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公开(公告)号：US4917977A
公开(公告)日：1990-04-17
申请号：US289119
申请日：1988-12-23
申请人： William K. Smothers
发明人： William K. Smothers
CPC分类号： G03F7/001 , G03F7/031 , Y10S430/108 , Y10S430/116 , Y10S430/117 , Y10S430/146
摘要： A photosensitive composition comprising:(a) a compound of the formula ##STR1## (b) an ethylenically unsaturated compound capable of free radical initiated addition polymerization;(c) a polymeric binder; and(d) a free radical generating system activatable by actinic radiation which comprises a hexaarylbiimidazole and a chain transfer agent.A single step process for forming a light-stable hologram using this photosensitive composition is also disclosed.
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公开(公告)号：US5256520A
公开(公告)日：1993-10-26
申请号：US974195
申请日：1992-11-10
申请人： William K. Smothers
发明人： William K. Smothers
IPC分类号： C07C225/22 , C07D209/12 , C07D263/56 , C07D277/64 , C07D455/04 , G03F7/031 , G03C1/72
CPC分类号： C07D263/56 , C07C225/22 , C07D209/12 , C07D277/64 , C07D455/04 , G03F7/031 , Y10S430/12 , Y10S430/121 , Y10S430/123 , Y10S430/124 , Y10S430/125
摘要： Photopolymerizable compositions containing photoinitiator systems that absorb in the visible are disclosed. The photopolymerizable compositions contain at least one ethylenically unsaturated monomer capable of free radical initiated addition polymerization and a photoinitiator system capable of being activated by actinic radiation. The photoinitiator system comprises a hexaarylbisimidazole, a chain transfer agent, and a sensitizer given by the formulae A or B wherein X and R.sub.1 -R.sub.13 are as defined herein. ##STR1##
摘要翻译： 公开了含有在可见光中吸收的光引发剂体系的光聚合组合物。 可光聚合组合物含有至少一种能够进行自由基引发加成聚合的烯键式不饱和单体和能够通过光化辐射活化的光引发剂体系。 光引发剂体系包括六芳基双咪唑，链转移剂和由式A或B给出的敏化剂，其中X和R 1 -R 13如本文所定义。 B图
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13.发明授权
公开(公告)号：US4942112A
公开(公告)日：1990-07-17
申请号：US144355
申请日：1988-01-15
CPC分类号： G03F7/027 , G03H2260/12 , Y10S430/108 , Y10S430/11 , Y10S430/111 , Y10S430/113
摘要： Solid photopolymerizable compositions and photosensitive elements are provided that are useful in preparing optical elements, and especially holograms. The composition contains a polymeric binder, a liquid ethylenically unsaturated monomer, and a photoinitiator system. Typical compositions have a refractive index modulation of at least 0.005 when measured per the specified test.
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公开(公告)号：US5217846A
公开(公告)日：1993-06-08
申请号：US714224
申请日：1991-06-11
申请人： William K. Smothers
发明人： William K. Smothers
IPC分类号： G03F7/031
CPC分类号： G03F7/031 , Y10S430/121 , Y10S430/127
摘要： This invention relates to photopolymerizable compositions containing initiator systems that absorb in the longer wavelength region of the visible spectrum. Photopolymerizable compositions containing selected photodissociable initiators in combination with photobleachable sensitizers are disclosed.
摘要翻译： 本发明涉及含有在可见光谱的较长波长区域吸收的引发剂体系的可光聚合组合物。 公开了含有选择的光可分解引发剂与光可漂白敏化剂组合的光聚合组合物。
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公开(公告)号：US5204467A
公开(公告)日：1993-04-20
申请号：US810997
申请日：1991-12-20
申请人： William K. Smothers
发明人： William K. Smothers
IPC分类号： C07C225/22 , C07D209/12 , C07D263/56 , C07D277/64 , C07D455/04 , C08F2/50 , G03F7/031
CPC分类号： C07D263/56 , C07C225/22 , C07D209/12 , C07D277/64 , C07D455/04 , G03F7/031
摘要： Photopolymerizable compositions containing photoinitiator systems that absorb in the visible are disclosed.
摘要翻译： 公开了含有在可见光中吸收的光引发剂体系的光聚合组合物。
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16.发明授权
公开(公告)号：US5098803A
公开(公告)日：1992-03-24
申请号：US480352
申请日：1990-02-14
IPC分类号： G03F7/027
CPC分类号： G03F7/027 , G03H2260/12 , Y10S430/11 , Y10S430/111 , Y10S430/112 , Y10S430/113
摘要： Solid photopolymerizable compositions and photosensitive elements are provided that are useful in preparing optical elements, and especially holograms. The compositions contains a polymeric binder, a liquid ethylenically unsaturated monomer, and a photoinitiator system. Typical compositions have a refractive index modulation of at least 0.005 when measured per the specified test.
摘要翻译： 提供固体光聚合组合物和光敏元件，其可用于制备光学元件，特别是全息图。 组合物含有聚合物粘合剂，液体烯属不饱和单体和光引发剂体系。 当按照规定的试验测量时，典型的组合物具有至少0.005的折射率调制。
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17.发明授权Storage stable photopolymerizable composition and element for refractive index imaging 失效存储稳定的光聚合组合物和用于折射率成像的元件
公开(公告)号：US4994347A
公开(公告)日：1991-02-19
申请号：US288916
申请日：1988-12-23
申请人： William K. Smothers
发明人： William K. Smothers
CPC分类号： G03F7/031 , G03F7/001 , Y10S430/11 , Y10S430/111 , Y10S430/112 , Y10S430/113 , Y10S430/117 , Y10S430/121 , Y10S430/122
摘要： Solid storage stable photopolymerizable compositions are provided that are useful in preparing optical elements, and especially holograms. The composition contains a polymeric binder, N-vinyl carbazole and a photoinitiator system that has a hydrogen donor component.
摘要翻译： 提供了可用于制备光学元件，特别是全息图的固体储存稳定的光聚合组合物。 该组合物含有聚合物粘合剂，N-乙烯基咔唑和具有氢供体组分的光引发剂体系。
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公开(公告)号：US4950567A
公开(公告)日：1990-08-21
申请号：US370275
申请日：1989-06-22
申请人： Dalen E. Keys , William K. Smothers , Albert F. Harrington , Jacob Beutel , Scott R. Schicker , Dillon F. Scofield
发明人： Dalen E. Keys , William K. Smothers , Albert F. Harrington , Jacob Beutel , Scott R. Schicker , Dillon F. Scofield
IPC分类号： G02B5/28 , G02B27/00 , G02B27/01 , G03F7/00 , G03F7/004 , G03F7/027 , G03H1/02 , G03H1/04 , G03H1/18 , G03H1/24
CPC分类号： B32B17/10036 , B32B17/10761 , G02B27/0103 , G03F7/001 , G03F7/027 , G03H1/02 , G03H1/18 , G03H1/24 , G02B2027/0107 , G02B2027/0109 , G02B2027/0118 , G02B5/28 , G03H1/182 , G03H2001/026 , G03H2001/2231 , G03H2250/44 , G03H2260/12 , Y10S430/113
摘要： Optical Combiners are provided for use in Head-Up Displays. The Combiners have a refractive index modulation greater than approximately 0.001.
摘要翻译： 光学组合器提供用于平视显示器。 组合体的折射率调制大于约0.001。
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