公开(公告)号：US20140018597A1

公开(公告)日：2014-01-16

申请号：US13937413

申请日：2013-07-09

Applicant: BASF SE

Inventor： Daniel Pfeiffer ,  Stefan Bitterlich ,  Michael Hübner

IPC: C07C7/10

CPC classification number: C07C7/10 ,  B01D3/06 ,  B01D17/0208 ,  B01D19/0036 ,  C07C5/29 ,  C07C7/00 ,  C07C7/005 ,  C07C2527/125 ,  C07C2531/02 ,  C07C2601/14 ,  C07C13/18

Abstract: The present invention relates to a process for treating an output from a hydrocarbon conversion, wherein the hydrocarbon conversion is performed in the presence of an acidic ionic liquid. The hydrocarbon conversion is preferably an isomerization. A mixture which originates from the hydrocarbon conversion and comprises at least one hydrocarbon and at least one hydrogen halide is washed with an aqueous medium having a pH between 5 and 9, which removes hydrogen halide from the mixture.

Abstract translation: 本发明涉及一种处理烃转化产物的方法，其中烃转化在酸性离子液体存在下进行。 烃转化率优选为异构化。 来自烃转化率并且包含至少一种烃和至少一种卤化氢的混合物用pH在5和9之间的水性介质洗涤，其从混合物中除去卤化氢。

公开(公告)号：US10815168B2

公开(公告)日：2020-10-27

申请号：US13937351

申请日：2013-07-09

Applicant: BASF SE

Inventor： Steffen Tschirschwitz ,  Joni Joni ,  Jochen Bürkle ,  Stefan Bitterlich ,  Daniel Pfeiffer ,  Michael Hübner ,  Nicole Holub

IPC: C07C5/29 ,  C07C5/27

Abstract: The present invention relates to a chemical conversion process, preferably an isomerization process, for at least one hydrocarbon in the presence of an ionic liquid. The chemical conversion is performed in a dispersion, with dispersion of the hydrocarbon (phase (B)) in the ionic liquid (phase (A)) in the dispersion, the volume ratio of phase (A) to phase (B) being in the range from 2.5 to 4:1 [vol/vol].

公开(公告)号：US10081580B2

公开(公告)日：2018-09-25

申请号：US14053634

申请日：2013-10-15

Applicant: BASF SE

Inventor： Steffen Tschirschwitz ,  Kathrin Wissel-Stoll ,  Jochen Bürkle ,  Albena Kostova ,  Markus Schmitt ,  Veronika Wloka ,  Stephan Deuerlein ,  Marco Bosch ,  Steffen Oehlenschläger ,  Michael Schreiber ,  Gauthier Luc Maurice Averlant ,  Joni Joni ,  Roman Prochazka ,  Martin Bock ,  Alois Kindler ,  Daniela Malkowsky ,  Katharina Spuhl ,  Stefan Bitterlich ,  Daniel Pfeiffer

IPC: C07C5/29 ,  C07C5/10 ,  C07C7/08 ,  C07C7/163

CPC classification number: C07C5/29 ,  C07C5/10 ,  C07C7/08 ,  C07C7/163 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2527/11 ,  C07C2527/1206 ,  C07C2527/1213 ,  C07C2527/125 ,  C07C2527/126 ,  C07C2527/135 ,  C07C2601/14 ,  C07C13/10 ,  C07C13/18

Abstract: The present invention relates to a process for preparing cyclohexane by isomerizing a hydrocarbon mixture (HM1) comprising methylcyclopentane (MCP) in the presence of a catalyst. The catalyst is preferably an acidic ionic liquid. The starting material used is a stream (S1) which originates from a steamcracking process. The hydrocarbon mixture (HM1) obtained from this stream (S1) in an apparatus for aromatics removal has a reduced aromatics content compared to stream (S1), and (HM1) may optionally also be (virtually) free of aromatics. Depending on the type and amount of the aromatics remaining in the hydrocarbon mixture (HM1), especially in the case that benzene is present, the isomerization may additionally be preceded by performance of a hydrogenation of (HM1). In addition, depending on the presence of other components of (HM1), further purification steps may optionally be performed prior to or after the isomerization or hydrogenation. High-purity (on-spec) cyclohexane is preferably isolated from the hydrocarbon mixture (HM2) obtained in the isomerization, the specifications being, for example, those applicable to the use of the cyclohexane for the preparation, known to those skilled in the art, of caprolactam.

