公开(公告)号：US12214548B2

公开(公告)日：2025-02-04

申请号：US16321079

申请日：2017-07-21

Applicant: BASF SE

Inventor： Claus Gabriel ,  Martin Weber ,  Philipp Kloke ,  Thomas Meier

IPC: B29C64/153 ,  B29K71/00 ,  B29K77/00 ,  B29K81/00 ,  B33Y10/00 ,  B33Y70/00 ,  B33Y80/00 ,  C08L71/12 ,  C08L77/02 ,  C08L81/06

Abstract: The present invention relates to a process for producing a shaped body by selective laser sintering of a sinter powder (SP). The sinter powder (SP) comprises at least one semicrystalline polyamide, at least one nylon-6I/6T and at least one polyaryl ether. The present invention further relates to a shaped body obtainable by the process of the invention and to the use of a polyaryl ether in a sinter powder (SP) for broadening the sintering window (WSP) of the sinter powder (SP).

公开(公告)号：US11613074B2

公开(公告)日：2023-03-28

申请号：US16652839

申请日：2018-10-01

Applicant: BASF SE

Inventor： Claus Gabriel ,  Natalie Beatrice Janine Herle ,  Thomas Meier ,  Michael Roth

IPC: B29C64/153 ,  B29C64/165 ,  B33Y70/10 ,  B33Y10/00 ,  B33Y80/00 ,  B29K77/00 ,  B29K305/02

Abstract: The present invention relates to a process for producing a shaped body, wherein, in step i), a layer of a sinter powder (SP) comprising at least one mineral flame retardant inter alia is provided and, in step ii), the layer provided in step i) is exposed. The present invention further relates to a process for producing a sinter powder (SP) and to a sinter powder (SP) obtainable by this process. The present invention also relates to the use of the sinter powder (SP) in a sintering process and to shaped bodies obtainable by the process of the invention.

公开(公告)号：US10655013B2

公开(公告)日：2020-05-19

申请号：US16259408

申请日：2019-01-28

Applicant: BASF SE

Inventor： Claus Gabriel ,  Manoranjan Prusty ,  Martin Baumert ,  Norbert Güntherberg

IPC: C08L77/06 ,  C08L77/00 ,  C08K3/08 ,  C08K3/16 ,  C08K3/32 ,  C08L23/08 ,  C08L25/08 ,  C08L25/16 ,  C08L35/06 ,  C08L79/02

Abstract: Thermoplastic molding compositions comprising A) from 10 to 99.7% by weight of a polyamide, B) from 1 to 30% by weight of an impact modifier, C) from 0.1 to 10% by weight of a copolymer of C1) from 50 to 95% by weight of styrene or substituted styrenes of the general formula I or a mixture of these in which R is an alkyl radical having from 1 to 8 carbon atoms or a hydrogen atom and R1 is an alkyl radical having from 1 to 8 carbon atoms and n has the value 0, 1, 2, or 3, and C2) from 5 to 50% by weight of structural units derived from one or more dicarboxylic anhydrides, D) from 0.001 to 20% by weight of iron powder, E) from 0.05 to 3% by weight of a copper-containing stabilizer, F) from 100 ppm to 5% by weight of a phosphorus-containing, inorganic acid or salts thereof or ester derivatives thereof or a mixture thereof, G) from 0 to 2% by weight of a polyethyleneimine homo- or copolymer, H) from 0 to 60% by weight of further additives, where the total of the percentages by weight of A) to H) is 100%.

公开(公告)号：US20190153223A1

公开(公告)日：2019-05-23

申请号：US16259408

申请日：2019-01-28

Applicant: BASF SE

Inventor： Claus Gabriel ,  Manoranjan Prusty ,  Martin Baumert ,  Norbert Güntherberg

IPC: C08L77/06 ,  C08L77/00 ,  C08L79/02 ,  C08L35/06 ,  C08L25/16 ,  C08K3/08 ,  C08L23/08 ,  C08K3/32 ,  C08K3/16 ,  C08L25/08

Abstract: Thermoplastic molding compositions comprising A) from 10 to 99.7% by weight of a polyamide, B) from 1 to 30% by weight of an impact modifier, C) from 0.1 to 10% by weight of a copolymer of C1) from 50 to 95% by weight of styrene or substituted styrenes of the general formula I or a mixture of these in which R is an alkyl radical having from 1 to 8 carbon atoms or a hydrogen atom and R1 is an alkyl radical having from 1 to 8 carbon atoms and n has the value 0, 1, 2, or 3, and C2) from 5 to 50% by weight of structural units derived from one or more dicarboxylic anhydrides, D) from 0.001 to 20% by weight of iron powder, E) from 0.05 to 3% by weight of a copper-containing stabilizer, F) from 100 ppm to 5% by weight of a phosphorus-containing, inorganic acid or salts thereof or ester derivatives thereof or a mixture thereof, G) from 0 to 2% by weight of a polyethyleneimine homo- or copolymer, H) from 0 to 60% by weight of further additives, where the total of the percentages by weight of A) to H) is 100%.

