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    Catalysts and process to manufacture 2,3,3,3-tetrafluoropropene
    11.
    发明授权
    Catalysts and process to manufacture 2,3,3,3-tetrafluoropropene 有权
    催化剂和制备2,3,3,3-四氟丙烯的方法

    公开(公告)号：US08227649B2

    公开(公告)日：2012-07-24

    申请号：US13188787

    申请日：2011-07-22

    申请人： Mario Joseph Nappa ,  Andrew Jackson

    发明人： Mario Joseph Nappa ,  Andrew Jackson

    IPC分类号： C07C17/00

    CPC分类号： C07C17/25 ,  C07C21/18

    摘要： Disclosed is a process for the manufacture of 2,3,3,3-tetrafluoropropene comprising: (a) contacting 1,1,1,2,3-pentafluoropropane with a catalyst comprised of chromium (III) oxide and from 0.1% to 2% of an alkali metal disposed on the surface of said catalyst, to produce a product mixture comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride; and (b) recovering said 2,3,3,3-tetrafluoropropene from the product mixture produced in (a).

    摘要翻译： 公开了一种制备2,3,3,3-四氟丙烯的方法，包括：（a）将1,1,1,2,3-五氟丙烷与由氧化铬（III）和0.1％至2 设置在所述催化剂表面上的碱金属的％，以产生包含2,3,3,3-四氟丙烯和氟化氢的产物混合物; 和（b）从（a）中制备的产物混合物回收所述2,3,3,3-四氟丙烯。

    COMPOSITIONS COMPRISING 2,3,3,3-TETRAFLUOROPROPENE, 2-CHLORO-2,3,3,3-TETRAFLUOROPROPANOL, 2-CHLORO-2,3,3,3-TETRAFLUORO-PROPYL ACETATE OR ZINC (2-CHLORO-2,3,3,3-TETRAFLUOROPROPOXY) CHLORIDE
    12.
    发明申请
    COMPOSITIONS COMPRISING 2,3,3,3-TETRAFLUOROPROPENE, 2-CHLORO-2,3,3,3-TETRAFLUOROPROPANOL, 2-CHLORO-2,3,3,3-TETRAFLUORO-PROPYL ACETATE OR ZINC (2-CHLORO-2,3,3,3-TETRAFLUOROPROPOXY) CHLORIDE 失效
    包含2,3,3,3-四氢呋喃，2-氯-2,3,3,3-四氢氟丙醇，2-氯-2,2,3,3-四氢丙酸乙酯或ZINC（2-氯-2）的组合物 3,3,3-TETRAFLOOROPROPOXY）氯化物

    公开(公告)号：US20120168672A1

    公开(公告)日：2012-07-05

    申请号：US13405657

    申请日：2012-02-27

    申请人： Mario Joseph Nappa ,  Xuehui Sun

    发明人： Mario Joseph Nappa ,  Xuehui Sun

    IPC分类号： C09K5/00

    CPC分类号： C09K5/045 ,  C09K2205/126

    摘要： Compositions comprising CF3CClFCH2OH, CF3CClFCH2OZnCl, and CF3CClFCH2OC(═O)CH3 are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf may comprise at least one additional compound selected from the group consisting of CFC-114a, HCFC-124, HFC-143a, CFO-1113, HFO-1123, HFO-1132a, tetrafluoroethene, HCFO-1122, 3,4,4,4-tetrafluoro-2-butanone, acetyl fluoride, 2-chloro-2,3,3,3-tetrafluoropropanol, 2-chloro-2,3,3,3-tetrafluoropropyl acetate, Zinc (2-chloro-2,3,3,3-tetrafluoropropoxy)chloride, 2-chloro-2,3,3,3-tetrafluoropropoxy methyl acetate, 1,3-bistrifluoromethyl-1,3-difluorocyclobutane, 2,3,3,3-tetrafluoropropyl acetate, dimethylformamide, pyridine, ethyl acetate, acetic acid, diethyl ether, acetic anhydride, methyl acetate, dimethylacetamide, methanol, ethanol, methyl formate, pyrazine, pyrimidine, N-methylpyrrolidine, N-methylpiperidine, hexamethylphosphoramide, tetrahydrofuran, 1,4-dioxane, N-methylpyrrolidinone, dimethyl sulfoxide, acetonitrile, benzonitrile, and mixtures thereof. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.

