公开(公告)号：US20130253110A1

公开(公告)日：2013-09-26

申请号：US13847801

申请日：2013-03-20

Applicant: BASF SE

Inventor： Claus Gabriel ,  Hans-Werner Schmidt ,  Florian Richter

IPC: C08K5/21

CPC classification number: C08K5/21 ,  C08L77/00

Abstract: The present invention relates to the use of at least one urea compound of the formula I where x is 1, 2 or 3; R1 and R2 are selected from hydrogen, linear C1-C7-alkyl, branched C3-C10-alkyl, unsubstituted or substituted C3-C12-cycloalkyl, unsubstituted or substituted C3-C12-cycloalkyl-C1-C4-alkyl, unsubstituted or substituted aryl and unsubstituted or substituted aryl-C1-C4-alkyl; and Z is selected from C3-C10-alkanediyl, unsubstituted or substituted arylene, unsubstituted or substituted arylene-C1-C4-alkylene-arylene, unsubstituted or substituted heteroarylene, unsubstituted or substituted heteroarylene-C1-C4-alkylene-heteroarylene, unsubstituted or substituted C5-C8-cycloalkylene, unsubstituted or substituted C5-C8-cycloalkylene-C1-C4-alkylene-C5-C8-cycloalkylene, unsubstituted or substituted heterocycloalkylene and unsubstituted or substituted heterocycloalkylene-C1-C4-alkylene-heterocycloalkylene for improving at least one solid state property of a polyamide resin. The solid state property is preferably selected from mechanical properties and gloss.

Abstract translation: 本发明涉及使用至少一种式I的脲化合物，其中x为1,2或3; R 1和R 2选自氢，直链C 1 -C 7 - 烷基，支链C 3 -C 10 - 烷基，未取代或取代的C 3 -C 12 - 环烷基，未取代或取代的C 3 -C 12 - 环烷基-C 1 -C 4烷基，未取代或取代的芳基 和未取代或取代的芳基-C 1 -C 4 - 烷基; Z为选自C 3 -C 10 - 烷二基，未取代或取代的亚芳基，未取代或取代的亚芳基-C 1 -C 4亚烷基亚芳基，未取代或取代的亚杂芳基，未取代或取代的杂亚芳基-C 1 -C 4 - 亚烷基 - 亚杂芳基，未取代或取代的 C5-C8-亚环烷基，未取代或取代的C5-C8-亚环烷基-C1-C4-亚烷基-C5-C8-亚环烷基，未取代或取代的杂环亚烷基和未取代或取代的亚环烷基-C 1 -C 4 - 亚烷基 - 亚杂烷基亚烷基，用于改善至少一种固体 聚酰胺树脂的状态特性。 固态性质优选选自机械性能和光泽度。

公开(公告)号：US09024308B2

公开(公告)日：2015-05-05

申请号：US14540838

申请日：2014-11-13

Applicant: BASF SE

Inventor： Markus Bold ,  Christian Lennartz ,  Martina Egen ,  Hans-Werner Schmidt ,  Mukundan Thelakkat ,  Markus Baete ,  Christian Neuber ,  Wolfgang Kowalsky ,  Christian Schildknecht ,  Hans-Hermann Johannes

IPC: H01L51/54 ,  C07F15/00 ,  H01L51/00 ,  H01L51/50

CPC classification number: H01L51/0085 ,  B01J31/2265 ,  B01J31/2273 ,  B01J2531/16 ,  B01J2531/17 ,  B01J2531/18 ,  B01J2531/57 ,  B01J2531/60 ,  B01J2531/70 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/828 ,  C07F15/0033 ,  C09B57/00 ,  C09B57/10 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1018 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/18 ,  C09K2211/185 ,  H01L51/0081 ,  H01L51/5016 ,  H01L51/5096 ,  Y02P20/582

Abstract: Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitriles and conjugated dienes which form a π complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≧1; o is the number of ligands K, where o can be 0 or ≧1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.

