitized with a fragmentable electron donor of the formula: X—Y′. or an electron donor which contains an —XY′ moiety; wherein X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is H a base, &bgr;−, is covalently linked directly or indirectly to X. and wherein: 1) X—Y′ has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X—Y′ fragments to give the radical X• and the leaving fragment Y′; and, optionally, 3) the radical X• has an oxidation potential ≦−0.7V (that is, equal to or more negative than about −0.7 V).

Abstract translation: 本发明包括一种照相元件，其包括载体和至少一种含有片状银卤化银乳剂的蓝色感光卤化银乳剂层，或其中卤化物含量为至少50％氯化物和不超过5％碘化物的乳液，其中 该乳液用至少一种提供446和500nm之间的峰敏感的染料和至少一种提供400和445nm之间的峰敏感的染料进行光谱增感，并用下式X-Y'的可裂解的电子给体进一步增感。 或含有-XY'部分的电子给体;其中X是电子给体部分，Y'是离开质子H或离去基团Y，条件是如果Y'是H，则基团是共价连接的 直接或间接地与X并且其中：1）XY'具有介于0和约1.4V之间的氧化电位; 和2）X-Y'片段的氧化形式，得到X基团和离去片段Y'; 和任选地，3）基团X的氧化电位<= -0.7V（即等于或大于约-0.7V的负）。

公开(公告)号：US06426180B1

公开(公告)日：2002-07-30

申请号：US09690569

申请日：2000-10-17

Applicant: Joseph F. Bringley ,  James A. Friday ,  Stephen P. Singer ,  Marcello Vitale

Inventor： Joseph F. Bringley ,  James A. Friday ,  Stephen P. Singer ,  Marcello Vitale

IPC: G03C106

CPC classification number: G03C7/3924 ,  G03C7/3005 ,  G03C7/30558 ,  Y10S430/156

Abstract: Disclosed is a color silver halide photographic element comprising a support bearing: (1) a light sensitive silver halide emulsion layer; (2) a nitrogen heterocycle with a minimum of three heteroatoms that does not react with oxidized developer, does not contain free thiol substituents, and has a C log P sufficient to increase the photographic speed of said element compared to the same element without the compound, said heterocycle compound located either in said light sensitive layer or in a layer adjacent to it; and (3) an ETARC, in or adjacent to said light sensitive silver halide emulsion layer, that releases, upon reaction with oxidized developer, an electron transfer agent having a C log P of at least 2.40. The invention provides improved light sensitivity.

Abstract translation: 公开了一种彩色卤化银照相元件，其包括载体：（1）感光卤化银乳剂层;（2）具有至少三个不与氧化显影剂反应的杂原子的氮杂环不含游离硫醇取代基 并且具有足够增加所述元件的照相速度的C log P，与没有化合物的相同元素相比，所述杂环化合物位于所述光敏层中或位于与其相邻的层中; 和（3）在所述感光卤化银乳剂层中或其附近的ETARC，其与氧化显影剂反应时释放具有至少2.40的C log P的电子转移剂。 本发明提供了改善的光敏度。

公开(公告)号：US06350565B1

公开(公告)日：2002-02-26

申请号：US09690230

申请日：2000-10-17

Applicant: Joseph F. Bringley ,  James A. Friday ,  Marcello Vitale

Inventor： Joseph F. Bringley ,  James A. Friday ,  Marcello Vitale

IPC: G03C146

CPC classification number: G03C7/3029 ,  G03C2007/3032 ,  G03C2007/3037 ,  G03C2200/35

Abstract: A color photographic element containing a support bearing: (a) a red record comprising, in order from the support, a less and a more red light sensitive silver halide emulsion layer, each having associated therewith at least one cyan dye-forming coupler; (b) further from the support a green record comprising, in order from the support, a less and a more green light sensitive silver halide emulsion layer, each having associated therewith at least one magenta dye-forming coupler, and (c) still further from the support, a blue record comprising in order from the support, a less and a more blue light sensitive silver halide emulsion layer, each having associated therewith at least one yellow dye-forming coupler; wherein: (d) there is located below and only below the most red light sensitive layer of the red record a relatively non-light sensitive “small 3-D emulsion layer” that is substantially free of red light absorbing dye.

