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公开(公告)号：US08445562B2
公开(公告)日：2013-05-21
申请号：US12705934
申请日：2010-02-15
Applicant: Mikhail Yurevich Balakshin , Alex Berlin , Humbert Thomas Dellicolli , Chadrick Adam Nathaniel Jordan Grunert , Vera Maximenko Gutman , Darwin Ortiz , Edward Kendall Pye
Inventor： Mikhail Yurevich Balakshin , Alex Berlin , Humbert Thomas Dellicolli , Chadrick Adam Nathaniel Jordan Grunert , Vera Maximenko Gutman , Darwin Ortiz , Edward Kendall Pye
CPC classification number: C08L97/005 , A23K10/32 , A23L33/105 , A61K36/15 , A61K36/48 , A61K36/54 , A61K36/76 , C07G1/00 , C08H6/00 , C08J3/00 , C08J2397/00 , C08K5/13 , C08L23/02 , C08L57/00 , C08L2207/04 , C09K15/06 , D21C11/0007 , D21H11/00 , Y02P20/582 , Y02P60/877
Abstract: One aspect of the invention relates to lignin derivatives having an aliphatic hydroxyl content of 2.35 mmol/g lignin or less, and the preparation method thereof. The lignin derivatives have a desired antioxidant activity characterized by the normalized radical scavenging index (RSI). Another aspect of the invention relates to compositions comprising the lignin derivative. Another aspect of the invention relates to a use of the lignin derivatives comprising incorporating the lignin derivatives into polymer compositions.
Abstract translation: 本发明的一个方面涉及具有2.35mmol / g木质素或更少的脂族羟基含量的木质素衍生物及其制备方法。 木质素衍生物具有所需的抗氧化活性，其特征在于归一化的自由基清除指数（RSI）。 本发明的另一方面涉及包含木质素衍生物的组合物。 本发明的另一方面涉及木质素衍生物的用途，其包括将木质素衍生物掺入聚合物组合物中。
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12.发明申请DERIVATIVES OF NATIVE LIGNIN, LIGNIN-WAX COMPOSITIONS, THEIR PREPARATION AND USES THEREOF 审中-公开本品LIGNIN，LIGNIN-WAX组合物的衍生物及其制备及其用途公开(公告)号：US20120247617A1
公开(公告)日：2012-10-04
申请号：US13322907
申请日：2010-05-27
Applicant: Alex Berlin , Paul Mulyk
Inventor： Alex Berlin , Paul Mulyk
IPC: C08L97/02 , C09D197/00 , B27D5/00 , C07G1/00
CPC classification number: C08L97/005 , A23K10/32 , A23L33/105 , A61K36/15 , A61K36/48 , A61K36/54 , A61K36/76 , B27N3/002 , C07G1/00 , C08H6/00 , C08J3/00 , C08J2397/00 , C08K5/13 , C08L23/02 , C08L57/00 , C08L91/06 , C08L97/02 , C08L2201/52 , C08L2207/04 , C09K15/06 , D21C11/0007 , D21H11/00 , Y02P20/582 , Y02P60/877
Abstract: A wax composition comprising a lignin derivative wherein the derivative has a total hydroxyl content of from about 0.1 mmol/g to about 7 mmol/g.
Abstract translation: 包含木质素衍生物的蜡组合物，其中所述衍生物的总羟基含量为约0.1mmol / g至约7mmol / g。
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13.发明授权公开(公告)号：US08227004B2
公开(公告)日：2012-07-24
申请号：US12268417
申请日：2008-11-10
Applicant: Christer Hallberg , Donald O'Connor , Michael Rushton , Edward Kendall Pye , Gordon Gjennestad , Alex Berlin , John Ross MacLachlan
Inventor： Christer Hallberg , Donald O'Connor , Michael Rushton , Edward Kendall Pye , Gordon Gjennestad , Alex Berlin , John Ross MacLachlan
IPC: C12C11/00
CPC classification number: C07H19/00 , B01D3/002 , B01D3/14 , B01D11/0226 , B01D11/0288 , C02F3/34 , C02F11/04 , C08H6/00 , C08H8/00 , C08L3/02 , C08L5/04 , C12M21/04 , C12M21/12 , C12M45/02 , C12M45/04 , C12M45/06 , C12M45/09 , C12P5/023 , C12P7/00 , C12P7/08 , C12P7/10 , C12P7/40 , C12P7/54 , C12P19/14 , C13K1/02 , D21H17/00 , Y02E50/16 , Y02E50/17 , Y02E50/343 , Y02W10/23
Abstract: A modular process for organosolv fractionation of lignocellulosic feedstocks into component parts and further processing of said component parts into at least fuel-grade ethanol and four classes of lignin derivatives. The modular process includes a first processing module configured for physico-chemically digesting lignocellulosic feedstocks with an organic solvent thereby producing a cellulosic solids fraction and a liquid fraction, a second processing module configured for producing at least a fuel-grade ethanol and a first class of novel lignin derivatives from the cellulosic solids fraction, a third processing module configured for separating a second class and a third class of lignin derivatives from the liquid fraction and further processing the liquid fraction to produce a distillate and a stillage, a fourth processing module configured for separating a fourth class of lignin derivatives from the stillage and further processing the stillage to produce a sugar syrup.