Abstract translation: 在有机发光二极管中使用式（I）的过渡金属配合物，其中：M1是金属原子; 卡宾是卡宾配体; L是单阴离子或双阴离子配体; K是选自磷化氢的不带电荷的单齿或双齿配体; CO; 吡啶 腈和共轭二烯，形成＆pgr; 与M1复合; n是卡宾配体的数目，至少为1; m是配体L的数目，其中m可以是0或≥1; o是配体K的数目，其中o可以是0或≥1; 其中总和n + m + o取决于金属原子的氧化态和配位数以及配体卡宾，L和K的配位数，以及配体卡宾和L上的电荷，条件是n 包含这些过渡金属络合物的OLED，包含这些过渡金属络合物的发光层，包含该发光层的OLED，包含根据本发明的OLED的器件和特定的过渡金属络合物，其包含 至少两个卡宾配体。

公开(公告)号：US20140309428A1

公开(公告)日：2014-10-16

申请号：US14314753

申请日：2014-06-25

Applicant: BASF SE

Inventor： Martina EGEN ,  Klaus Kahle ,  Markus Bold ,  Thomas Gessner ,  Christian Lennartz ,  Simon Nord ,  Hans-Werner Schmidt ,  Mukundan Thelakkat ,  Markus Baete ,  Christian Neuber ,  Wolfgang Kowalsky ,  Christian Schildknecht ,  Hans-Hermann Johannes

IPC: H01L51/00

Abstract: The present invention relates to the use of transition metal-carbene complexes in organic light-emitting diodes (OLEDs), to a light-emitting layer, to a blocking layer for electrons or excitons, or to a blocking layer for holes, each comprising these transition metal-carbene complexes, to OLEDs comprising these transition metal-carbene complexes, to devices which comprise an inventive OLED, and to transition metal-carbene complexes.

Abstract translation: 本发明涉及将有机发光二极管（OLED）中的过渡金属 - 碳烯复合物用于发光层，用于电子或激子的阻挡层或用于空穴的阻挡层，每个包含这些 过渡金属 - 卡宾复合物，包含这些过渡金属 - 碳烯配合物的OLED，包含本发明的OLED的装置和过渡金属 - 卡宾络合物。

公开(公告)号：US09328219B2

公开(公告)日：2016-05-03

申请号：US13847752

申请日：2013-03-20

Applicant: BASF SE

Inventor： Claus Gabriel ,  Florian Richter ,  Hye Jin Park ,  Rainer Xalter ,  Hans-Werner Schmidt

IPC: C08K5/21

CPC classification number: C08K5/21 ,  Y10T428/1352 ,  Y10T428/139 ,  C08L77/00

Abstract: The present invention relates to a polymer composition comprising at least one polyamide and at least one urea compound of the formula I where x is 1, 2 or 3; R1 and R2 are selected from hydrogen, linear C1-C7-alkyl, branched C3-C10-alkyl, unsubstituted or substituted C3-C12-cycloalkyl, unsubstituted or substituted C3-C12-cycloalkyl-C1-C4-alkyl, unsubstituted or substituted aryl and unsubstituted or substituted aryl-C1-C4-alkyl; and Z is selected from C3-C10-alkanediyl, unsubstituted or substituted arylene, unsubstituted or substituted aryl unsubstituted or substituted ene-C1-C4-alkylene-arylene, unsubstituted or substituted heteroarylene, unsubstituted or substituted heteroarylene-C1-C4-alkylene-heteroarylene, unsubstituted or substituted C5-C8-cycloalkylene, C5-C8-cycloalkylene-C1-C4-alkylene-C5-C8-cycloalkylene, unsubstituted or substituted heterocycloalkylene and heterocycloalkylene-C1-C4-alkylene-heterocycloalkylene. This urea compound is used for improving the optical properties of the polyamide polymer composition. The present invention also relates to shaped articles obtained from said composition and to novel urea compounds.

Abstract translation: 本发明涉及包含至少一种聚酰胺和至少一种式I的脲化合物的聚合物组合物，其中x为1,2或3; R 1和R 2选自氢，直链C 1 -C 7 - 烷基，支链C 3 -C 10 - 烷基，未取代或取代的C 3 -C 12 - 环烷基，未取代或取代的C 3 -C 12 - 环烷基-C 1 -C 4烷基，未取代或取代的芳基 和未取代或取代的芳基-C 1 -C 4 - 烷基; Z为选自C 3 -C 10 - 烷二基，未取代或取代的亚芳基，未取代或取代的芳基未取代或取代的烯 - C 1 -C 4 - 亚烷基 - 亚芳基，未取代或取代的亚杂芳基，未取代或取代的杂亚芳基-C 1 -C 4亚烷基 - 亚杂芳基 未取代或取代的C 5 -C 8 - 亚环烷基，C 5 -C 8 - 亚环烷基-C 1 -C 4 - 亚烷基-C 5 -C 8 - 亚环烷基，未取代或取代的杂环亚烷基和亚杂环烷基-C 1 -C 4亚烷基 - 亚杂环亚烷基。 该尿素化合物用于改善聚酰胺聚合物组合物的光学性能。 本发明还涉及由所述组合物获得的成型制品和新型尿素化合物。

