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公开(公告)号：US09123899B2
公开(公告)日：2015-09-01
申请号：US13024425
申请日：2011-02-10
申请人： Anthony J. Wigglesworth , Yiliang Wu , Ping Liu
发明人： Anthony J. Wigglesworth , Yiliang Wu , Ping Liu
IPC分类号： H01L51/00 , C07D471/06 , H01L51/05
CPC分类号： H01L51/0072 , C07D471/06 , H01L51/0076 , H01L51/0541 , H01L51/0545
摘要： A semiconducting tetrahydroacridinoacridine compound of Formula (I): wherein R1 to R12 are as described herein. The compounds are designed to ensure air stability, good solubility, and high mobility.
摘要翻译： 式（I）的半导体四氢吖啶吖啶化合物：其中R 1至R 12如本文所述。 这些化合物被设计成确保空气稳定性，良好的溶解性和高迁移率。
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公开(公告)号：US08558109B2
公开(公告)日：2013-10-15
申请号：US13424204
申请日：2012-03-19
IPC分类号： H01L31/00
CPC分类号： H01L51/0036 , H01L51/0558 , Y02E10/549
摘要： A copolymer having a structure represented by: wherein R1 and R2 are independently selected from a hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group; Ar1 and Ar2 are independently an aromatic or heteroaromatic group including about 4 to about 30 carbon atoms, and can be optionally substituted; a and b are independently an integer from 1 to about 4; Ar3 and Ar4 are independently an aromatic or heteroaromatic group comprising about 4 to about 20 carbon atoms, and can be optionally substituted; c and e are independently an integer from about 0 to about 2; d is 1 to 4 and the carbon-carbon double bond is in the E-configuration; and n represents a number from 2 to about 5,000.
摘要翻译： 具有以下结构的共聚物：其中R1和R2独立地选自氢，取代或未取代的烷基，取代或未取代的芳基或取代或未取代的杂芳基; Ar 1和Ar 2独立地是包括约4至约30个碳原子的芳族或杂芳族基团，并且可以任选被取代; a和b独立地为1至约4的整数; Ar 3和Ar 4独立地是包含约4至约20个碳原子的芳族或杂芳基，并且可以任选被取代; c和e独立地为约0至约2的整数; d为1〜4，碳 - 碳双键为E构型; n表示2〜5000的数。
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13.发明申请PHOTOCHROMIC AND ELETROCHROMIC COMPOUNDS AND METHODS OF SYNTHESIZING AND USING SAME 有权光致变色和非光致变色化合物及其合成和使用方法公开(公告)号：US20110003966A1
公开(公告)日：2011-01-06
申请号：US12828756
申请日：2010-07-01
IPC分类号： C08G75/00 , C07D495/04 , C07D409/08
CPC分类号： C07D495/04 , C08G61/02 , C08G61/126 , C09K9/02 , C09K2211/1458 , G03H2001/0264 , G03H2260/52 , Y10T428/1041
摘要： This invention relates to novel photochromic and electrochromic monomers and polymers based on 1,2-dithienylcyclopentene derivatives and method of using and synthesizing same. The compounds are reversibly interconvertible between different isomeric forms under suitable photochromic or electrochromic conditions. The electrochromic conversion may be catalytic. The application also relates to ultra-high density homopolymers prepared using ring-opening methathesis polymerization (ROMP) where the central ring of the 1,2-bis(3-thienyl)-cyclopentene is incorporated directly into the polymer backbone. The monomer units may be readily functionalized to enable the synthesis of polymers with diverse structural and electronic properties. The compounds have many potential applications including high-density optical information storage systems, photoregulated molecular switches, reversible holographic systems, ophthalmic lenses, actinometry and molecular sensors, photochromic inks, paints and fibers and optoelectronic systems such as optical waveguides, Bragg reflectors and dielectric mirrors.