    摘要翻译： 包含CF 3 CClFCH 2 OH，CF 3 CClFCH 2 OZnCl和CF 3 CClFCH 2 OC（= O）CH 3的组合物可用于制备HFO-1234yf的方法中。 包含HFO-1234yf的组合物可以包含至少一种选自CFC-114a，HCFC-124，HFC-143a，CFO-1113，HFO-1123，HFO-1132a，四氟乙烯，HCFO-1122,3， 4,4,4-四氟-2-丁酮，乙酰氟，2-氯-2,3,3,3-四氟丙醇，2-氯-2,3,3,3-四氟丙基乙酸酯，锌（2-氯 - 2,3,3,3-四氟丙氧基）氯化物，2-氯-2,3,3,3-四氟丙氧基甲酸乙酯，1,3-双三氟甲基-1,3-二氟环丁烷，乙酸2,3,3,3-四氟丙酯 吡啶，乙酸乙酯，乙酸甲酯，二甲基乙酰胺，甲醇，乙醇，甲酸甲酯，吡嗪，嘧啶，N-甲基吡咯烷，N-甲基哌啶，六甲基磷酰胺，四氢呋喃，1,4-二恶烷 ，N-甲基吡咯烷酮，二甲基亚砜，乙腈，苄腈及其混合物。 包括HFO-1234yf的组合物在其它用途中可用作用于制冷，空调和热泵系统的热传递组合物。

    Compositions comprising 3,3,3-trifluoropropyne
    13.
    发明授权
    Compositions comprising 3,3,3-trifluoropropyne 有权
    包含3,3,3-三氟丙炔的组合物

    公开(公告)号：US08147709B2

    公开(公告)日：2012-04-03

    申请号：US12437014

    申请日：2009-05-07

    申请人： Barry Asher Mahler ,  Mario Joseph Nappa ,  Jeffrey P. Knapp

    发明人： Barry Asher Mahler ,  Mario Joseph Nappa ,  Jeffrey P. Knapp

    IPC分类号： C09K5/04

    CPC分类号： C09K5/00 ,  B01J27/125 ,  B01J37/26 ,  C07C17/25 ,  C07C17/354 ,  C07C21/18 ,  C07C21/22 ,  C08J9/146 ,  C08J9/149 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/12 ,  C09K2205/126 ,  C07C19/08

    摘要： Disclosed are compositions comprising HFC-245eb and at least one additional compound selected from the group consisting of HFO-1234ze, HFC-245fa, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-143a, HFC-134, HFC-134a, FC-1216, HFO-1234yf, HFC-254eb, HFO-1243zf, and HFC-254fb. Compositions comprising HFC-245eb are useful in processes to make HFO-1234yf. Also disclosed are compositions comprising HFO-1234yf and at least one additional compound selected from the group consisting of HFO-1234ze, HFC-254eb, HFC-254fb, HFO-1243zf, HFCHFC-245eb, HFC-245fa, HFC-245cb, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-134, HFC-134a, HFO-1132a and FC-1216. Compositions comprising HFO-1234yf are useful as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.

    摘要翻译： 公开了包含HFC-245eb和至少一种选自HFO-1234ze，HFC-245fa，HFC-236cb，HFC-236ea，HFC-236fa，HFC-227ea，HFC-227ca，HFO-1225yc ，HFO-1225zc，HFO-1225ye，甲烷，乙烷，丙烷，HFC-23，HFC-143a，HFC-134，HFC-134a，FC-1216，HFO-1234yf，HFC-254eb，HFO-1243zf和HFC- 254fb。 包含HFC-245eb的组合物可用于制备HFO-1234yf的方法。 还公开了包含HFO-1234yf和至少一种选自HFO-1234ze，HFC-254eb，HFC-254fb，HFO-1243zf，HFCHFC-245eb，HFC-245fa，HFC-245cb，HFC- 236cb，HFC-236ea，HFC-236fa，HFC-227ea，HFC-227ca，HFO-1225yc，HFO-1225zc，HFO-1225ye，甲烷，乙烷，丙烷，HFC-23，HFC-134，HFC-134a， 1132a和FC-1216。 包含HFO-1234yf的组合物可用作用于制冷，空调和热泵系统的热转印组合物。

