摘要:
The present invention relates to a chemical conversion process, preferably an isomerization process, for at least one hydrocarbon in the presence of an ionic liquid. The chemical conversion is performed in a dispersion, with dispersion of the hydrocarbon (phase (B)) in the ionic liquid (phase (A)) in the dispersion, the volume ratio of phase (A) to phase (B) being in the range from 2.5 to 4:1 [vol/vol].
摘要:
The present invention relates to a chemical reaction process, preferably an isomerization process, of at least one hydrocarbon in the presence of an ionic liquid and a hydrogen halide (HX). The chemical reaction is carried out in an apparatus (V1) in which a gas phase is in direct contact with a liquid reaction mixture. The gas phase and the liquid reaction mixture each comprise the hydrogen halide and the liquid reaction mixture additionally comprises at least one hydrocarbon and the ionic liquid. Gaseous HX is introduced into the apparatus (V1) in such a way that the hydrogen halide partial pressure is kept constant in the gas phase. The ionic liquid used in the respective chemical reaction, in particular in an isomerization, can (inter alia) be regenerated by the process of the invention.
摘要:
The present invention relates to a chemical reaction process, preferably an isomerization process, of at least one hydrocarbon in the presence of an ionic liquid. The chemical reaction is carried out in an apparatus (V1) with at least one metal halide, preferably aluminum halide, being introduced repeatedly or continuously into the apparatus (V1). The anion of the ionic liquid used comprises at least one metal component and at least one halogen component. Here, the anion of the ionic liquid and the metal halide introduced into the apparatus (V1) have the same halogen component and the same metal component. The ionic liquid used in the respective chemical reaction, in particular in an isomerization, can (inter alia) be regenerated by the process of the invention.
摘要:
A process for separating a phase (A) comprising at least one ionic liquid from a phase (B), where phase (A) has a higher viscosity than phase (B), comprising: a) providing a stream (S1) comprising a dispersion (D1) in which phase (A) is dispersed in phase (B), b) introducing stream (S1) into a coalescing device (KV), where the inflow rate of stream (S1) is from 0.05 to 150 kg/(cm2*h) based on the average cross-sectional area of coalescing device (KV), wherein the packing density of coalescing device (KV) is from 50 to 500 kg/m3, separating phase (A) from phase (B) in coalescing device (KV), discharging a stream (S2) comprising at least 70% by weight of phase (A) from coalescing device (KV) and discharging a stream (S3) comprising at least 70% by weight of phase (B) from coalescing device (KV).
摘要:
The present invention relates to a process for preparing cyclohexane from benzene and/or methylcyclopentane (MCP) by hydrogenation or isomerization. Prior to the cyclohexane preparation, the dimethylpentanes (DMP) are removed in a distillation apparatus (D1) from a hydrocarbon mixture (HM1) comprising not only benzene and/or MCP but also DMP. If cyclohexane is already present in the hydrocarbon mixture (HM1), this cyclohexane is first removed together with DMP from benzene and/or MCP. This cyclohexane already present can be separated again from DMP in a downstream distillation step and recycled into the process for cyclohexane preparation.
摘要:
The present invention relates to a chemical conversion process, preferably an isomerization process, for at least one hydrocarbon in the presence of an ionic liquid. The chemical conversion is performed in a dispersion, with dispersion of the hydrocarbon (phase (B)) in the ionic liquid (phase (A)) in the dispersion, the volume ratio of phase (A) to phase (B) being in the range from 2.5 to 4:1 [vol/vol].
摘要:
The present invention relates to a process for preparing cyclohexane from methylcyclopentane (MCP) and benzene. In the context of the present invention, MCP and benzene are constituents of a hydrocarbon mixture (HM1) additionally comprising dimethylpentanes (DMP), possibly cyclohexane and possibly at least one compound (low boiler) selected from acyclic C5-C6-alkanes and cyclopentane. First of all, benzene is converted in a hydrogenation step to cyclohexane (that present in the hydrocarbon mixture (HM2)), while MCP is isomerized in the presence of a catalyst, preferably of an acidic ionic liquid, to cyclohexane. After the hydrogenation but prior to the isomerization the dimethylpentanes (DMP) are removed, with initial removal of the cyclohexane present in the hydrocarbon mixture (HM2) together with DMP. This cyclohexane already present prior to the isomerization can be separated again from DMP in a downstream rectification step and isolated and/or recycled into the process for cyclohexane preparation. Between the DMP removal and MCP isomerization—if low boilers are present in the hydrocarbon mixture (HM1)—low boilers are, optionally removed. After the isomerization, the cyclohexane is isolated, optionally with return of unisomerized MCP and optionally of low boilers. Preferably, cyclohexane and/or low boilers are present in the hydrocarbon mixture (HM1), and so a low boiler removal is preferably conducted between the DMP removal from isomerization. It is additionally preferable that the removal of the cyclohexane from DMP is additionally conducted, meaning that the cyclohexane component which arises in the benzene hydrogenation and may be present in the starting mixture (HM1) is isolated and hence recovered.
摘要:
The present invention relates to a process for treating an output from a chemical reaction, wherein the chemical reaction is performed in the presence of an ionic liquid. The chemical reaction is preferably an isomerization. In a rectifying column with a partial condenser, the hydrogen halide is drawn off from a mixture which originates from the chemical reaction and comprises at least one organic compound, preferably at least one hydrocarbon, and at least one hydrogen halide.
摘要:
The present invention relates to a process for performing a hydrocarbon conversion or processing an output from a hydrocarbon conversion in the presence of an acidic ionic liquid. The hydrocarbon conversion, which is preferably an isomerization, is performed in apparatuses whose surfaces which come into contact with the acidic ionic liquid have been manufactured completely or at least partially from at least one nonmetallic material. The nonmetallic material in turn has been applied to at least one further material other than the nonmetallic material.
摘要:
The present invention relates to a process for isomerizing at least one hydrocarbon in the presence of an acidic ionic liquid and at least one hydrogen halide (HX) in an apparatus (V1), wherein the hydrogen halide (HX) is removed in an apparatus (V2) in gaseous form from the isomerization product and is at least partly recycled into apparatus (V1).