公开(公告)号：US07057880B2

公开(公告)日：2006-06-06

申请号：US10834005

申请日：2004-04-29

申请人： Masato Kurosaki ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Yuuji Nakagawa ,  Shinya Yoshida ,  Tomoki Nobuta ,  Masaya Mitani

发明人： Masato Kurosaki ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Yuuji Nakagawa ,  Shinya Yoshida ,  Tomoki Nobuta ,  Masaya Mitani

IPC分类号： H01G9/04 ,  H01G9/145

CPC分类号： H01G9/155 ,  H01G9/22 ,  H01G11/02 ,  H01G11/42 ,  H01M4/137 ,  H01M4/60 ,  H01M4/606 ,  H01M4/608 ,  H01M10/05 ,  H01M10/36 ,  Y02E60/13

摘要： The present invention provides a secondary battery and a capacitor which may provide an excellent high rate and cycle characteristic as well as sufficient electromotive force and capacity. The secondary battery and a capacitor have an active material of an electrode comprising a trimer compound comprising three units of indole or indole derivatives in condensed ring form, wherein the second position and the third position of each unit form a six-membered ring, and a proton which can be utilized as a charge carrier of the trimer compound.

公开(公告)号：US06869731B2

公开(公告)日：2005-03-22

申请号：US10271636

申请日：2002-10-15

申请人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuji Nakagawa ,  Shinako Kaneko ,  Masaya Mitani

发明人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuji Nakagawa ,  Shinako Kaneko ,  Masaya Mitani

IPC分类号： H01G9/02 ,  H01G11/02 ,  H01G11/08 ,  H01G11/22 ,  H01G11/48 ,  H01G11/52 ,  H01G11/54 ,  H01G11/58 ,  H01M4/60 ,  H01M6/04 ,  H01M10/05 ,  H01M10/36 ,  H01M10/42

CPC分类号： H01G9/038 ,  H01G9/028 ,  H01G11/48 ,  H01G11/58 ,  H01G11/64 ,  H01M4/60 ,  H01M4/602 ,  H01M6/045 ,  H01M10/36 ,  H01M10/4235 ,  H01M2300/0011 ,  Y02E60/13

摘要： The present invention relates to an electrolytic solution comprising an aqueous solution of an organic or inorganic acid whereto a water-soluble N-containing heterocyclic compound is added, and an electrochemical cell such as a secondary battery and an electric double layer capacitor that uses such an electrolytic solution.

摘要翻译： 本发明涉及一种电解液，其包含添加了水溶性含氮杂环化合物的有机或无机酸的水溶液，以及使用这样的二价电池和双电层电容器的电化学电池 电解液。

公开(公告)号：US06800395B2

公开(公告)日：2004-10-05

申请号：US09986791

申请日：2001-11-13

申请人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuuji Nakagawa ,  Shinya Yoshida ,  Masaya Mitani

发明人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuuji Nakagawa ,  Shinya Yoshida ,  Masaya Mitani

IPC分类号： H01M460

CPC分类号： H01M4/608 ,  H01M4/137 ,  H01M4/60 ,  H01M4/62 ,  H01M4/622 ,  H01M10/36 ,  H01M2300/0005 ,  H01M2300/0011

摘要： A secondary battery of a proton conductive polymer, wherein a positive electrode and a negative electrode are arranged facing to each other via a separator in an electrolyte and only a proton or a proton of a hydroxyl group in an indole trimer and a &pgr; conjugated polymer, i.e., an active material of electrode in the positive electrode and in the negative electrode participates in a charge/discharge, and a proton concentration is 5 to 40% and an anion concentration is 30 to 60% in the solution, respectively, and the anion concentration is at least higher than the proton concentration.