公开(公告)号：US20140114099A1

公开(公告)日：2014-04-24

申请号：US14053634

申请日：2013-10-15

Applicant: BASF SE

Inventor： Steffen Tschirschwitz ,  Kathrin Wissel-Stoll ,  Jochen Bürkle ,  Albena Kostova ,  Markus Schmitt ,  Veronika Wloka ,  Stephan Deuerlein ,  Marco Bosch ,  Steffen Oehlenschläger ,  Michael Schreiber ,  Gauthier Luc Maurice Averlant ,  Joni Joni ,  Roman Prochazka ,  Martin Bock ,  Alois Kindler ,  Daniela Malkowsky ,  Katharina Spuhl ,  Stefan Bitterlich ,  Daniel Pfeiffer

IPC: C07C5/29

CPC classification number: C07C5/29 ,  C07C5/10 ,  C07C7/08 ,  C07C7/163 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2527/11 ,  C07C2527/1206 ,  C07C2527/1213 ,  C07C2527/125 ,  C07C2527/126 ,  C07C2527/135 ,  C07C2601/14 ,  C07C13/10 ,  C07C13/18

Abstract: The present invention relates to a process for preparing cyclohexane by isomerizing a hydrocarbon mixture (HM1) comprising methylcyclopentane (MCP) in the presence of a catalyst. The catalyst is preferably an acidic ionic liquid. The starting material used is a stream (S1) which originates from a steamcracking process. The hydrocarbon mixture (HM1) obtained from this stream (S1) in an apparatus for aromatics removal has a reduced aromatics content compared to stream (S1), and (HM1) may optionally also be (virtually) free of aromatics. Depending on the type and amount of the aromatics remaining in the hydrocarbon mixture (HM1), especially in the case that benzene is present, the isomerization may additionally be preceded by performance of a hydrogenation of (HM1). In addition, depending on the presence of other components of (HM1), further purification steps may optionally be performed prior to or after the isomerization or hydrogenation. High-purity (on-spec) cyclohexane is preferably isolated from the hydrocarbon mixture (HM2) obtained in the isomerization, the specifications being, for example, those applicable to the use of the cyclohexane for the preparation, known to those skilled in the art, of caprolactam.

Abstract translation: 本发明涉及通过在催化剂存在下异构化包含甲基环戊烷（MCP）的烃混合物（HM1）来制备环己烷的方法。 催化剂优选为酸性离子液体。 使用的起始材料是来自蒸汽裂化过程的流（S1）。 在与物流（S1）相比，用于除去芳烃的装置中从该料流（S1）获得的烃混合物（HM1）具有降低的芳族化合物含量，（HM1）也可任选地（实际上）不含芳族化合物。 取决于残留在烃混合物（HM1）中的芳族化合物的类型和量，特别是在存在苯的情况下，异构化可另外进行（HM1）的氢化。 此外，根据（HM1）的其它组分的存在，可以任选地在异构化或氢化之前或之后进行进一步的纯化步骤。 高纯度（特定）环己烷优选与在异构化中获得的烃混合物（HM2）分离，其规格是例如适用于本领域技术人员已知的用于制备环己烷的那些 的己内酰胺。

公开(公告)号：US20140014596A1

公开(公告)日：2014-01-16

申请号：US13937428

申请日：2013-07-09

Applicant: BASF SE

Inventor： Daniel Pfeiffer ,  Stefan Bitterlich

IPC: B01D17/02

CPC classification number: B01D17/02 ,  B01D17/0214

Abstract: The present invention relates to a process for separating a phase (A) from a phase (B), phase (A) having a higher viscosity than phase (B), by inverting the direction of dispersion from phase (B) in phase (A) to phase (A) in phase (B) by recycling a stream comprising phase (B) in excess.

Abstract translation: 本发明涉及通过将相（B）的相分散方向（A相）反相，从相（B）相（A）相分离相（A）的相（A） ）通过将包含相（B）的物流过量地再循环到相（B）中的相（A）。

公开(公告)号：US09873646B2

公开(公告)日：2018-01-23

申请号：US15305111

申请日：2015-04-20

Applicant: BASF SE

Inventor： Michael Hübner ,  Lukas Schulz ,  Pawel Czajka ,  Oliver Christian Gobin ,  Nicole Holub ,  Daniel Pfeiffer ,  Andreas Weickgenannt ,  Marta Porta Garcia

IPC: C07C5/10 ,  C07C5/27 ,  C07C5/31 ,  C07C5/03 ,  C07C7/04

CPC classification number: C07C5/03 ,  C07C5/10 ,  C07C5/29 ,  C07C5/31 ,  C07C7/04 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2527/08 ,  C07C2527/11 ,  C07C2527/1213 ,  C07C2527/126 ,  C07C2527/135 ,  C07C2531/02 ,  C07C2601/14 ,  C07C13/18

