公开(公告)号：US5767222A

公开(公告)日：1998-06-16

申请号：US127907

申请日：1993-09-29

Applicant: Edward S. Lipinsky ,  Richard G. Sinclair ,  James D. Browning ,  Alex Cheung ,  Kevin H. Schilling ,  Dan W. Verser

Inventor： Edward S. Lipinsky ,  Richard G. Sinclair ,  James D. Browning ,  Alex Cheung ,  Kevin H. Schilling ,  Dan W. Verser

IPC: A61L15/26 ,  A61L15/62 ,  C07D319/12 ,  C08G63/06 ,  C08G63/08 ,  C08G63/664 ,  C08G69/44 ,  C08J5/18 ,  C08K3/00 ,  C08K5/00 ,  C08K5/101 ,  C08L53/00 ,  C08L57/00 ,  C08L67/00 ,  C08L67/04 ,  C08L101/00 ,  C09D167/00 ,  C09D167/04 ,  C09D177/00 ,  C09D177/12 ,  C09J167/00 ,  C09J167/04 ,  C09J177/00 ,  C09J177/12 ,  D21H17/53 ,  C07D323/04 ,  C07D321/112

CPC classification number: C08J5/18 ,  A61L15/26 ,  A61L15/62 ,  C07D319/12 ,  C08G63/664 ,  C08G69/44 ,  C08K3/0025 ,  C08K5/0033 ,  C08K5/101 ,  C08L101/00 ,  C08L53/00 ,  C08L57/00 ,  C08L67/00 ,  C08L67/04 ,  C09D167/04 ,  C09J167/04 ,  D21H17/53 ,  B01J2219/1942 ,  C08G2230/00 ,  C08J2367/04 ,  Y10S521/916

Abstract: Disclosed are degradable materials including molded products, laminates, foams, nonwoven materials, adhesives, coatings and films, and particularly packaging films. The materials are made using polydioxaneone polymers comprising at least two different dioxaneone-based repeating units. Preferred polymers are polydioxanediones. First repeating units have less carbon atoms in constituent groups extending from the polymer backbone than second repeating units. Physical characteristics and degradation of the materials can be varied by varying the choice and/or relative proportions of first and second repeating units in the polydioxaneone polymers. Methods for preparing polydioxaneone polymers that can be used in the manufacture of the materials are also discussed, as are suitable monomers and methods for preparing such monomers.

公开(公告)号：US5444113A

公开(公告)日：1995-08-22

申请号：US128520

申请日：1993-09-29

Applicant: Richard G. Sinclair ,  Edward S. Lipinsky ,  James D. Browning ,  Donald Bigg ,  Thomas A. Rogers

Inventor： Richard G. Sinclair ,  Edward S. Lipinsky ,  James D. Browning ,  Donald Bigg ,  Thomas A. Rogers

IPC: A61L15/26 ,  A61L15/62 ,  C08G63/08 ,  C08J5/18 ,  C08K5/10 ,  C08K5/101 ,  C08L53/00 ,  C08L57/00 ,  C08L67/00 ,  C08L67/04 ,  C08L101/00 ,  C09D167/04 ,  C09J167/00 ,  C09J167/04 ,  D21H17/53

CPC classification number: C08J5/18 ,  A61L15/26 ,  A61L15/62 ,  C08G63/08 ,  C08K5/10 ,  C08K5/101 ,  C08L101/00 ,  C08L53/00 ,  C08L57/00 ,  C08L67/00 ,  C08L67/04 ,  C09D167/04 ,  C09J167/00 ,  C09J167/04 ,  D21H17/53 ,  B01J2219/1942 ,  C08J2367/04

Abstract: Disclosed are products made of degradable materials which include a hydrolytically degradable polymer. The degradable materials can be internally or externally modified. The internally modified polymer composition has polymers modified by the use of comonomers having a relatively high molecular weight. The externally modified polymer composition includes a modifier, wherein the modifier is compatible with the polymer and the modifier is nontoxic, nonvolatile and nonfugitive. The various degradable materials include films, fibers, extruded and molded products, laminates, foams, powders, nonwovens, adhesives and coatings. The disclosed materials are particularly useful for the production of a variety of products in high volumes which are suitable for recycling after use or which are discarded into the environment in large volumes.

Abstract translation: 本发明公开了包含可降解水解聚合物的可降解材料制成的产品。 可降解材料可以在内部或外部改性。 内部改性的聚合物组合物具有通过使用具有相对较高分子量的共聚单体改性的聚合物。 外部改性的聚合物组合物包括改性剂，其中改性剂与聚合物相容，改性剂是无毒的，非挥发性的和非挥发性的。 各种可降解材料包括膜，纤维，挤出和模制产品，层压材料，泡沫，粉末，无纺布，粘合剂和涂料。 所公开的材料特别适用于大量生产各种适用于使用后再循环或大量排放到环境中的产品。

公开(公告)号：US08378010B2

公开(公告)日：2013-02-19

申请号：US12529360

申请日：2008-03-10

Applicant: James D. Browning ,  Bhima R. Vijayendran

Inventor： James D. Browning ,  Bhima R. Vijayendran

IPC: C08L89/00 ,  C08L31/00 ,  C09J189/00

CPC classification number: C08F2/24

Abstract: A method of forming a stable latex polymer emulsion is provided which includes mixing one or more monomers including polymerizable acid monomers, esters, and unsaturated monomers with water and a soy protein. The emulsion is then polymerized and may be formed into adhesive compositions having improved water resistance and mechanical strength.

