公开(公告)号：US20210155571A1

公开(公告)日：2021-05-27

申请号：US16613456

申请日：2018-05-17

Applicant: Arkema France

Inventor： Guillaume LE ,  Julien JOUANNEAU ,  Jérome AMSTUTZ

IPC: C07C45/80 ,  C07C45/46 ,  C08G65/40 ,  C07C45/79

Abstract: A method for manufacturing 1,4-bis(4-phenoxybenzoyl)benzene, including: reacting terephthaloyl chloride with diphenyl ether in a reaction solvent and in the presence of a Lewis acid, so as to obtain a product mixture comprising a 1,4-bis(4-phenoxybenzoyl)benzene-Lewis acid complex; putting the product mixture in contact with a protic solvent, so as to obtain a first phase containing the Lewis acid and a second phase containing 1,4-bis(4-phenoxybenzoyl)benzene; subjecting at least the second phase to a solid/liquid separation step by centrifugal filtration, so as to recover solid 1,4-bis(4-phenoxybenzoyl)benzene.

公开(公告)号：US20200262989A1

公开(公告)日：2020-08-20

申请号：US16648180

申请日：2018-09-13

Applicant: Arkema France

Inventor： Guillaume LE ,  Fabien SGUERRA

IPC: C08J5/10 ,  C08J5/04 ,  C08J5/24 ,  B29B11/16

Abstract: A process for preparing a semifinished product comprising a PAEK-based resin and reinforcing fibers, including: preparing a dispersion comprising a PAEK-based resin in pulverulent form dispersed in an aqueous phase including at least one volatile organic compound and optionally a surfactant; bringing the reinforcing fibers into contact with said aqueous dispersion; drying the fibers impregnated with dispersion; and heating the impregnated fibers to a temperature sufficient for the melting of the resin, so as to form a semifinished product, wherein the aqueous phase of the dispersion has a dynamic viscosity, measured at 25° C. under a shear stress of 6.8 s−1 on a Brookfield DV2T Extra viscometer, is between 0.1 and 25 Pa·s; and wherein when the surfactant is present, its content is less than 1% by weight relative to the mass of dispersed resin.

公开(公告)号：US20180334420A1

公开(公告)日：2018-11-22

申请号：US15982625

申请日：2018-05-17

Applicant: ARKEMA FRANCE

Inventor： Guillaume LE ,  Julien JOUANNEAU

IPC: C07C45/46 ,  C07C45/80 ,  C07C45/79 ,  C08G65/40

CPC classification number: C07C45/46 ,  C07C45/85 ,  C08G61/12 ,  C07C49/84

Abstract: A method for manufacturing 1,4-bis(4-phenoxybenzoylbenzene), including: reacting terephthaloyl chloride with diphenyl ether in a reaction solvent and in the presence of a Lewis acid, so as to obtain a product mixture including a 1,4-bis(4-phenoxybenzoylbenzene)-Lewis acid complex; contacting the product mixture with an aqueous solution, so as to obtain an aqueous phase containing the Lewis acid and an organic phase containing 1,4-bis(4-phenoxybenzoylbenzene).

公开(公告)号：US20180208741A1

公开(公告)日：2018-07-26

申请号：US15746142

申请日：2016-07-21

Applicant: ARKEMA FRANCE

Inventor： Guillaume LE ,  Philippe BUSSI

IPC: C08K3/32 ,  C08K5/521

CPC classification number: C08K3/32 ,  C08G65/40 ,  C08G65/4012 ,  C08G2650/40 ,  C08K5/521 ,  C08K2003/322 ,  C08K2003/324 ,  C08L71/00 ,  C08L2201/08 ,  C08L2205/025

Abstract: A method for stabilizing a composition made from PAEK, said method including a step of incorporating a stabilizing agent against thermo-oxidation phenomena, said method being characterized in that said incorporated stabilizing agent is a phosphate salt, or a mixture of phosphate salts. The phosphate salt is incorporated into the composition based on PAEK by one of the following techniques: dry blending, compounding, wet impregnation or during the process for synthesizing the PAEK polymer.

公开(公告)号：US20140255713A1

公开(公告)日：2014-09-11

申请号：US14284142

申请日：2014-05-21

Applicant: ARKEMA FRANCE

Inventor： Samuel DEVISME ,  Fabrice CHOPINEZ ,  Jean-Laurent PRADEL ,  Guillaume LE ,  Thomas ROUSSEL ,  Jean-Luc DUBOIS

IPC: C08F255/04 ,  B32B7/12 ,  C09J151/06 ,  B32B27/08 ,  C08F255/02 ,  C08L51/06

CPC classification number: C08F255/04 ,  B32B7/12 ,  B32B27/08 ,  C08F255/02 ,  C08L51/06 ,  C08L2666/02 ,  C09J151/06 ,  Y10T428/2804 ,  Y10T428/2891 ,  Y10T428/31511 ,  Y10T428/31522 ,  Y10T428/31678 ,  Y10T428/31725 ,  Y10T428/31855 ,  Y10T428/31859

Abstract: A method for manufacturing a propylene polymer, including: a) fermenting and optionally purifying first renewable materials to produce an alcohol or an alcohol mixture, the alcohol or alcohol mixture including at least isopropanol and/or at least a mixture of ethanol and 1-butanol; b) dehydrating the resulting alcohol or the alcohol mixture to produce an alkene or alkene mixture in a first series of reactors, the alkene or alkene mixture containing at least propylene; c) polymerizing the propylene in a second reactor, optionally in the presence of a comonomer, so as to produce a propylene polymer; d) isolating the propylene polymer obtained in step c); and e) grafting the propylene polymer obtained from step d). A grafted propylene polymer capable of being obtained by the method, to the compositions containing the polymer, as well as to the uses of the polymer.