    Processes for the synthesis of 2-chloro-1,1,1,3,3,4,4,4-heptafluoro-2-butene and hexafluoro-2-butyne
    14.
    发明授权
    Processes for the synthesis of 2-chloro-1,1,1,3,3,4,4,4-heptafluoro-2-butene and hexafluoro-2-butyne 失效
    合成2-氯-1,1,1,3,3,4,4,4-七氟-2-丁烯和六氟-2-丁炔的方法

    公开(公告)号：US08143462B2

    公开(公告)日：2012-03-27

    申请号：US12334873

    申请日：2008-12-15

    申请人： Mario Joseph Nappa

    发明人： Mario Joseph Nappa

    IPC分类号： C07C17/25

    CPC分类号： C07C17/23 ,  C07C17/278 ,  C07C17/354 ,  C07C21/18 ,  C07C21/22 ,  C07C19/10

    摘要： Disclosed is a process comprising reacting CF3CCl2CF2CF3 (CFC-318ma) with hydrogen in the presence of a dehalogenation catalyst to produce CF3CCl═CFCF3 (CFC-1317mx). Also disclosed is a process comprising reacting CF3CCl═CFCF3 (CFC-1317mx) with hydrogen in the presence of a dehalogenation catalyst to produce CF3C≡CCF3 (hexafluoro-2-butyne). Hexafluoro-2-butyne can be used to produce CF3CH═CHCF2CF3 (1,1,1,4,4,5,5,5-octafluoro-2-pentene).

    摘要翻译： 公开了一种方法，其包括在脱卤催化剂存在下使CF 3 CCl 2 CF 2 CF 3（CFC-318ma）与氢气反应以产生CF 3 CCl = CFCF 3（CFC-1317mx）。 还公开了包括在脱卤催化剂存在下使CF 3 CCl = CFCF 3（CFC-1317mx）与氢气反应以产生CF 3C≡CCF3（六氟-2-丁炔）的方法。 六氟-2-丁炔可用于制备CF 3 CH = CHCF 2 CF 3（1,1,1,4,4,5,5,5-八氟-2-戊烯）。

    Catalytic isomerization between E and Z isomers of 1,2,3,3,3-pentafluoropropene
    15.
    发明授权
    Catalytic isomerization between E and Z isomers of 1,2,3,3,3-pentafluoropropene 失效
    1,2,3,3,3-五氟丙烯的E和Z异构体之间的催化异构化

    公开(公告)号：US08044252B2

    公开(公告)日：2011-10-25

    申请号：US12373588

    申请日：2007-07-11

    申请人： Mario Joseph Nappa ,  Donald J. Toton ,  Velliyur Nott Mallikarjuna Rao

    发明人： Mario Joseph Nappa ,  Donald J. Toton ,  Velliyur Nott Mallikarjuna Rao

    IPC分类号： C07C17/00

    CPC分类号： B01J27/12 ,  B01J27/135 ,  C07C17/358 ,  C07C21/18

    摘要： A process is disclosed to increase the Z/E ratio of 1,2,3,3,3-pentafluoropropene. The process involves contacting a starting material comprising 1,2,3,3,3-pentafluoropropene with a catalyst on AlF3 or carbon, wherein the catalyst is selected from the group consisting of SbClwF5-w, TiClxF4-x, SnClyF4-y and TaCl2F5-z wherein w is from 0 to 4, x is from 0 to 3, y is from 0 to 3, z is from 0 to 4, to obtain a product wherein the Z/E ratio of 1,2,3,3,3-pentafluoropropene is increased relative to the Z/E ratio of 1,2,3,3,3-pentafluoropropene in the starting material.A process is also disclosed to decrease the Z/E ratio of 1,2,3,3,3-pentafluoropropene. The process involves contacting a starting material comprising 1,2,3,3,3-pentafluoropropene with a catalyst on AlF3 or carbon, wherein the catalyst is selected from the group consisting of SbClwF5-w, TiClxF4-x, SnClyF4-y and TaClzF5-z wherein w is from 0 to 4, x is from 0 to 3, y is from 0 to 3, z is from 0 to 4, to obtain a product wherein the Z/E ratio of 1,2,3,3,3-pentafluoropropene is decreased relative to the Z/E ratio of 1,2,3,3,3-pentafluoropropene in the starting material.