摘要翻译： 本发明涉及基于1,2-二噻吩环戊烯衍生物的新型光致变色和电致变色单体和聚合物及其使用和合成方法。 在合适的光致变色或电致变色条件下，化合物在不同的异构体形式之间是可逆的相互转化的。 电致变色可能是催化的。 本申请还涉及使用开环错译聚合（ROMP）制备的超高密度均聚物，其中1,2-双（3-噻吩基） - 环戊烯的中心环直接并入聚合物主链。 单体单元可以容易地官能化以使得能够合成具有不同结构和电子性质的聚合物。 这些化合物具有许多潜在的应用，包括高密度光学信息存储系统，光调节分子开关，可逆全息系统，眼用透镜，光化学测量和分子传感器，光致变色油墨，油漆和纤维以及光电子系统，例如光波导，布拉格反射器和电介质反射镜 。
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14.发明授权Photochromic and electrochromic compounds and methods of synthesizing and using same 有权光致变色和电致变色化合物及其合成和使用方法公开(公告)号：US07777055B2
公开(公告)日：2010-08-17
申请号：US10523965
申请日：2003-08-11
IPC分类号： C07D333/50 , C07D409/14
CPC分类号： C07D495/04 , C08G61/02 , C08G61/126 , C09K9/02 , C09K2211/1458 , G03H2001/0264 , G03H2260/52 , Y10T428/1041
摘要： This invention relates to novel photochromic and electrochromic monomers and polymers based on 1,2-dithienylcyclopentene derivatives and method of using and synthesizing same. The compounds are reversibly interconvertible between different isomeric forms under suitable photochromic or electrochromic conditions. The electrochromic conversion may be catalytic. The application also relates to ultra-high density homopolymers prepared using ring-opening methathesis polymerization (ROMP) where the central ring of the 1,2-bis(3-thienyl)-cyclopentene is incorporated directly into the polymer backbone. The monomer units may be readily functionalized to enable the synthesis of polymers with diverse structural and electronic properties. The compounds have many potential applications including high-density optical information storage systems, photoregulated molecular switches, reversible holographic systems, ophthalmic lenses, actinometry and molecular sensors, photochromic inks, paints and fibers and optoelectronic systems such as optical waveguides, Bragg reflectors and dielectric mirrors.
摘要翻译： 本发明涉及基于1,2-二噻吩环戊烯衍生物的新型光致变色和电致变色单体和聚合物及其使用和合成方法。 在合适的光致变色或电致变色条件下，化合物在不同的异构体形式之间是可逆的相互转化的。 电致变色可能是催化的。 本申请还涉及使用开环错译聚合（ROMP）制备的超高密度均聚物，其中1,2-双（3-噻吩基） - 环戊烯的中心环直接并入聚合物主链。 单体单元可以容易地官能化以使得能够合成具有不同结构和电子性质的聚合物。 这些化合物具有许多潜在的应用，包括高密度光学信息存储系统，光调节分子开关，可逆全息系统，眼用透镜，光化学测量和分子传感器，光致变色油墨，油漆和纤维以及光电子系统，例如光波导，布拉格反射器和电介质反射镜 。
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15.发明授权Photochromic and electrochromic compounds and methods of synthesizing and using same 有权光致变色和电致变色化合物及其合成和使用方法公开(公告)号：US08450503B2
公开(公告)日：2013-05-28
申请号：US12828756
申请日：2010-07-01
IPC分类号： C07D333/50 , C07D409/02
CPC分类号： C07D495/04 , C08G61/02 , C08G61/126 , C09K9/02 , C09K2211/1458 , G03H2001/0264 , G03H2260/52 , Y10T428/1041
摘要： This invention relates to novel photochromic and electrochromic monomers and polymers based on 1,2-dithienylcyclopentene derivatives and method of using and synthesizing same. The compounds are reversibly interconvertible between different isomeric forms under suitable photochromic or electrochromic conditions. The electrochromic conversion may be catalytic. The application also relates to ultra-high density homopolymers prepared using ring-opening methathesis polymerization (ROMP) where the central ring of the 1,2-bis(3-thienyl)-cyclopentene is incorporated directly into the polymer backbone. The monomer units may be readily functionalized to enable the synthesis of polymers with diverse structural and electronic properties. The compounds have many potential applications including high-density optical information storage systems, photoregulated molecular switches, reversible holographic systems, ophthalmic lenses, actinometry and molecular sensors, photochromic inks, paints and fibers and optoelectronic systems such as optical waveguides, Bragg reflectors and dielectric mirrors.
摘要翻译： 本发明涉及基于1,2-二噻吩环戊烯衍生物的新型光致变色和电致变色单体和聚合物及其使用和合成方法。 在合适的光致变色或电致变色条件下，化合物在不同的异构体形式之间是可逆的相互转化的。 电致变色可能是催化的。 本申请还涉及使用开环错译聚合（ROMP）制备的超高密度均聚物，其中1,2-双（3-噻吩基） - 环戊烯的中心环直接并入聚合物主链。 单体单元可以容易地官能化以使得能够合成具有不同结构和电子性质的聚合物。 这些化合物具有许多潜在的应用，包括高密度光学信息存储系统，光调节分子开关，可逆全息系统，眼用透镜，光化学测量和分子传感器，光致变色油墨，油漆和纤维以及光电子系统，如光波导，布拉格反射器和电介质镜 。
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