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公开(公告)号：US09914815B2
公开(公告)日：2018-03-13
申请号：US15015184
申请日：2016-02-04
Applicant: Arkema Inc.
Inventor： Benjamin Bin Chen , Joseph S. Costa , Philippe Bonnet , Maher Y. Elsheikh , Brett L. Van Horn
CPC classification number: C08J9/144 , B01F17/0085 , C08G18/06 , C08J9/146 , C08J9/149 , C08J2203/142 , C08J2203/162 , C08J2203/182 , C08J2300/104 , C08J2300/106 , C08J2375/04
Abstract: A blowing agent for thermosetting foams is disclosed. The blowing agent is a hydrofluoroolefin (HCFO), preferably HFCO-1234yf in combination with a hydrochlorofluoroolefin (HCFO) preferably one selected from HCFO-1233zd, HCFO-1223, HCFO-1233xf and mixtures thereof. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.
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公开(公告)号：US09404678B2
公开(公告)日：2016-08-02
申请号：US14188986
申请日：2014-02-25
Applicant: Arkema Inc.
Inventor： Brett L. Van Horn , Philippe Bonnet , Laurent Abbas
CPC classification number: C09K5/044 , C09K3/30 , C09K5/045 , C09K2205/112 , C09K2205/122 , C09K2205/126 , C09K2205/32 , C09K2205/40 , C09K2205/41 , C10M171/008 , C10M2203/065 , C10M2203/1006 , C10M2205/028 , C10M2205/0285 , C10M2205/223 , C10M2207/2835 , C10M2209/043 , C10M2209/1033 , C10N2040/30 , C10N2220/301 , C10N2220/302 , C10N2220/303 , C10N2220/305 , C10N2240/30 , F25B1/005 , F25B1/053 , F25B1/10 , F25B9/006 , F25B31/002 , F25B45/00 , F25B2339/047 , F25B2400/18
Abstract: This invention relates to the use of chloro-trifluoropropenes as refrigerants in negative-pressure liquid chillers and methods of replacing an existing refrigerant in a chiller with chloro-trifluoropropenes. The chloro-trifluoropropenes, particularly 1-chloro-3,3,3-trifluoropropene, have high efficiency and unexpectedly high capacity in liquid chiller applications and are useful as more environmentally sustainable refrigerants for such applications, including the replacement of R-123 and R-11.
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13.发明申请公开(公告)号：US20140213678A1
公开(公告)日：2014-07-31
申请号：US14243048
申请日：2014-04-02
Applicant: Arkema Inc.
Inventor： Brett L. Van Horn , Maher Y. Elsheikh , Benjamin Bin Chen , Philippe Bonnet
IPC: C08J9/14
CPC classification number: C08J9/144 , C08J9/127 , C08J9/142 , C08J9/146 , C08J9/149 , C08J2203/12 , C08J2203/162 , C08J2203/182 , C08J2203/202 , C08J2325/06 , Y10T428/249953
Abstract: The present invention relates to blowing agent compositions comprising (1) at least one hydrofluoroolefin (HFO) and (2) at least one hydrochlorofluoroolefin (HCFO) used in the preparation of foamable thermoplastic compositions. The HFOs of component (1) include, but are not limited too, 3,3,3-trifluoropropene (HFO-1243zf), 1,2,3,3,3 -pentafluoropropene (HFO-1225ye), cis- and/or trans-1,3,33-tetrafluoropropene (HFO-1234ze), and 2,3,3,3-tetrafluoropropene (HFO 1234yf), and mixtures thereof. The HCFOs of component (2) include, but are not limited to, 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd), 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf) and mixtures thereof. The blowing agent compositions are useful in the production of low density insulating foams with improved k-factor.
Abstract translation: 本发明涉及包含（1）至少一种氢氟烯烃（HFO）和（2）用于制备可发泡热塑性组合物的至少一种氢氯氟烯烃（HCFO）的发泡剂组合物。 组分（1）的HFO包括但不限于3,3,3-三氟丙烯（HFO-1243zf），1,2,3,3,3-五氟丙烯（HFO-1225ye），顺式和/或 反式-1,3,33-四氟丙烯（HFO-1234ze）和2,3,3,3-四氟丙烯（HFO 1234yf）及其混合物。 组分（2）的HCFO包括但不限于1-氯-3,3,3-三氟丙烯（HCFO-1233zd），2-氯-3,3,3-三氟丙烯（HCFO-1233xf）和混合物 其中。 发泡剂组合物可用于生产具有改进的k因子的低密度绝缘泡沫。
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14.发明授权公开(公告)号：US08772364B2
公开(公告)日：2014-07-08
申请号：US13914711
申请日：2013-06-11
Applicant: Arkema Inc.