摘要翻译： 质子传导性聚合物的二次电池，其中正电极和负极通过电解质中的隔膜彼此面对，并且仅吲哚三聚体中的羟基的质子或质子和π共轭聚合物， 即，正极和负极中的电极的活性物质分别参与充放电，溶液中的质子浓度为5〜40％，阴离子浓度为30〜60％，阴离子 浓度至少高于质子浓度。

公开(公告)号：US07205071B2

公开(公告)日：2007-04-17

申请号：US10365550

申请日：2003-02-13

申请人： Shinako Kaneko ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Masaya Mitani ,  Masato Kurosaki ,  Tomoki Nobuta ,  Yuji Nakagawa

发明人： Shinako Kaneko ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Masaya Mitani ,  Masato Kurosaki ,  Tomoki Nobuta ,  Yuji Nakagawa

IPC分类号： H01M4/58 ,  H01M4/60

CPC分类号： H01G9/155 ,  H01M4/60 ,  H01M4/608 ,  Y02E60/13

摘要： A secondary battery and capacitor includes as an active material of an electrode a compound having a trimer structure comprising three structure units of one or more kind of indole compounds selected from indole and indole derivatives and a condensed polycyclic structure having a six-membered ring composed of atoms of the second and the third position of the each three structure units, wherein the active material comprises as the compound a first compound having a trimer structure wherein any bonds between the structure units are formed among the second position of one structure unit and the third position of the other structure unit and a second compound having a trimer structure comprising a bond formed among the second position of one structure unit and the second position of the other structure unit, and a proton is utilized as a charge carrier of the first compound and the second compound.

摘要翻译： 二次电池和电容器包括作为电极的活性材料，具有三聚体结构的化合物，所述三聚体结构包含三种选自吲哚和吲哚衍生物的一种或多种吲哚化合物的结构单元和具有六元环的缩合多环结构，所述六元环由 每个三个结构单元的第二和第三位置的原子，其中活性材料包含作为化合物的具有三聚体结构的第一化合物，其中在一个结构单元的第二位置和第三个结构单元之间形成结构单元之间的任何键 另一个结构单元的位置和具有包含在一个结构单元的第二位置和另一个结构单元的第二位置之间形成的键的三聚体结构的第二化合物和质子被用作第一化合物的电荷载体， 第二种化合物。

公开(公告)号：US20050185247A1

公开(公告)日：2005-08-25

申请号：US11014911

申请日：2004-12-20

申请人： Hideo Ooi ,  Naoto Yazawa ,  Masaya Mitani ,  Tomoki Nobuta ,  Toshihiko Nishiyama ,  Tetuya Yoshinari ,  Naoki Takahashi

发明人： Hideo Ooi ,  Naoto Yazawa ,  Masaya Mitani ,  Tomoki Nobuta ,  Toshihiko Nishiyama ,  Tetuya Yoshinari ,  Naoki Takahashi

IPC分类号： C07D487/14 ,  C07D519/00 ,  G02F1/03 ,  H01M4/60

CPC分类号： C07D487/14 ,  H01M4/60 ,  H01M4/608

摘要： The present invention provides a novel indole carboxylic ester trimer which is characterized by being represented by the following general formula (1): wherein R represents a straight or branched chain alkyl group having 1-6 carbon atoms; n is an integer of 1-4; Xa− represents at least one anion selected from a group of anions having a valency of 1-3 consisting of chloride ion, bromide ion, iodide ion, fluoride ion, nitrate ion, sulfate ion, hydrogen sulfate ion, phosphate ion, borofluoride ion, perchlorate ion, thiocyanate ion, acetic acid ion, propionic acid ion, methanesulfonic acid ion, p-toluenesulfonic acid ion, trifluoroacetic acid ion and trifluoromethanesulfonic acid ion; a represents the ionic valence number of X and is an integer of 1-3; and m is 0-0.5.

摘要翻译： 本发明提供一种新颖的吲哚羧酸酯三聚体，其特征在于由以下通式（1）表示：其中R表示具有1-6个碳原子的直链或支链烷基; n为1-4的整数; 代表从氯离子，溴离子，碘离子，氟离子，硝酸根离子，硫酸根离子，硫酸氢盐等离子体中选出的化合价1-3的阴离子中的至少一种阴离子 离子，磷酸根离子，氟硼酸离子，高氯酸根离子，硫氰酸根离子，乙酸离子，丙酸离子，甲磺酸离子，对甲苯磺酸离子，三氟乙酸离子和三氟甲磺酸离子; a表示X的离子价数，为1-3的整数; m为0〜0.5。