Abstract translation: 用于将木质纤维素原料有机溶剂分馏成组分并将所述组分部分进一步加工成至少燃料级乙醇和四类木质素衍生物的模块化方法。 模块化方法包括第一处理模块，其被配置用于用有机溶剂物理化学消化木质纤维素原料，从而产生纤维素固体部分和液体馏分，第二处理模块被配置用于生产至少燃料级乙醇和第一类 来自纤维素固体部分的新型木质素衍生物，第三处理模块，其被配置用于从液体馏分中分离第二类和第三类木质素衍生物，并进一步处理液体馏分以产生馏出物和釜馏塔;第四处理模块， 从釜中分离第四类木质素衍生物，并进一步处理釜渣以产生糖浆。
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14.发明授权公开(公告)号：US08193324B2
公开(公告)日：2012-06-05
申请号：US12324311
申请日：2008-11-26
Applicant: Christer Hallberg , Donald O'Connor , Michael Rushton , Edward Kendall Pye , Gordon Gjennstad , Alex Berlin , John Ross MacLachlan , Raymond Ma
Inventor： Christer Hallberg , Donald O'Connor , Michael Rushton , Edward Kendall Pye , Gordon Gjennstad , Alex Berlin , John Ross MacLachlan , Raymond Ma
CPC classification number: B01D3/002 , B01D3/143 , B01D3/145 , B01D3/148 , C07H19/00 , C08H8/00 , C12M21/04 , C12M45/06 , C12M45/09 , C12P5/023 , C12P7/00 , C12P7/08 , C12P7/16 , C12P7/18 , C12P7/40 , C12P7/54 , C12P7/56 , C12P19/14 , Y02E50/10 , Y02E50/16 , Y02E50/343
Abstract: A modular process for organosolv fractionation of lignocellulosic feedstocks into component parts and further processing of said component parts into one or more of a de-lignified cellulose stream, a sugar stream, small-chain alcohol streams and four structurally distinct classes of lignin derivatives. The modular process comprises a first processing module configured for digesting lignocellulosic feedstocks with an organic solvent thereby producing a cellulosic solids fraction and a liquid fraction, a second processing module configured for recovering small-chain alcohols and optionally a first class of lignin derivatives from the cellulosic solids fraction, a third processing module configured for recovering from the liquid fraction at least one of a second class and a third class of lignin derivatives or mixtures thereof, and waste stream comprising a fourth class of lignin derivatives. The fourth processing module may optionally recover the fourth class of lignin derivatives.
Abstract translation: 用于将木质纤维素原料有机溶剂分馏成组分部分并将所述组分部分进一步加工成一种或多种脱木质纤维素流，糖流，小链醇流和四种结构不同类型的木质素衍生物的模块化方法。 模块化方法包括第一处理模块，其被配置用于用有机溶剂消化木质纤维素原料，从而产生纤维素固体部分和液体部分，第二处理模块被配置用于从纤维素中回收小链醇和任选的第一类木质素衍生物 固体部分，第三处理模块，其被配置用于从第二类和第三类木质素衍生物或其混合物中的至少一种液体馏分回收，以及包含第四类木质素衍生物的废物流。 第四处理模块可任选地回收第四类木质素衍生物。
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公开(公告)号：US20100305242A1
公开(公告)日：2010-12-02
申请号：US12705944
申请日：2010-02-15
Applicant: Mikhail Yurevich Balakshin , Alex Berlin , Humbert Thomas Dellicolli , Chadrick Adam Nathaniel Jordan Grunert , Vera Maximenko Gutman , Darwin Ortiz , Edward Kendall Pye
Inventor： Mikhail Yurevich Balakshin , Alex Berlin , Humbert Thomas Dellicolli , Chadrick Adam Nathaniel Jordan Grunert , Vera Maximenko Gutman , Darwin Ortiz , Edward Kendall Pye
CPC classification number: C08L97/005 , A23K10/32 , A23L33/105 , A61K36/15 , A61K36/48 , A61K36/54 , A61K36/76 , C07G1/00 , C08H6/00 , C08J3/00 , C08J2397/00 , C08K5/13 , C08L23/02 , C08L57/00 , C08L2207/04 , C09K15/06 , D21C11/0007 , D21H11/00 , Y02P20/582 , Y02P60/877
Abstract: The present invention provides hardwood derivatives of native lignin having a certain aliphatic hydroxyl content. Surprisingly, it has been found that consistent and predictable antioxidant activity may be provided by selecting for derivatives of native lignin having a certain aliphatic hydroxyl content.