公开(公告)号：US20130251929A1

公开(公告)日：2013-09-26

申请号：US13847752

申请日：2013-03-20

Applicant: BASF SE

Inventor： Claus Gabriel ,  Hans-Werner Schmidt ,  Florian Richter

IPC: C08K5/21

CPC classification number: C08K5/21 ,  Y10T428/1352 ,  Y10T428/139 ,  C08L77/00

Abstract: The present invention relates to a polymer composition comprising at least one polyamide and at least one urea compound of the formula I where x is 1, 2 or 3; R1 and R2 are selected from hydrogen, linear C1-C7-alkyl, branched C3-C10-alkyl, unsubstituted or substituted C3-C12-cycloalkyl, unsubstituted or substituted C3-C12-cycloalkyl-C1-C4-alkyl, unsubstituted or substituted aryl and unsubstituted or substituted aryl-C1-C4-alkyl; and Z is selected from C3-C10-alkanediyl, unsubstituted or substituted arylene, unsubstituted or substituted aryl unsubstituted or substituted ene-C1-C4-alkylene-arylene, unsubstituted or substituted heteroarylene, unsubstituted or substituted heteroarylene-C1-C4-alkylene-heteroarylene, unsubstituted or substituted C5-C8-cycloalkylene, C5-C8-cycloalkylene-C1-C4-alkylene-C5-C8-cycloalkylene, unsubstituted or substituted heterocycloalkylene and heterocycloalkylene-C1-C4-alkylene-heterocycloalkylene.This urea compound is used for improving the optical properties of the polyamide polymer composition. The present invention also relates to shaped articles obtained from said composition and to novel urea compounds.

Abstract translation: 本发明涉及包含至少一种聚酰胺和至少一种式I的脲化合物的聚合物组合物，其中x为1,2或3; R 1和R 2选自氢，直链C 1 -C 7 - 烷基，支链C 3 -C 10 - 烷基，未取代或取代的C 3 -C 12 - 环烷基，未取代或取代的C 3 -C 12 - 环烷基-C 1 -C 4烷基，未取代或取代的芳基 和未取代或取代的芳基-C 1 -C 4 - 烷基; Z为选自C 3 -C 10 - 烷二基，未取代或取代的亚芳基，未取代或取代的芳基未取代或取代的烯 - C 1 -C 4 - 亚烷基 - 亚芳基，未取代或取代的亚杂芳基，未取代或取代的杂亚芳基-C 1 -C 4亚烷基 - 亚杂芳基 未取代或取代的C 5 -C 8 - 亚环烷基，C 5 -C 8 - 亚环烷基-C 1 -C 4 - 亚烷基-C 5 -C 8 - 亚环烷基，未取代或取代的杂环亚烷基和亚杂环烷基-C 1 -C 4 - 亚烷基 - 亚杂环亚烷基。 该尿素化合物用于改善聚酰胺聚合物组合物的光学性能。 本发明还涉及由所述组合物获得的成型制品和新型尿素化合物。

公开(公告)号：US20130210973A1

公开(公告)日：2013-08-15

申请号：US13717804

申请日：2012-12-18

Applicant: BASF SE

Inventor： Klaus Stoll ,  Kurt Hoffmann ,  Bruno Rotzinger ,  Hans-Werner Schmidt

IPC: C08K5/20 ,  C08K5/1575

CPC classification number: C08K5/20 ,  C08K5/1575 ,  C08K7/02

Abstract: A process for improving the flow properties of a melt containing a thermoplastic polymer, which comprises incorporating 0.005% to 0.5% by weight, relative to the weight of the thermoplastic polymer, of one or more additives selected from the group consisting of organic and inorganic compounds with needle-like morphology in their solid state into said thermoplastic polymer prior to or during melt processing.

Abstract translation: 一种用于改善含有热塑性聚合物的熔体的流动性能的方法，其包括相对于热塑性聚合物的重量掺入0.005重量％至0.5重量％的一种或多种选自有机和无机化合物的添加剂 在熔融加工之前或期间，其固态的针状形态进入所述热塑性聚合物。