Abstract translation: 提供了形成稳定的胶乳聚合物乳液的方法，其包括将一种或多种包括可聚合酸单体，酯和不饱和单体的单体与水和大豆蛋白混合。 然后将乳液聚合，并且可以形成具有改善的耐水性和机械强度的粘合剂组合物。

公开(公告)号：US5556895A

公开(公告)日：1996-09-17

申请号：US455990

申请日：1995-05-31

Applicant: Edward S. Lipinsky ,  Richard G. Sinclair ,  James D. Browning ,  Alex Cheung ,  Kevin H. Schilling ,  Dan W. Verser

Inventor： Edward S. Lipinsky ,  Richard G. Sinclair ,  James D. Browning ,  Alex Cheung ,  Kevin H. Schilling ,  Dan W. Verser

IPC: A61L15/26 ,  A61L15/62 ,  C07D319/12 ,  C08G63/06 ,  C08G63/08 ,  C08G63/664 ,  C08G69/44 ,  C08J5/18 ,  C08K3/00 ,  C08K5/00 ,  C08K5/101 ,  C08L53/00 ,  C08L57/00 ,  C08L67/00 ,  C08L67/04 ,  C08L101/00 ,  C09D167/00 ,  C09D167/04 ,  C09D177/00 ,  C09D177/12 ,  C09J167/00 ,  C09J167/04 ,  C09J177/00 ,  C09J177/12 ,  D21H17/53 ,  C08J9/00

CPC classification number: C08J5/18 ,  A61L15/26 ,  A61L15/62 ,  C07D319/12 ,  C08G63/664 ,  C08G69/44 ,  C08K3/0025 ,  C08K5/0033 ,  C08K5/101 ,  C08L101/00 ,  C08L53/00 ,  C08L57/00 ,  C08L67/00 ,  C08L67/04 ,  C09D167/04 ,  C09J167/04 ,  D21H17/53 ,  B01J2219/1942 ,  C08G2230/00 ,  C08J2367/04 ,  Y10S521/916

Abstract: Disclosed are degradable materials including molded products, laminates, foams, nonwoven materials, adhesives, coatings and films, and particularly packaging films. The materials are made using polydioxaneone polymers comprising at least two different dioxaneone-based repeating units. Preferred polymers are polydioxanediones. First repeating units have less carbon atoms in constituent groups extending from the polymer backbone than second repeating units. Physical characteristics and degradation of the materials can be varied by varying the choice and/or relative proportions of first and second repeating units in the poldioxaneone polymers. Methods for preparing polydioxaneone polymers that can be used in the manufacture of the materials are also discussed, as are suitable monomers and methods for preparing such monomers.

Abstract translation: 公开了可降解材料，包括模制产品，层压材料，泡沫，非织造材料，粘合剂，涂料和薄膜，特别是包装薄膜。 所述材料是使用包含至少两种不同的腙类重复单元的聚二恶烷酮聚合物制成的。 优选的聚合物是聚二氧杂乙二酮。 第一重复单元在比聚合物主链延伸的组成基团中的碳原子少于第二重复单元。 材料的物理特性和降解可以通过改变聚二恶烷酮聚合物中第一和第二重复单元的选择和/或相对比例来改变。 还可以讨论制备可用于制备材料的聚二恶烷酮聚合物的方法，以及合适的单体和制备这种单体的方法。

公开(公告)号：US5001290A

公开(公告)日：1991-03-19

申请号：US467332

申请日：1990-01-19

Applicant: Melville Hillman ,  James D. Browning

Inventor： Melville Hillman ,  James D. Browning

IPC: B01J8/02 ,  B01J27/128 ,  C07C17/12

CPC classification number: B01J27/128 ,  B01J8/0278 ,  C07C17/12

Abstract: A method for producing p-dichlorobenzene using a reactor containing a catalyst/reagent to convert chlorobenzene (or benzene) to p-dichlorobenzene, the reactor having an inlet and an outlet for introducing reactants and removing product; introducing a pulse of gaseous chlorobenzene (or benzene) into the reactor and reacting the chlorobenzene with the catalyst/reagent whereby p-dichlorobenzene is formed; introducing a pulse of inert gas into the reactor; introducing a pulse of gaseous chlorine into the reactor and reacting the chlorine with the catalyst/reagent; introducing a pulse of inert gas into the reactor; repeating the pulsing steps in a sequential manner, whereby mixing of the vaporized benzene or chlorobenzene, and the chlorine gas is prevented; and continuously removing product containing p-dichlorobenzene from the outlet of the reactor.

Abstract translation: 使用含有催化剂/试剂以将氯苯（或苯）转化为对二氯苯的反应器生产对二氯苯的方法，所述反应器具有用于引入反应物和除去产物的入口和出口; 向反应器中引入气态氯苯（或苯）的脉冲，并使氯苯与形成对二氯苯的催化剂/试剂反应; 将惰性气体脉冲引入反应器; 向反应器中引入气态氯脉冲，并使氯与催化剂/试剂反应; 将惰性气体脉冲引入反应器; 以顺序的方式重复脉冲步骤，从而防止蒸发的苯或氯苯与氯气的混合; 并从反应器的出口连续地除去含有对二氯苯的产物。