Inventor： Brett L. Van Horn , Maher Y. Elsheikh , Benjamin Bin Chen , Philippe Bonnet
CPC classification number: C08J9/144 , C08J9/127 , C08J9/142 , C08J9/146 , C08J9/149 , C08J2203/12 , C08J2203/162 , C08J2203/182 , C08J2203/202 , C08J2325/06 , Y10T428/249953
Abstract: The present invention relates to blowing agent compositions comprising (1) at least one hydrofluoroolefin (HFO) and (2) at least one hydrochlorofluoroolefin (HCFO) used in the preparation of foamable thermoplastic compositions. The HFOs of component (1) include, but are not limited too, 3,3,3-trifluoropropene (HFO-1243zf), 1,2,3,3,3-pentafluoropropene (HFO-1225ye), cis- and/or trans-1,3,3,3-tetrafluoropropene (HFO-1234ze), and 2,3,3,3-tetrafluoropropene (HFO 1234yf), and mixtures thereof. The HCFOs of component (2) include, but are not limited to, 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd), 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf) and mixtures thereof. The blowing agent compositions are useful in the production of low density insulating foams with improved k-factor.
Abstract translation: 本发明涉及包含（1）至少一种氢氟烯烃（HFO）和（2）用于制备可发泡热塑性组合物的至少一种氢氯氟烯烃（HCFO）的发泡剂组合物。 组分（1）的HFO包括但不限于3,3,3-三氟丙烯（HFO-1243zf），1,2,3,3,3-五氟丙烯（HFO-1225ye），顺式和/或 反式-1,3,3,3-四氟丙烯（HFO-1234ze）和2,3,3,3-四氟丙烯（HFO 1234yf）及其混合物。 组分（2）的HCFO包括但不限于1-氯-3,3,3-三氟丙烯（HCFO-1233zd），2-氯-3,3,3-三氟丙烯（HCFO-1233xf）和混合物 其中。 发泡剂组合物可用于生产具有改进的k因子的低密度绝缘泡沫。
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公开(公告)号：US08691107B2
公开(公告)日：2014-04-08
申请号：US13778584
申请日：2013-02-27
Applicant: Arkema Inc.
Inventor： Maher Y. Elsheikh , Brett L. Van Horn , Philippe Bonnet , Benjamin Bin Chen
IPC: C09K5/00
CPC classification number: C09K5/045 , A62D1/0028 , A62D1/0057 , C08F2/42 , C08J9/144 , C08J9/146 , C08J9/149 , C08J2325/06 , C08J2375/04 , C09K3/30 , C09K5/044 , C09K2205/126 , C11D3/0073 , C11D3/0084 , C11D7/5018 , C23G5/02809 , C23G5/02861
Abstract: Disclosed is a combination of hydrofluoroolefins and/or hydrochlorofluoroolefins with stabilizers wherein the stabilizers minimize the degradation of the hydrofluoroolefins and hydrochlorofluoroolefins during storage, handling and use yet allow for atmospheric degradation. The combinations exhibit low or zero ozone depletion potential and lower global warming potential making them of interest as replacements for chlorofluorocarbons and hydrfluorocarbons. The combinations of the present invention comprise hydrofluoroolefins and/or hydrochlorofluoroolefins in combination with a stabilizer or stabilizers selected from free radical scavengers, acid scavengers, oxygen scavengers, polymerization inhibitors and combinations thereof.
Abstract translation: 公开了氢氟烯烃和/或氢氯氟烯烃与稳定剂的组合，其中稳定剂使储存，处理和使用期间氢氟烯烃和氢氯氟烯烃的降解最小化，但允许大气降解。 这些组合表现出低或零臭氧消耗潜能和较低的全球变暖潜能，使其成为氯氟烃和氢氟碳化物的替代品。 本发明的组合包括与选自自由基清除剂，酸清除剂，除氧剂，聚合抑制剂及其组合的稳定剂或稳定剂组合的氢氟烯烃和/或氢氯氟烯烃。
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Patent Agency Ranking
16.发明授权公开(公告)号：US09303900B2
公开(公告)日：2016-04-05
申请号：US13873266
申请日：2013-04-30
Applicant: Arkema Inc.