    摘要翻译： 公开了提高1,2,3,3,3-五氟丙烯的Z / E比的方法。 该方法包括使包含1,2,3,3,3-五氟丙烯的起始材料与AlF 3或碳上的催化剂接触，其中催化剂选自SbClwF5-w，TiClxF4-x，SnClyF4-y和TaCl2F5 -z其中w为0至4，x为0至3，y为0至3，z为0至4，得到其Z / E比为1,2,3,3， 3-五氟丙烯相对于起始原料中1,2,3,3,3-五氟丙烯的Z / E比增加。 还公开了降低1,2,3,3,3-五氟丙烯的Z / E比的方法。 该方法包括将包含1,2,3,3,3-五氟丙烯的原料与AlF 3或碳上的催化剂接触，其中催化剂选自SbClwF5-w，TiClxF4-x，SnClyF4-y和TaClzF5 -z其中w为0至4，x为0至3，y为0至3，z为0至4，得到其Z / E比为1,2,3,3， 3-五氟丙烯相对于起始原料中1,2,3,3,3-五氟丙烯的Z / E比降低。

    Processes for producing and compositions comprising 2,3,3,3-tetrafluoropropene and/or 1,2,3,3-tetrafluoropropene
    16.
    发明授权
    Processes for producing and compositions comprising 2,3,3,3-tetrafluoropropene and/or 1,2,3,3-tetrafluoropropene 失效
    制备方法和包含2,3,3,3-四氟丙烯和/或1,2,3,3-四氟丙烯的组合物

    公开(公告)号：US07981312B2

    公开(公告)日：2011-07-19

    申请号：US12442952

    申请日：2007-10-31

    申请人： Mario Joseph Nappa ,  Velliyur Mallikarjuna Nott Rao ,  Allen Capron Sievert

    发明人： Mario Joseph Nappa ,  Velliyur Mallikarjuna Nott Rao ,  Allen Capron Sievert

    IPC分类号： C09K5/04 ,  C07C17/20 ,  C07C17/357 ,  C07C17/25

    CPC分类号： C07C21/18 ,  C07C17/23 ,  C07C17/25 ,  C07C17/278 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/126 ,  C07C19/10

    摘要： A process is disclosed for making CF3CF═CH2 or mixtures thereof with CHF═CFCHF2. The process involves contacting CCl3CF2CF3 and optionally CCl2FCF2CClF2 with H2 in the presence of a palladium catalyst supported on a support of alumina, fluorided alumina and/or aluminum fluoride, to produce a product mixture including CH2═CFCF3 (and when CCl2FCF2CClF2 is present, CHF═CFCHF2); recovering CH2═CFCF3 or a mixture thereof with CHF═CFCHF2 from the product mixture. The present invention also provides another process that involves reacting CCl3CF2CF3 and optionally CCl2FCF2CClF2 with H2 in the presence of a hydrogenation catalyst to form CH3CF2CF3 (and when CCl2FCF2CClF2 is present, CH2FCF2CHF2); dehydrofluorinating; and recovering CH2═CFCF3 or a mixture thereof with CHF═CFCHF2.

    摘要翻译： 公开了制备CF 3CF≡CH2或其与CHF = CFCHF 2的混合物的方法。 该方法包括在负载在氧化铝，氟化氧化铝和/或氟化铝载体上的钯催化剂存在下，将CCl 3 CF 2 CF 3和任选的CCl 2 FFCFCl 2与H 2接触，以产生包含CH 2 = CFCF 3的产物混合物（当存在CCl 2 CFF 2 CClF 2时，CHF = CFCHF 2）; 从产物混合物中回收CH 2 = CFCF 3或其与CHF = CFCHF 2的混合物。 本发明还提供了另一种方法，其包括在氢化催化剂存在下使CCl 3 CF 2 CF 3和任选的CCl 2 F F 2​​ CClF 2与H 2反应以形成CH 3 CF 2 CF 3（当存在CCl 2 CFF 2 CClF 2时，CH 2 F 2 F F F 2​​）; 脱氟化氢; 并回收CH 2 = CFFF 3或其与CHF = CFCHF 2的混合物。