CHEMICAL REACTION PROCESS AT CONSTANT HYDROGEN HALIDE PARTIAL PRESSURE
    2.
    发明申请
    CHEMICAL REACTION PROCESS AT CONSTANT HYDROGEN HALIDE PARTIAL PRESSURE 审中-公开
    恒温氢化物部分压力下的化学反应过程

    公开(公告)号:US20140257007A1

    公开(公告)日:2014-09-11

    申请号:US14199117

    申请日:2014-03-06

    申请人: BASF SE

    IPC分类号: C07C5/27

    摘要: The present invention relates to a chemical reaction process, preferably an isomerization process, of at least one hydrocarbon in the presence of an ionic liquid and a hydrogen halide (HX). The chemical reaction is carried out in an apparatus (V1) in which a gas phase is in direct contact with a liquid reaction mixture. The gas phase and the liquid reaction mixture each comprise the hydrogen halide and the liquid reaction mixture additionally comprises at least one hydrocarbon and the ionic liquid. Gaseous HX is introduced into the apparatus (V1) in such a way that the hydrogen halide partial pressure is kept constant in the gas phase. The ionic liquid used in the respective chemical reaction, in particular in an isomerization, can (inter alia) be regenerated by the process of the invention.

    摘要翻译: 本发明涉及在离子液体和卤化氢(HX)存在下至少一种烃的化学反应过程,优选异构化方法。 化学反应在气相与液体反应混合物直接接触的装置(V1)中进行。 气相和液体反应混合物各自包含卤化氢,液体反应混合物另外包含至少一种烃和离子液体。 将气态HX引入装置(V1)中,使得卤化氢分压在气相中保持恒定。 用于各化学反应的离子液体,特别是在异构化中,可以通过本发明的方法(尤其是)再生。

    CHEMICAL REACTION PROCESS WITH ADDITION OF METAL HALIDES
    3.
    发明申请
    CHEMICAL REACTION PROCESS WITH ADDITION OF METAL HALIDES 审中-公开
    添加金属卤化物的化学反应过程

    公开(公告)号:US20140257003A1

    公开(公告)日:2014-09-11

    申请号:US14199065

    申请日:2014-03-06

    申请人: BASF SE

    IPC分类号: C07C5/29

    摘要: The present invention relates to a chemical reaction process, preferably an isomerization process, of at least one hydrocarbon in the presence of an ionic liquid. The chemical reaction is carried out in an apparatus (V1) with at least one metal halide, preferably aluminum halide, being introduced repeatedly or continuously into the apparatus (V1). The anion of the ionic liquid used comprises at least one metal component and at least one halogen component. Here, the anion of the ionic liquid and the metal halide introduced into the apparatus (V1) have the same halogen component and the same metal component. The ionic liquid used in the respective chemical reaction, in particular in an isomerization, can (inter alia) be regenerated by the process of the invention.

    摘要翻译: 本发明涉及在离子液体存在下至少一种烃的化学反应过程,优选异构化方法。 化学反应在设备(V1)中进行,其中至少一种金属卤化物,优选卤化铝,被重复地或连续地引入到设备(V1)中。 使用的离子液体的阴离子包括至少一种金属组分和至少一种卤素组分。 这里,引入到设备(V1)中的离子液体和金属卤化物的阴离子具有相同的卤素组分和相同的金属组分。 用于各化学反应的离子液体,特别是在异构化中,可以通过本发明的方法(尤其是)再生。

    Separation of ionic liquids in coalescing devices

    公开(公告)号:US10137386B2

    公开(公告)日:2018-11-27

    申请号:US15039084

    申请日:2014-12-01

    申请人: BASF SE

    摘要: A process for separating a phase (A) comprising at least one ionic liquid from a phase (B), where phase (A) has a higher viscosity than phase (B), comprising: a) providing a stream (S1) comprising a dispersion (D1) in which phase (A) is dispersed in phase (B), b) introducing stream (S1) into a coalescing device (KV), where the inflow rate of stream (S1) is from 0.05 to 150 kg/(cm2*h) based on the average cross-sectional area of coalescing device (KV), wherein the packing density of coalescing device (KV) is from 50 to 500 kg/m3, separating phase (A) from phase (B) in coalescing device (KV), discharging a stream (S2) comprising at least 70% by weight of phase (A) from coalescing device (KV) and discharging a stream (S3) comprising at least 70% by weight of phase (B) from coalescing device (KV).