Inventor： Brett L. Van Horn , Philippe Bonnet , Benjamin Bin Chen , Maher Y. Elsheikh , Richard M. Crooker
IPC: C09K5/04 , F25B1/00 , C09K3/30 , C10M171/00 , F25B45/00
CPC classification number: C09K5/044 , C09K3/30 , C09K5/045 , C09K2205/112 , C09K2205/122 , C09K2205/126 , C09K2205/32 , C09K2205/40 , C09K2205/41 , C10M171/008 , C10M2203/065 , C10M2203/1006 , C10M2205/028 , C10M2205/0285 , C10M2205/223 , C10M2207/2835 , C10M2209/043 , C10M2209/1033 , C10N2040/30 , C10N2220/301 , C10N2220/302 , C10N2220/303 , C10N2220/305 , C10N2240/30 , F25B1/005 , F25B1/053 , F25B1/10 , F25B9/006 , F25B31/002 , F25B45/00 , F25B2339/047 , F25B2400/18
Abstract: The invention relates to heat transfer agents and heat transfer compositions containing hydrocarbon lubricating oils and halogenated alkene heat transfer fluid that promote oil flow and provide for improved oil return. The heat transfer compositions are useful in various heat transfer systems such as refrigeration, cooling, air conditioning, chiller operations.
Abstract translation: 本发明涉及含有烃润滑油和卤代烯烃传热流体的传热剂和传热组合物，其促进油流并提供改进的回油。 传热组合物可用于各种传热系统，例如制冷，冷却，空调，冷却器操作。
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公开(公告)号：US09254468B2
公开(公告)日：2016-02-09
申请号：US14132263
申请日：2013-12-18
Applicant: Arkema Inc.
Inventor： Brett L. Van Horn , Maher Y. Elsheikh , Benjamin Bin Chen , Philippe Bonnet
CPC classification number: C09K5/04 , B01F17/0085 , C09K5/00 , C09K5/044 , C10M171/008 , C10M2203/065 , C10M2205/0285 , C10M2207/2835 , C10M2209/043 , C10M2209/1033 , C10N2220/302
Abstract: The present invention relates to formulated refrigerant systems of 1-chloro-3,3,3-trifluoropropene (R-1233zd) that are sufficiently thermally and chemically stable such that they can be effectively used sans additional stabilizers. The formulations of the present invention are particularly useful compositions for refrigeration, heat transfer and foam blowing.
Abstract translation: 本发明涉及足够热和化学稳定的1-氯-3,3,3-三氟丙烯（R-1233zd）的配制的制冷剂体系，使得它们可以有效地用于另外的稳定剂。 本发明的制剂是用于制冷，传热和发泡的特别有用的组合物。
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公开(公告)号：US09234070B2
公开(公告)日：2016-01-12
申请号：US13649346
申请日：2012-10-11
Applicant: Arkema Inc.
Inventor： Benjamin Bin Chen , Maher Y. Elsheikh , Philippe Bonnet , Brett L. Van Horn , Joseph S. Costa
CPC classification number: C08G18/7664 , C08G18/4018 , C08G18/482 , C08G18/6674 , C08G2101/00 , C08J9/144 , C08J9/146 , C08J9/149 , C08J2203/142 , C08J2203/162 , C08J2203/182 , C08J2375/04
Abstract: A blowing agent for thermosetting foams is disclosed. The blowing agent is predominately the trans isomer of the hydrochlorofluoroolefin (HCFO) HFCO-1233zd alone or in combination with a hydrofluoroolefin (HFO), hydrofluorocarbon (HFC), hydrochlorofluoroolefin (HCFO), a hydrocarbon. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.
Abstract translation: 公开了一种用于热固性泡沫的发泡剂。 发泡剂主要是氢氯氟烯烃（HCFO）HFCO-1233zd单独或与氢氟烯烃（HFO），氢氟烃（HFC），氢氯氟烯烃（HCFO），烃类的组合的反式异构体。 发泡剂在制造热固性泡沫时作为发泡剂是有效的。
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公开(公告)号：US09206297B2
公开(公告)日：2015-12-08
申请号：US14519456
申请日：2014-10-21
Applicant: Arkema Inc.