Abstract: The present invention relates to a process for preparing cyclohexane from methylcyclopentane (MCP) and benzene. In the context of the present invention, MCP and benzene are constituents of a hydrocarbon mixture (HM1) additionally comprising dimethylpentanes (DMP), possibly cyclohexane and possibly at least one compound (low boiler) selected from acyclic C5-C6-alkanes and cyclopentane. First of all, benzene is converted in a hydrogenation step to cyclohexane (that present in the hydrocarbon mixture (HM2)), while MCP is isomerized in the presence of a catalyst, preferably of an acidic ionic liquid, to cyclohexane. After the hydrogenation but prior to the isomerization the dimethylpentanes (DMP) are removed, with initial removal of the cyclohexane present in the hydrocarbon mixture (HM2) together with DMP. This cyclohexane already present prior to the isomerization can be separated again from DMP in a downstream rectification step and isolated and/or recycled into the process for cyclohexane preparation. Between the DMP removal and MCP isomerization—if low boilers are present in the hydrocarbon mixture (HM1)—low boilers are, optionally removed. After the isomerization, the cyclohexane is isolated, optionally with return of unisomerized MCP and optionally of low boilers. Preferably, cyclohexane and/or low boilers are present in the hydrocarbon mixture (HM1), and so a low boiler removal is preferably conducted between the DMP removal from isomerization. It is additionally preferable that the removal of the cyclohexane from DMP is additionally conducted, meaning that the cyclohexane component which arises in the benzene hydrogenation and may be present in the starting mixture (HM1) is isolated and hence recovered.

公开(公告)号：US09409839B2

公开(公告)日：2016-08-09

申请号：US13937395

申请日：2013-07-09

Applicant: BASF SE

Inventor： Daniel Pfeiffer ,  Stefan Bitterlich

IPC: C07C7/144

CPC classification number: C07C7/144 ,  C07C2601/14 ,  C07C13/18

Abstract: The present invention relates to a process for separating a phase (A) comprising at least one ionic liquid from a phase (B), phase (A) having a higher viscosity than phase (B), comprising the following steps: a) providing a stream (S1) comprising a dispersion (D1) in which phase (A) is dispersed in phase (B), b) introducing stream (S1) into a phase separation unit (PT1) comprising a knitted fabric, preferably a knitted glass fiber fabric, c) separating the dispersed phase (A) from phase (B) in the phase separation unit (PT1), d) discharging a stream (S2) comprising at least 70% by weight, preferably at least 90% by weight, of phase (A) from the phase separation unit (PT1), and e) discharging a stream (S3) comprising at least 70% by weight, preferably at least 90% by weight, of phase (B) from the phase separation unit (PT1).

Abstract translation: 本发明涉及一种分离包含至少一种离子液体的相（A）的方法，所述相（A）相具有比相（B）更高的粘度的相（B）相（A）相，包括以下步骤：a） 流（S1），其中相（A）相分散在相（B）中的分散体（D1），b）将流（S1）引入到包括针织物的相分离单元（PT1）中，优选为针织玻璃纤维织物 ，c）在相分离单元（PT1）中分离相（B）的分散相（A）; d）排出包含至少70重量％，优选至少90重量％的相 （A）的相分离单元（PT1），以及e）从相分离单元（PT1）排出包含至少70重量％，优选至少90重量％的相（B）的物流（S3） 。

公开(公告)号：US20140018590A1

公开(公告)日：2014-01-16

申请号：US13937402

申请日：2013-07-09

Applicant: BASF SE

Inventor： Steffen Tschirschwitz ,  Joni Joni ,  Daniel Pfeiffer ,  Stefan Bitterlich ,  Michael Hübner

IPC: B01J19/02

CPC classification number: B01J19/02 ,  B01J2219/0209 ,  B01J2219/0213 ,  B01J2219/0236 ,  B01J2219/0245 ,  C10G45/58

Abstract: The present invention relates to a process for performing a hydrocarbon conversion or processing an output from a hydrocarbon conversion in the presence of an acidic ionic liquid. The hydrocarbon conversion, which is preferably an isomerization, is performed in apparatuses whose surfaces which come into contact with the acidic ionic liquid have been manufactured completely or at least partially from at least one nonmetallic material. The nonmetallic material in turn has been applied to at least one further material other than the nonmetallic material.

Abstract translation: 本发明涉及一种在酸性离子液体存在下进行烃转化或加工烃转化产物的方法。 优选异构化的烃转化在其与酸性离子液体接触的表面已经完全制造或至少部分地由至少一种非金属材料制造的装置中进行。 非金属材料又被应用于非金属材料以外的至少一种其它材料。

公开(公告)号：US20140018588A1

公开(公告)日：2014-01-16

申请号：US13937247

申请日：2013-07-09

Applicant: BASF SE

Inventor： Katharina Spuhl ,  Markus Schmitt ,  Jochen Bürkle ,  Joni Joni ,  Steffen Tschrischwitz ,  Daniel Pfeiffer ,  Steffen Bitterlich ,  Lukas Schulz ,  Michael Hübner

IPC: C07C5/29

CPC classification number: C07C5/29 ,  C07C2527/125 ,  C07C2601/14 ,  C07C13/18

Abstract: The present invention relates to a process for isomerizing at least one hydrocarbon in the presence of an acidic ionic liquid and at least one hydrogen halide (HX) in an apparatus (V1), wherein the hydrogen halide (HX) is removed in an apparatus (V2) in gaseous form from the isomerization product and is at least partly recycled into apparatus (V1).

Abstract translation: 本发明涉及在装置（V1）中在酸性离子液体和至少一种卤化氢（HX）存在下使至少一种烃异构化的方法，其中在设备中除去卤化氢（HX）（ V2），并且至少部分地再循环到装置（V1）中。