    PROCESS FOR PREPARING CYCLOHEXANE COMPRISING A PRIOR REMOVAL OF DIMETHYLPENTANES
    5.
    发明申请
    PROCESS FOR PREPARING CYCLOHEXANE COMPRISING A PRIOR REMOVAL OF DIMETHYLPENTANES 审中-公开
    制备环己烷的方法,包括去除二甲基氨基甲酸酯

    公开(公告)号:US20140114103A1

    公开(公告)日:2014-04-24

    申请号:US14053659

    申请日:2013-10-15

    申请人: BASF SE

    IPC分类号: C07C5/31 C07C5/10

    摘要: The present invention relates to a process for preparing cyclohexane from benzene and/or methylcyclopentane (MCP) by hydrogenation or isomerization. Prior to the cyclohexane preparation, the dimethylpentanes (DMP) are removed in a distillation apparatus (D1) from a hydrocarbon mixture (HM1) comprising not only benzene and/or MCP but also DMP. If cyclohexane is already present in the hydrocarbon mixture (HM1), this cyclohexane is first removed together with DMP from benzene and/or MCP. This cyclohexane already present can be separated again from DMP in a downstream distillation step and recycled into the process for cyclohexane preparation.

    摘要翻译: 本发明涉及通过氢化或异构化由苯和/或甲基环戊烷(MCP)制备环己烷的方法。 在环己烷制备之前,在不仅包含苯和/或MCP而且还包含DMP的烃混合物(HM1)的蒸馏装置(D1)中除去二甲基戊烷(DMP)。 如果烃混合物(HM1)中已经存在环己烷,则首先从苯和/或MCP与DMP一起除去该环己烷。 已经存在的环己烷可以在下游蒸馏步骤中再次从DMP分离并再循环到环己烷制备方法中。

    CHEMICAL CONVERSION PROCESS IN A DISPERSION
    6.
    发明申请
    CHEMICAL CONVERSION PROCESS IN A DISPERSION 审中-公开
    化学转化过程

    公开(公告)号:US20140018591A1

    公开(公告)日:2014-01-16

    申请号:US13937351

    申请日:2013-07-09

    申请人: BASF SE

    IPC分类号: C07C5/29

    摘要: The present invention relates to a chemical conversion process, preferably an isomerization process, for at least one hydrocarbon in the presence of an ionic liquid. The chemical conversion is performed in a dispersion, with dispersion of the hydrocarbon (phase (B)) in the ionic liquid (phase (A)) in the dispersion, the volume ratio of phase (A) to phase (B) being in the range from 2.5 to 4:1 [vol/vol].

    摘要翻译: 本发明涉及在离子液体存在下至少一种烃的化学转化方法,优选异构化方法。 在分散体中进行化学转化,其中烃(相(B))在分散体中的离子液体(相(A))中分散,相(A)与相(B)的体积比在 范围为2.5至4:1 [vol / vol]。

    PROCESS FOR REMOVING HYDROGEN HALIDES IN A RECTIFYING COLUMN WITH A PARTIAL CONDENSER
    8.
    发明申请
    PROCESS FOR REMOVING HYDROGEN HALIDES IN A RECTIFYING COLUMN WITH A PARTIAL CONDENSER 审中-公开
    在具有部分冷凝器的整流柱中去除氢化物的方法

    公开(公告)号:US20140018595A1

    公开(公告)日:2014-01-16

    申请号:US13937373

    申请日:2013-07-09

    申请人: BASF SE

    IPC分类号: C07C7/00

    摘要: The present invention relates to a process for treating an output from a chemical reaction, wherein the chemical reaction is performed in the presence of an ionic liquid. The chemical reaction is preferably an isomerization. In a rectifying column with a partial condenser, the hydrogen halide is drawn off from a mixture which originates from the chemical reaction and comprises at least one organic compound, preferably at least one hydrocarbon, and at least one hydrogen halide.

    摘要翻译: 本发明涉及一种处理化学反应输出的方法,其中化学反应是在离子液体存在下进行的。 化学反应优选为异构化。 在具有部分冷凝器的精馏塔中,卤化物从起始于化学反应的混合物中排出,并且包含至少一种有机化合物,优选至少一种烃和至少一种卤化氢。