Abstract translation: 一种含有载体轴承的彩色照相元件：（a）一个红色记录，其中从支持体的顺序依次包括一个较少和一个更多的红色感光卤化银乳剂层，每一个都与其中至少一个青色染料成色剂相关联;（ b）从支持体进一步的绿色记录，包括从支持的顺序，包含少于一个更绿和更绿的感光卤化银乳剂层，每一个都具有与其相关联的至少一种品红色染料形成成色剂，和（c） 支持体，蓝色记录，从载体的顺序包括较少和更多的蓝色感光卤化银乳剂层，每一个都具有至少一个形成黄色染料的成色剂;其中：（d）位于下方且仅存在 在红色记录的最红色光敏层之下，基本上不含红光吸收染料的相对非光敏的“小3-D乳剂层”。

公开(公告)号：US6090536A

公开(公告)日：2000-07-18

申请号：US213739

申请日：1998-12-17

Applicant: Joe E. Maskasky ,  Kenneth J. Reed ,  Victor P. Scaccia ,  James A. Friday

Inventor： Joe E. Maskasky ,  Kenneth J. Reed ,  Victor P. Scaccia ,  James A. Friday

IPC: G03C7/00 ,  G03C1/005 ,  G03C1/035 ,  G03C1/04 ,  G03C1/08 ,  G03C1/10 ,  G03C1/12 ,  G03C1/047 ,  G03C1/09

CPC classification number: G03C1/10 ,  G03C1/0051 ,  G03C1/04 ,  G03C1/12 ,  G03C2200/24

Abstract: A photographic emulsion is disclosed containing for enhanced imaging speed high bromide {111} tabular grain emulsion peptizer with a cationic starch and sensitized with a fragmentable electron donating sensitizer. The photographic emulsion is disclosed for use in black-and-white and color photographic elements.

Abstract translation: 公开了一种照相乳剂，其包含用于具有阳离子淀粉的增强成像速度的高溴酸盐{111}片状颗粒乳剂胶溶剂，并且用可裂解的电子给体敏化剂敏化。 公开了用于黑白和彩色照相元件的照相乳剂。

公开(公告)号：US4148642A

公开(公告)日：1979-04-10

申请号：US884469

申请日：1978-03-07

Applicant: Derek D. Chapman ,  James A. Friday ,  James K. Elwood

Inventor： Derek D. Chapman ,  James A. Friday ,  James K. Elwood

IPC: C09B45/00 ,  G03C8/10 ,  G03C1/40 ,  G03C1/10 ,  G03C5/54 ,  G03C7/00

CPC classification number: C09B45/00 ,  G03C8/10

Abstract: Photographic elements, diffusion transfer assemblages and processes are described which employ a novel nondiffusible compound having a releasable 1-arylazo-4-isoquinolinol dye moiety. The compound contains:(a) in the ortho position of the arylazo moiety a metal chelating group, a salt thereof or a hydrolyzable precursor thereof; and(b) a ballasted carrier moiety which is capable of releasing the diffusible azo dye under alkaline conditions. The dye is transferred imagewise to an image-receiving layer where it is contacted with metal ions to form a metal-complexed azo dye transfer image of excellent stability.

Abstract translation: 描述了摄影元件，扩散转移组合和方法，其使用具有可释放的1-芳基偶氮-4-异喹啉酮染料部分的新型不扩散化合物。 该化合物包含：

公开(公告)号：US06893809B2

公开(公告)日：2005-05-17

申请号：US10244569

申请日：2002-09-16

Applicant: Kenneth J. Reed ,  James A. Friday ,  John E. Keevert ,  Stephen P. Singer ,  Mary C. Brick

Inventor： Kenneth J. Reed ,  James A. Friday ,  John E. Keevert ,  Stephen P. Singer ,  Mary C. Brick

IPC: G03C1/035 ,  G03C1/04 ,  G03C1/43 ,  G03C7/00 ,  G03C7/30 ,  G03C7/305 ,  G03C7/333 ,  G03C1/46

CPC classification number: G03C7/30541 ,  G03C1/0051 ,  G03C1/04 ,  G03C7/3022 ,  G03C7/3029 ,  G03C7/3041 ,  G03C7/30594 ,  G03C7/333 ,  G03C2007/3032 ,  G03C2007/3034 ,  G03C2200/38 ,  G03C2200/53 ,  Y10S430/156

Abstract: This invention relates to a negative silver halide photographic element comprising a support and a silver halide imaging layer containing a light sensitive silver halide imaging emulsion, said silver halide imaging layer further comprising a separately precipitated non-imaging intentionally fogged fine grain emulsion and an electron transfer agent releasing compound represented by formula (I): CAR1-(L)n-ETA  (I) wherein: CAR1 is a carrier moiety which is capable of releasing -(L)n-ETA on reaction with oxidized developing agent; L is a divalent linking group, n is 0, 1 or 2; and ETA is a releasable electron transfer agent, and (optionally) a development accelerator releasing compound represented by the formula (II): CAR2—(SAM)-NX1—NX2X3  (II) wherein: CAR2 is a carrier moiety which is capable of releasing —(SAM)-NX1—NX2X3 on reaction with oxidized developing agent; SAM is a silver absorbable moiety attached to the carrier moiety and is released on reaction with oxidized development agent; and —NX1—NX2X3 is a hydrazine group wherein X1, X2 and X3 are individually hydrogen or a substituent chosen from alkyl, aryl, carbonyl, or sulfonyl groups with the proviso that at least one of X1, X2 and X3 is hydrogen.