Abstract translation: 本发明提供具有某些脂族羟基含量的天然木质素的硬木衍生物。 令人惊奇的是，已经发现可以通过选择具有某种脂肪族羟基含量的天然木质素的衍生物来提供一致和可预测的抗氧化活性。
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Patent Agency Ranking
公开(公告)号：US20150299951A1
公开(公告)日：2015-10-22
申请号：US14570815
申请日：2014-12-15
Applicant: Mikhail Yurevich BALAKSHIN , Alex Berlin , Humbert Thomas Dellicolli , Chadrick Adam Nathaniel Jordan GRUNERT , Vera Maximenko Gutman , Darwin Ortiz , Edward Kendall Pye
Inventor： Mikhail Yurevich BALAKSHIN , Alex Berlin , Humbert Thomas Dellicolli , Chadrick Adam Nathaniel Jordan GRUNERT , Vera Maximenko Gutman , Darwin Ortiz , Edward Kendall Pye
CPC classification number: C08L97/005 , A23K10/32 , A23L33/105 , A61K36/15 , A61K36/48 , A61K36/54 , A61K36/76 , C07G1/00 , C08H6/00 , C08J3/00 , C08J2397/00 , C08K5/13 , C08L23/02 , C08L57/00 , C08L2207/04 , C09K15/06 , D21C11/0007 , D21H11/00 , Y02P20/582 , Y02P60/877
Abstract: The present invention provides derivatives of native lignin having certain aliphatic hydroxyl content. Surprisingly, it has been found that consistent and predictable antioxidant activity may be provided by selecting for derivatives of native lignin having certain aliphatic hydroxyl content.
Abstract translation: 本发明提供具有某些脂肪族羟基含量的天然木质素的衍生物。 令人惊奇的是，已经发现通过选择具有某些脂族羟基含量的天然木质素的衍生物可以提供一致和可预测的抗氧化活性。
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公开(公告)号：US08431635B2
公开(公告)日：2013-04-30
申请号：US12705938
申请日：2010-02-15
Applicant: Mikhail Yurevich Balakshin , Alex Berlin , Humbert Thomas Dellicolli , Chadrick Adam Nathaniel Jordan Grunert , Vera Maximenko Gutman , Darwin Ortiz , Edward Kendall Pye
Inventor： Mikhail Yurevich Balakshin , Alex Berlin , Humbert Thomas Dellicolli , Chadrick Adam Nathaniel Jordan Grunert , Vera Maximenko Gutman , Darwin Ortiz , Edward Kendall Pye
IPC: C08L97/02
CPC classification number: C08L97/005 , A23K10/32 , A23L33/105 , A61K36/15 , A61K36/48 , A61K36/54 , A61K36/76 , C07G1/00 , C08H6/00 , C08J3/00 , C08J2397/00 , C08K5/13 , C08L23/02 , C08L57/00 , C08L2207/04 , C09K15/06 , D21C11/0007 , D21H11/00 , Y02P20/582 , Y02P60/877
Abstract: One aspect of the invention relates to softwood lignin derivatives having an aliphatic hydroxyl content of from about 2.5 mmol/g to about 7 mmol/g lignin, and the preparation method thereof. The lignin derivatives have a desired antioxidant activity characterized by radical scavenging index (RSI). Another aspect of the invention relates to compositions comprising the softwood lignin derivative. Another aspect of the invention relates to a use of the softwood lignin derivatives comprising incorporating the softwood lignin derivatives into polymer compositions.
Abstract translation: 本发明的一个方面涉及具有约2.5mmol / g至约7mmol / g木质素的脂族羟基含量的软木木素衍生物及其制备方法。 木质素衍生物具有以自由基清除指数（RSI）为特征的所需抗氧化活性。 本发明的另一方面涉及包含软木木质素衍生物的组合物。 本发明的另一方面涉及软木木质素衍生物的用途，其包括将软木木质素衍生物掺入聚合物组合物中。
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公开(公告)号：US08288460B2
公开(公告)日：2012-10-16
申请号：US12705944
申请日：2010-02-15
Applicant: Mikhail Yurevich Balakshin , Alex Berlin , Humbert Thomas Dellicolli , Chadrick Adam Nathaniel Jordan Grunert , Vera Maximenko Gutman , Darwin Ortiz , Edward Kendall Pye
Inventor： Mikhail Yurevich Balakshin , Alex Berlin , Humbert Thomas Dellicolli , Chadrick Adam Nathaniel Jordan Grunert , Vera Maximenko Gutman , Darwin Ortiz , Edward Kendall Pye
CPC classification number: C08L97/005 , A23K10/32 , A23L33/105 , A61K36/15 , A61K36/48 , A61K36/54 , A61K36/76 , C07G1/00 , C08H6/00 , C08J3/00 , C08J2397/00 , C08K5/13 , C08L23/02 , C08L57/00 , C08L2207/04 , C09K15/06 , D21C11/0007 , D21H11/00 , Y02P20/582 , Y02P60/877
Abstract: One aspect of the invention relates to hardwood lignin derivatives having an aliphatic hydroxyl content of from about 5.2 mmol/g to about 7 mmol/g lignin, and the preparation method thereof. The lignin derivatives have a desired antioxidant activity characterized by the normalized radical scavenging index (RSI). Another aspect of the invention relates to compositions comprising the hardwood lignin derivative. Another aspect of the invention relates to a use of the hardwood lignin derivatives comprising incorporating the hardwood lignin derivatives into polymer compositions.