Abstract translation: 一种制备丙烯聚合物的方法，包括：a）发酵和任选地净化第一种可再生材料以产生醇或醇混合物，所述醇或醇混合物至少包括异丙醇和/或至少一种乙醇和1-丁醇的混合物 ; b）使所得醇或醇混合物脱水以在第一系列反应器中产生烯烃或烯烃混合物，所述烯烃或烯烃混合物至少含有丙烯; c）任选地在共聚单体存在下，在第二反应器中聚合丙烯，以产生丙烯聚合物; d）分离步骤c）中获得的丙烯聚合物; 和e）接枝由步骤d）得到的丙烯聚合物。 能够通过该方法获得的含有聚合物的组合物的接枝丙烯聚合物以及聚合物的用途。

公开(公告)号：US20250145763A1

公开(公告)日：2025-05-08

申请号：US18503546

申请日：2023-11-07

Applicant: ARKEMA FRANCE

Inventor： Guillaume LE ,  Laura LUIZ ,  Martin HERBLOT ,  Jérôme AMSTUTZ

IPC: C08G61/12

Abstract: The invention relates to a process for manufacturing a polyether ketone ketone, which involves placing in contact an aromatic ether which is diphenyl ether, 1,3-bis(4-phenoxybenzoyl)benzene, 1,4-bis(4-phenoxybenzoyl)benzene or a mixture thereof, an acyl chloride which is isophthaloyl chloride, terephthaloyl chloride, or a mixture thereof, a Lewis acid, and a first fraction s1 of a reaction solvent, so as to form a premix at a temperature T0 less than or equal to 25° C. and placing the premix formed at T0 in contact with a fraction s2 of the reaction solvent, the fraction s2 of reaction solvent being preheated, so as to form a reaction mixture heated to a temperature T1.

公开(公告)号：US20240124738A1

公开(公告)日：2024-04-18

申请号：US18270257

申请日：2021-12-23

Applicant: ARKEMA FRANCE

Inventor： Roderick REBER ,  Guillaume LE

IPC: C09D161/16 ,  B33Y70/00 ,  C08G65/40 ,  C09D11/102

CPC classification number: C09D161/16 ,  B33Y70/00 ,  C08G65/4012 ,  C09D11/102 ,  B29K2071/00 ,  C08G2650/48

Abstract: The invention concerns an additive manufacturing process by extrusion for forming a three-dimensional part with an additive manufacturing machine comprising a nozzle, the process comprising:



i) providing a pseudo-amorphous composition having a glass temperature Tg;
ii) softening the composition at a softening temperature above Tg and below 300° C. to form a softened composition which is fluid enough to flow and, extruding the softened composition from the nozzle to form an extruded part section; and,
iii) solidifying the extruded part section;


wherein the composition is based on a homopolymer or a copolymer of poly-ether-ketone-ketone, consisting of: at least an isophthalic (I) repeating unit, having the formula:






and, in the case of the copolymer, a terephthalic (T) repeating unit, having the formula:






wherein the molar proportion of T units relative to the sum of the T and I units ranges from 0% to 45% or from 55% to 65%.

公开(公告)号：US20230097436A1

公开(公告)日：2023-03-30

申请号：US17786044

申请日：2020-12-18

Applicant: ARKEMA FRANCE

Inventor： Philippe BUSSI ,  Guillaume LE ,  Anne-Claude GAUMONT ,  Hashim ALBADRI

IPC: C08G61/12 ,  C08G65/40

Abstract: A process for manufacturing an aromatic diether, including the reaction of a compound A including at least two halogenated aromatic groups with a compound B, B being an aromatic alkoxide, optionally in the presence of a compound C acting as reaction solvent, the molar proportion of compound B to compound A being at least 2:1 and the molar amount of compound C to compound A being, where appropriate, not more than 10:1. Also, a process for manufacturing a polyaryl ether ketone.

公开(公告)号：US20200079717A1

公开(公告)日：2020-03-12

申请号：US16613587

申请日：2018-05-16

Applicant: Arkema France

Inventor： Guillaume LE ,  Julien JOUANNEAU

IPC: C07C45/46 ,  C08G65/40

Abstract: A method for manufacturing 1,4-bis(4-phenoxybenzoyl)benzene, including: providing terephthaloyl chloride, diphenyl ether, a solvent and a Lewis acid, wherein the terephthaloyl chloride is of a purity grade such that, 10 minutes after introducing it at a reference concentration of 6.5 wt. % into said solvent, at a temperature of 20° C., a solution is obtained having a turbidity of less than 500 NTU; mixing the terephthaloyl chloride, the diphenyl ether and the solvent so as to make a reactant mixture; adding the Lewis acid to the reactant mixture so as to effect the reaction of the terephthaloyl chloride with the diphenyl ether; recovering a product mixture comprising a 1,4-bis(4-phenoxybenzoyl)benzene-Lewis acid complex.

公开(公告)号：US20200062683A1

公开(公告)日：2020-02-27

申请号：US16609648

申请日：2018-05-16

Applicant: Arkema France

Inventor： Julien JOUANNEAU ,  Guillaume LE ,  Jérome AMSTUTZ

IPC: C07C45/46 ,  C08G65/40

Abstract: The invention relates to a method for manufacturing 1,4-bis(4-phenoxybenzoylbenzene), comprising: providing a reactant mixture comprising terephthaloyl chloride and diphenyl ether in a solvent; adding a Lewis acid to the reactant mixture, so as to obtain a product mixture; wherein the temperature of the reactant mixture is greater than 5° C. during at least part of the step of adding the Lewis acid to the reactant mixture.