公开(公告)号：US20050178659A1

公开(公告)日：2005-08-18

申请号：US11051344

申请日：2005-02-04

申请人： Naoki Takahashi ,  Toshihiko Nishiyama ,  Tomoki Nobuta ,  Masaya Mitani ,  Tetsuya Yoshinari

发明人： Naoki Takahashi ,  Toshihiko Nishiyama ,  Tomoki Nobuta ,  Masaya Mitani ,  Tetsuya Yoshinari

IPC分类号： C08G61/12 ,  C08G73/06 ,  C08J5/22 ,  C25B11/04 ,  H01B1/12 ,  H01M4/60 ,  H01M10/36

CPC分类号： C08J5/2256 ,  C08G61/124 ,  C08G73/0672 ,  C08J2361/20 ,  H01M4/137 ,  H01M4/60 ,  H01M4/608

摘要： The present invention relates to a copolymer compound prepared by copolymerizing two or more monomers selected from indole and indole derivatives. The copolymer compound can be used as an electrode active material to provide an electrochemical cell with an increased capacity and improved cycle properties.

摘要翻译： 本发明涉及通过共聚选自吲哚和吲哚衍生物的两种或更多种单体制备的共聚物化合物。 共聚物化合物可以用作电极活性材料，以提供具有增加的容量和改善循环性能的电化学电池。

公开(公告)号：US20050165214A1

公开(公告)日：2005-07-28

申请号：US11042900

申请日：2005-01-25

申请人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Masaya Mitani ,  Naoki Takahashi ,  Tetsuya Yoshinari

发明人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Masaya Mitani ,  Naoki Takahashi ,  Tetsuya Yoshinari

IPC分类号： C08G81/00 ,  C08G61/12 ,  C08G73/00 ,  H01B1/12 ,  H01G9/00 ,  H01G9/025 ,  H01G9/22 ,  H01G11/02 ,  H01G11/30 ,  H01G11/48 ,  H01G11/56 ,  H01G11/86 ,  H01M4/60 ,  H01M10/36

CPC分类号： H01M4/137 ,  C08G73/08 ,  C08G73/18 ,  H01B1/122 ,  H01G9/058 ,  H01G9/22 ,  H01G11/02 ,  H01G11/48 ,  H01M4/60 ,  H01M4/608 ,  Y02E60/13

摘要： This invention relates to a polymer having a chain structure of a repeating unit of a proton-conducting compound which causes an electrochemical redox reaction in a solution of a proton source to act as an electrode active material, and a heterocyclic compound structure; and an electrochemical cell comprising the polymer as an electrode active material.

摘要翻译： 本发明涉及具有质子传导性化合物的重复单元的链结构的聚合物，该质子传导性化合物在质子源的溶液中产生电化学氧化还原反应，作为电极活性物质，以及杂环化合物结构; 以及包含聚合物作为电极活性材料的电化学电池。

公开(公告)号：US06899974B2

公开(公告)日：2005-05-31

申请号：US09985272

申请日：2001-11-02

申请人： Hiroyuki Kamisuki ,  Toshihiko Nishiyama ,  Gaku Harada ,  Shinya Yoshida ,  Masato Kurosaki ,  Yuuji Nakagawa ,  Tomoki Nobuta ,  Masaya Mitani

发明人： Hiroyuki Kamisuki ,  Toshihiko Nishiyama ,  Gaku Harada ,  Shinya Yoshida ,  Masato Kurosaki ,  Yuuji Nakagawa ,  Tomoki Nobuta ,  Masaya Mitani

IPC分类号： H01M2/16 ,  H01M4/60 ,  H01M10/36

CPC分类号： H01M10/36 ,  H01M2/1653 ,  H01M4/60 ,  H01M4/602

摘要： A secondary battery of a proton conductive polymer, wherein a positive electrode 2 and a negative electrode 4 are arranged facing to each other via a separator in an electrolytic solution and only a proton in a π conjugated polymer or a proton of a hydroxyl group in a hydroxyl-containing macromolecular as an active material of an electrode in the positive and negative electrodes participates in a charge/discharge; the secondary battery uses a membrane, which has acid resistance, oxidation resistance and a functional group having cation exchange function, as the separator 3.