公开(公告)号：US20140323631A1

公开(公告)日：2014-10-30

申请号：US14359355

申请日：2012-11-14

Applicant: BASF SE

Inventor： Claus Gabriel ,  Manoranjan Prusty ,  Martin Baumert ,  Norbert Güntherberg

IPC: C08L77/06

CPC classification number: C08L77/06 ,  C08K3/08 ,  C08K3/16 ,  C08K3/32 ,  C08L23/08 ,  C08L23/0846 ,  C08L25/08 ,  C08L25/16 ,  C08L35/06 ,  C08L77/00 ,  C08L79/02

Abstract: Thermoplastic molding compositions comprising A) from 10 to 99.7% by weight of a polyamide, B) from 1 to 30% by weight of an impact modifier, C) from 0.1 to 10% by weight of a copolymer of C1) from 50 to 95% by weight of styrene or substituted styrenes of the general formula I or a mixture of these in which R is an alkyl radical having from 1 to 8 carbon atoms or a hydrogen atom and R1 is an alkyl radical having from 1 to 8 carbon atoms and n has the value 0, 1, 2, or 3, and C2) from 5 to 50% by weight of structural units derived from one or more dicarboxylic anhydrides, D) from 0.001 to 20% by weight of iron powder, E) from 0.05 to 3% by weight of a copper-containing stabilizer, F) from 100 ppm to 5% by weight of a phosphorus-containing, inorganic acid or salts thereof or ester derivatives thereof or a mixture thereof, G) from 0 to 2% by weight of a polyethyleneimine homo- or copolymer, H) from 0 to 60% by weight of further additives, where the total of the percentages by weight of A) to H) is 100%.

Abstract translation: 热塑性模塑组合物，其包含A）10至99.7重量％的聚酰胺，B）1至30重量％的抗冲改性剂，C）0.1至10重量％的C1至50重量％的共聚物 重量％的苯乙烯或通式I的取代苯乙烯或这些的混合物，其中R是具有1至8个碳原子的烷基或氢原子，R 1是具有1至8个碳原子的烷基和 n为0至1，2或3，C2为5至50重量％的衍生自一种或多种二羧酸酐的结构单元，D）0.001至20重量％的铁粉，E） 0.05〜3重量％的含铜稳定剂，F）100重量％〜5重量％的含磷无机酸或其盐或其酯衍生物或其混合物，G）0〜2重量％ 重量的聚乙烯亚胺均聚物或共聚物，H）0至60重量％的其它添加剂，其中A） 至H）为100％。

公开(公告)号：US20130253110A1

公开(公告)日：2013-09-26

申请号：US13847801

申请日：2013-03-20

Applicant: BASF SE

Inventor： Claus Gabriel ,  Hans-Werner Schmidt ,  Florian Richter

IPC: C08K5/21

CPC classification number: C08K5/21 ,  C08L77/00

Abstract: The present invention relates to the use of at least one urea compound of the formula I where x is 1, 2 or 3; R1 and R2 are selected from hydrogen, linear C1-C7-alkyl, branched C3-C10-alkyl, unsubstituted or substituted C3-C12-cycloalkyl, unsubstituted or substituted C3-C12-cycloalkyl-C1-C4-alkyl, unsubstituted or substituted aryl and unsubstituted or substituted aryl-C1-C4-alkyl; and Z is selected from C3-C10-alkanediyl, unsubstituted or substituted arylene, unsubstituted or substituted arylene-C1-C4-alkylene-arylene, unsubstituted or substituted heteroarylene, unsubstituted or substituted heteroarylene-C1-C4-alkylene-heteroarylene, unsubstituted or substituted C5-C8-cycloalkylene, unsubstituted or substituted C5-C8-cycloalkylene-C1-C4-alkylene-C5-C8-cycloalkylene, unsubstituted or substituted heterocycloalkylene and unsubstituted or substituted heterocycloalkylene-C1-C4-alkylene-heterocycloalkylene for improving at least one solid state property of a polyamide resin. The solid state property is preferably selected from mechanical properties and gloss.

Abstract translation: 本发明涉及使用至少一种式I的脲化合物，其中x为1,2或3; R 1和R 2选自氢，直链C 1 -C 7 - 烷基，支链C 3 -C 10 - 烷基，未取代或取代的C 3 -C 12 - 环烷基，未取代或取代的C 3 -C 12 - 环烷基-C 1 -C 4烷基，未取代或取代的芳基 和未取代或取代的芳基-C 1 -C 4 - 烷基; Z为选自C 3 -C 10 - 烷二基，未取代或取代的亚芳基，未取代或取代的亚芳基-C 1 -C 4亚烷基亚芳基，未取代或取代的亚杂芳基，未取代或取代的杂亚芳基-C 1 -C 4 - 亚烷基 - 亚杂芳基，未取代或取代的 C5-C8-亚环烷基，未取代或取代的C5-C8-亚环烷基-C1-C4-亚烷基-C5-C8-亚环烷基，未取代或取代的杂环亚烷基和未取代或取代的亚环烷基-C 1 -C 4 - 亚烷基 - 亚杂烷基亚烷基，用于改善至少一种固体 聚酰胺树脂的状态特性。 固态性质优选选自机械性能和光泽度。