Inventor： Brett L. Van Horn , Maher Y. Elsheikh , Benjamin Bin Chen , Philippe Bonnet
CPC classification number: C08J9/144 , C08J9/122 , C08J9/127 , C08J9/141 , C08J9/146 , C08J9/149 , C08J2201/03 , C08J2203/06 , C08J2203/14 , C08J2203/162 , C08J2203/182 , C08J2203/202 , C08J2205/052 , C08J2323/06 , C08J2323/12 , C08J2325/06
Abstract: The present invention relates to foam products made with blowing agent compositions comprising at least one hydrochlorofluoroolefin (HCFO) used in the preparation of foamable thermoplastic compositions. The HCFOs of the present invention include, but are not limited to, 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd), particularly the trans-isomer, 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), dichloro-fluorinated propenes, and mixtures thereof. The blowing agent compositions of the present invention are used with coblowing agents including carbon dioxide, atmospheric gases, hydrofluorocarbons (HFC), hydrofluoroolefins (HFO), alkanes, hydrofluoroethers (HFE), and mixtures thereof. Preferred HFCs used as coblowing agents in the present invention include, but are not limited too, 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1-difluoroethane (HFC-152a), 1,1,1-trifluoroethane (HFC-143a), pentafluorethane (HFC-125), difluoromethane (HFC-32). The blowing agent compositions are useful in the production of low density insulating foams with improved k-factor.
Abstract translation: 本发明涉及由用于制备可发泡热塑性组合物的至少一种氢氯氟烯烃（HCFO）的发泡剂组合物制成的泡沫产品。 本发明的HCFO包括但不限于1-氯-3,3,3-三氟丙烯（HCFO-1233zd），特别是反式异构体2-氯-3,3,3-三氟丙烯（HCFO -1233xf），二氯氟化丙烯及其混合物。 本发明的发泡剂组合物与包括二氧化碳，大气，氢氟烃（HFC），氢氟烯烃（HFO），烷烃，氢氟醚（HFE）及其混合物的助熔剂一起使用。 在本发明中用作起泡剂的优选的HFCs包括但不限于1,1,1,2-四氟乙烷（HFC-134a），1,1-二氟乙烷（HFC-152a），1,1,1-三氟乙烷 三氟乙烷（HFC-143a），五氟乙烷（HFC-125），二氟甲烷（HFC-32）。 发泡剂组合物可用于生产具有改进的k因子的低密度绝缘泡沫。
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20.发明授权Method of obtaining a combination of Z and E stereoisomers of hydrofluoroolefins 有权获得氢氟烯烃的Z和E立体异构体的组合的方法公开(公告)号：US09181154B2
公开(公告)日：2015-11-10
申请号：US13939233
申请日：2013-07-11
Applicant: Arkema Inc.
Inventor： Philippe Bonnet , Maher Y. Elsheikh
IPC: C07C17/358 , C07C17/383 , C07C17/38 , C07C17/386 , C07C17/389 , C07C21/18 , C08J9/14 , C09K3/30 , C09K5/04
CPC classification number: C07C17/358 , C07C17/38 , C07C17/383 , C07C17/386 , C07C17/389 , C07C21/18 , C08J9/146 , C09K3/30 , C09K5/045 , C09K2205/126 , C09K2205/22 , Y02P20/127
Abstract: Disclosed are the combinations containing Z and E stereoisomers of hydrofluoroolefins where the more toxic isomer is less than about 30% weight of the combination (vs the sum of Z+E), to minimize the toxicity impact in the applications they will be used for such as cooling and heat fluids, foams blowing agents or solvents. Also disclosed are means to obtain combinations containing Z and E stereoisomers of hydrofluoroolefins.
Abstract translation: 公开了含有氢氟烯烃的Z和E立体异构体的组合，其中较毒的异构体小于组合的约30重量％（相对于Z + E的总和），以最小化其将用于这些的应用中的毒性影响 作为冷却和热流体，泡沫发泡剂或溶剂。 还公开了获得含有氢氟烯烃的Z和E立体异构体的组合的方法。
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