摘要翻译： 质子传导性聚合物的二次电池，其中正电极2和负电极4经电解液中的隔膜相互排列，仅在π共轭聚合物中的质子或羟基的质子 含羟基的大分子作为正极和负极中的电极的活性材料参与充电/放电; 二次电池使用具有耐酸性，抗氧化性的膜和具有阳离子交换功能的官能团作为隔膜3。

公开(公告)号：US07255779B2

公开(公告)日：2007-08-14

申请号：US11014911

申请日：2004-12-20

申请人： Hideo Ooi ,  Naoto Yazawa ,  Masaya Mitani ,  Tomoki Nobuta ,  Toshihiko Nishiyama ,  Tetuya Yoshinari ,  Naoki Takahashi

发明人： Hideo Ooi ,  Naoto Yazawa ,  Masaya Mitani ,  Tomoki Nobuta ,  Toshihiko Nishiyama ,  Tetuya Yoshinari ,  Naoki Takahashi

IPC分类号： C25B11/04

CPC分类号： C07D487/14 ,  H01M4/60 ,  H01M4/608

摘要： The present invention provides a novel indole carboxylic ester trimer which is characterized by being represented by the following general formula (1): wherein R represents a straight or branched chain alkyl group having 1-6 carbon atoms; n is an integer of 1-4; Xa− represents at least one anion selected from a group of anions having a valency of 1-3 consisting of chloride ion, bromide ion, iodide ion, fluoride ion, nitrate ion, sulfate ion, hydrogen sulfate ion, phosphate ion, borofluoride ion, perchlorate ion, thiocyanate ion, acetic acid ion, propionic acid ion, methanesulfonic acid ion, p-toluenesulfonic acid ion, trifluoroacetic acid ion and trifluoromethanesulfonic acid ion; a represents the ionic valence number of X and is an integer of 1-3; and m is 0-0.5.

摘要翻译： 本发明提供一种新颖的吲哚羧酸酯三聚体，其特征在于由以下通式（1）表示：其中R表示具有1-6个碳原子的直链或支链烷基; n为1-4的整数; 代表从氯离子，溴离子，碘离子，氟离子，硝酸根离子，硫酸根离子，硫酸氢盐等离子体中选出的化合价1-3的阴离子中的至少一种阴离子 离子，磷酸根离子，氟硼酸离子，高氯酸根离子，硫氰酸根离子，乙酸离子，丙酸离子，甲磺酸离子，对甲苯磺酸离子，三氟乙酸离子和三氟甲磺酸离子; a表示X的离子价数，为1-3的整数; m为0〜0.5。

公开(公告)号：US20050135045A1

公开(公告)日：2005-06-23

申请号：US11050958

申请日：2005-02-04

申请人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuji Nakagawa ,  Shinako Kaneko ,  Masaya Mitani

发明人： Tomoki Nobuta ,  Toshihiko Nishiyama ,  Hiroyuki Kamisuki ,  Gaku Harada ,  Masato Kurosaki ,  Yuji Nakagawa ,  Shinako Kaneko ,  Masaya Mitani

IPC分类号： H01G9/02 ,  H01G11/02 ,  H01G11/08 ,  H01G11/22 ,  H01G11/48 ,  H01G11/52 ,  H01G11/54 ,  H01G11/58 ,  H01M4/60 ,  H01M6/04 ,  H01M10/05 ,  H01M10/36 ,  H01M10/42 ,  H01G9/038

CPC分类号： H01G9/038 ,  H01G9/028 ,  H01G11/48 ,  H01G11/58 ,  H01G11/64 ,  H01M4/60 ,  H01M4/602 ,  H01M6/045 ,  H01M10/36 ,  H01M10/4235 ,  H01M2300/0011 ,  Y02E60/13

摘要： A proton-conducting electric double layer capacitor comprising a electrolytic solution containing an aqueous solution of an organic or inorganic acid whereto a water-soluble N-containing heterocyclic compound is added.

摘要翻译： 包含含有水溶性含N杂环化合物的有机或无机酸水溶液的电解液的质子传导双电层电容器。