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公开(公告)号：US20170028370A1
公开(公告)日：2017-02-02
申请号：US15302525
申请日：2015-04-15
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor： Klaus Hintzer , Egon Obermaier , Arne Thaler
CPC classification number: B01F17/0035 , B01J41/05 , B01J41/12 , B01J49/07 , B01J49/57 , C07C51/47 , C07C59/135
Abstract: Described herein is a process for recovering a branched, ether-containing fluorinated emulsifier from an anion exchange resin by (1) contacting the anion exchange resin with a recovery fluid to form an eluate, the recovery fluid comprising an ammonium salt, water, and a water-miscible solvent, wherein the fluorinated emulsifier is of the formula: [Rf-(0-R′f)n-0-CF(CF3)-C(0)0-]i M+1; and (2) separating the anion exchange resin from the eluate.
Abstract translation: 本文描述的是通过（1）使阴离子交换树脂与回收流体接触以形成洗脱液，从阴离子交换树脂中回收支链含醚的含氟乳化剂的方法，该回收流体包含铵盐，水和 其中氟化乳化剂具有下式：[Rf-（0-R'f）n-0-CF（CF 3）-C（O）O-] i M + 1; 和（2）从洗脱液中分离阴离子交换树脂。
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公开(公告)号：US12034193B2
公开(公告)日：2024-07-09
申请号：US17782193
申请日：2020-12-18
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor： Lisa P. Chen , Gregg D. Dahlke , Denis Duchesne , Klaus Hintzer , Matthew J. Lindell , Sean M. Smith , Arne Thaler , Michael A. Yandrasits
IPC: H01M8/1039 , H01M4/88 , H01M4/90 , H01M8/1004
CPC classification number: H01M8/1039 , H01M4/881 , H01M4/9008 , H01M8/1004 , H01M2300/0082
Abstract: The copolymer includes divalent units represented by formula —[CF2—CF2]—, at least one divalent unit represented by formula (I): and at least one divalent unit independently represented by formula (II): A is —N(RFa)2 or a is non-aromatic, 5- to 8-membered, perfluorinated ring comprising one or two nitrogen atoms in the ring and optionally comprising at least one oxygen atom in the ring, each RFa is independently linear or branched perfluoroalkyl having 1 to 8 carbon atoms and optionally interrupted by at least one catenated O or N atom, each Y is independently —H or —F, with the proviso that one Y may be —CF3, h is 0, 1, or 2, each i is independently 2 to 8, and j is 0, 1, or 2. A catalyst ink and polymer electrolyte membrane including the copolymer are also provided.
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13.发明申请公开(公告)号：US20230090482A1
公开(公告)日：2023-03-23
申请号：US17908265
申请日：2021-04-09
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor： Arne Thaler , Andreas Rosin , Mark W. Muggli , Klaus Hintzer , Patrick K. Heimerdinger , Thorsten Gerdes , Denis Duchesne , Gregg D. Dahlke
IPC: H01M8/1039 , H01M8/1004 , H01M4/88
Abstract: A composite includes a fluorinated polymer and nanoparticles of a metal salt. The metal salt has a solubility product of not more than 1×10−4. The fluorinated polymer includes a fluorinated polymer backbone chain and a plurality of groups represented by formula —SO2X, in which each X is independently —NZH, —NZSO2(CF2)1-6SO2X′, —NZ[SO2(CF2)dSO2NZ]1-10SO2(CF2)dSO2X′ or —OZ, and Z is independently a hydrogen, an alkali-metal cation, or a quaternary ammonium cation, X′ is independently —NZH or —OZ, and each d is independently 1 to 6. A polymer electrolyte membrane, an electrode, and a membrane electrode assembly including the composite are also provided.
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14.发明申请公开(公告)号：US20200277420A1
公开(公告)日：2020-09-03
申请号：US16645882
申请日：2018-09-14
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor： Lisa P. Chen , Gregg D. Dahlke , Denis Duchesne , Steven J. Hamrock , Klaus Hintzer , Markus E. Hirschberg , Arne Thaler , Tilman C. Zipplies
IPC: C08F214/18 , C08F214/26 , C09D11/52 , C08F8/44 , H01M8/1039 , H01M8/1004
Abstract: The copolymer includes divalent units represented by formula —[CF2—CF2]—, divalent units represented by formula: and one or more divalent units independently represented by formula: The copolymer has an —SO2X equivalent weight in a range from 300 to 2000. A polymer electrolyte membrane that includes the copolymer and a membrane electrode assembly that includes such a polymer electrolyte membrane are also provided.
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公开(公告)号：US10751262B2
公开(公告)日：2020-08-25
申请号：US15533293
申请日：2015-12-08
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor： Andreas R. Maurer , Hendrik Grupp , Joachim W. Zech , Arne Thaler , Kai H. Lochhaas , Klaus Hintzer , Christoph Schulte
Abstract: The invention relates to a curable dental composition comprising a cationically hardenable compound (A) comprising at least two aziridine moieties, a starter (B) being suitable to cure the hardenable compound (A), polymeric particles as filler component (C), the polymeric particles having a maximum particle size of 150 μm or below and the component(s) the polymeric particles are made of being based on fluoropolymers comprising more than 99% monomer repeating units of tetra fluoro ethylene. The invention also relates to the use of such composition for producing a dental impression material or a dental retraction material.