Abstract translation: 本发明的一个方面涉及具有约5.2mmol / g至约7mmol / g木质素的脂族羟基含量的硬木素衍生物及其制备方法。 木质素衍生物具有所需的抗氧化活性，其特征在于归一化的自由基清除指数（RSI）。 本发明的另一方面涉及包含硬木木质素衍生物的组合物。 本发明的另一方面涉及硬木木质素衍生物的用途，其包括将硬木木质素衍生物掺入聚合物组合物中。
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公开(公告)号：US20100305241A1
公开(公告)日：2010-12-02
申请号：US12705934
申请日：2010-02-15
Applicant: Mikhail Yurevich Balakshin , Alex Berlin , Humbert Thomas Dellicolli , Chadrick Adam Nathaniel Jordan Grunert , Vera Maximenko Gutman , Darwin Ortiz , Edward Kendall Pye
Inventor： Mikhail Yurevich Balakshin , Alex Berlin , Humbert Thomas Dellicolli , Chadrick Adam Nathaniel Jordan Grunert , Vera Maximenko Gutman , Darwin Ortiz , Edward Kendall Pye
CPC classification number: C08L97/005 , A23K10/32 , A23L33/105 , A61K36/15 , A61K36/48 , A61K36/54 , A61K36/76 , C07G1/00 , C08H6/00 , C08J3/00 , C08J2397/00 , C08K5/13 , C08L23/02 , C08L57/00 , C08L2207/04 , C09K15/06 , D21C11/0007 , D21H11/00 , Y02P20/582 , Y02P60/877
Abstract: The present invention provides derivatives of native lignin having a certain aliphatic hydroxyl content. Surprisingly, it has been found that consistent and predictable antioxidant activity may be provided by selecting for derivatives of native lignin having a certain aliphatic hydroxyl content.
Abstract translation: 本发明提供具有某些脂族羟基含量的天然木质素的衍生物。 令人惊奇的是，已经发现可以通过选择具有某种脂肪族羟基含量的天然木质素的衍生物来提供一致和可预测的抗氧化活性。
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公开(公告)号：US20080295980A1
公开(公告)日：2008-12-04
申请号：US12016932
申请日：2008-01-18
Applicant: Christer Hallberg , Donald O'Connor , Michael Rushton , Edward Kendall Pye , Gordon Gjennestad , Alex Berlin , John Ross MacLachlan
Inventor： Christer Hallberg , Donald O'Connor , Michael Rushton , Edward Kendall Pye , Gordon Gjennestad , Alex Berlin , John Ross MacLachlan
CPC classification number: C07H19/00 , B01D3/002 , B01D3/14 , B01D11/0226 , B01D11/0288 , C02F3/34 , C02F11/04 , C08H6/00 , C08H8/00 , C08L3/02 , C08L5/04 , C12M21/04 , C12M21/12 , C12M45/02 , C12M45/04 , C12M45/06 , C12M45/09 , C12P5/023 , C12P7/00 , C12P7/08 , C12P7/10 , C12P7/40 , C12P7/54 , C12P19/14 , C13K1/02 , D21H17/00 , Y02E50/16 , Y02E50/17 , Y02E50/343 , Y02W10/23
Abstract: A modular process for organosolv fractionation of lignocellulosic feedstocks into component parts and further processing of said component parts into at least fuel-grade ethanol and four classes of lignin derivatives. The modular process comprises a first processing module configured for physico-chemically digesting lignocellulosic feedstocks with an organic solvent thereby producing a cellulosic solids fraction and a liquid fraction, a second processing module configured for producing at least a fuel-grade ethanol and a first class of novel lignin derivatives from the cellulosic solids fraction, a third processing module configured for separating a second class and a third class of lignin derivatives from the liquid fraction and further processing the liquid fraction to produce a distillate and a stillage, a fourth processing module configured for separating a fourth class of lignin derivatives from the stillage and further processing the stillage to produce a sugar syrup.
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