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Patent Agency Ranking
公开(公告)号：US20190027769A1
公开(公告)日：2019-01-24
申请号：US16082721
申请日：2017-03-06
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor： Gregg D. Dahlke , Denis Duchesne , Klaus Hintzer , Kai Helmut Lochhaas , Arne Thaler , Tilman C. Zipplies
IPC: H01M8/1039 , H01M4/62 , H01M8/1032 , C08F214/26
Abstract: The copolymer includes divalent units represented by formula: (I), one or more independently selected fluorinated divalent units, and —SO2X end groups. In this formula, b is 2 to 8, c is 0 to 2, and e is 1 to 8. In each SO2X, X is independently F, —NZH, —NZSO2(CF2)1−6SO2X′, —NZ[SO2(CF2)aSO2NZ]1−10SO2X′, or —OZ, wherein Z is a hydrogen, an alkali-metal cation or a quaternary ammonium cation, X′ is independently —NZH or —OZ, and each a is independently 1 to 6. The copolymer has an —SO2X equivalent weight of up to 1000. The method includes copolymerizing components including fluorinated olefin and a compound represented by formula CF2═CF—CF2(O—CbF2b)c—O—(CeF2e)—SO2X′, wherein b, c, and e are as defined above. A method of making a membrane using the copolymer or ionomer is also provided. A polymer electrolyte membrane that includes the copolymer or the ionomer and a membrane electrode assembly that includes such a polymer electrolyte membrane are also provided.
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公开(公告)号：US09694333B2
公开(公告)日：2017-07-04
申请号：US15302525
申请日：2015-04-15
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor： Klaus Hintzer , Egon Obermaier , Arne Thaler
CPC classification number: B01F17/0035 , B01J41/05 , B01J41/12 , B01J49/07 , B01J49/57 , C07C51/47 , C07C59/135
Abstract: Described herein is a process for recovering a branched, ether-containing fluorinated emulsifier from an anion exchange resin by (1) contacting the anion exchange resin with a recovery fluid to form an eluate, the recovery fluid comprising an ammonium salt, water, and a water-miscible solvent, wherein the fluorinated emulsifier is of the formula: [Rf-(0-R′f)n-0-CF(CF3)-C(0)0-]i M+1; and (2) separating the anion exchange resin from the eluate.
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18.发明申请METHOD FOR REDUCING FLUORINATED EMULSIFIERS FROM AQUEOUS FLUOROPOLYMER DISPERSIONS USING SUGAR-BASED EMULSIFIERS 审中-公开使用基于蔗糖的乳化剂从含水氟聚合物分散液中还原氟化乳化剂的方法公开(公告)号：US20160122572A1
公开(公告)日：2016-05-05
申请号：US14891566
申请日：2014-05-16
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor： Tilman C. Zipples , Arne Thaler , Egon Obermaier , Klaus Hintzer , Michael C. Dadalas
IPC: C09D127/18 , C08K5/41 , C08K5/42 , C08K5/521 , C09D105/00 , C08K5/06
CPC classification number: C09D127/18 , C08F6/16 , C08F6/20 , C08J3/03 , C08J3/05 , C08K5/053 , C08K5/06 , C08K5/1545 , C08K5/41 , C08K5/42 , C08K5/521 , C09D105/00 , C08L27/18
Abstract: Provided are processes for upconcentrating fluoropolymer dispersions. Also provided are upconcentrated dispersions and substrates coated with such dispersions.
Abstract translation: 提供了富含氟聚合物分散体的方法。 还提供了上层分散体和涂有这种分散体的基材。
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公开(公告)号：US12286387B2
公开(公告)日：2025-04-29
申请号：US17777837
申请日：2020-12-17
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor： Arne Thaler , Achim Schmidt-Rodenkirchen , Mark W. Muggli , Konstantin Mierdel , Klaus Hintzer , Thorsten Gerdes , Denis Duchesne , Gregg D. Dahlke
IPC: C07C17/367
Abstract: The process produces a fluorinated olefin from a fluorinated copolymer having at least one of sulfonic acid groups, carboxylic acid groups, or salts thereof. The process includes heating the fluorinated copolymer at a first temperature not more than 450° C. to decompose at least one of the sulfonic acid groups, carboxylic acid groups, or salts thereof to form a partially pyrolyzed intermediate and subsequently heating the partially pyrolyzed intermediate at a second temperature of at least 550° C. to produce the fluorinated olefin.
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公开(公告)号：US20240274848A1
公开(公告)日：2024-08-15
申请号：US18566288
申请日：2022-06-03
Applicant: 3M Innovative Properties Company , Colorado School Of Mines , GM Global Technology Operations LLC
Inventor： Michael A. Yandrasits , Matthew J. Lindell , Arne Thaler , Andrew M. Herring , ChulOong Kim , Mei-Chen Kuo , Craig S. Gittleman
IPC: H01M8/1039 , C08F214/26 , C08J5/22 , H01M8/10 , H01M8/1023
CPC classification number: H01M8/1039 , C08F214/262 , C08J5/225 , H01M8/1023 , C08J2327/18 , H01M2008/1095 , H01M2300/0082
Abstract: Fluorinated ionomers (i.e., ion conducting polymers) that include a fluorinated polymer backbone with covalently bound pendent groups that include heteropolyacid (HP A) groups, or salts thereof, and perfluorosulfonic acid (PF SA) groups, or salts thereof, as well as polymer electrolyte membranes, fuel cells, and methods.
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